• Title/Summary/Keyword: Cr layer

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Characteristics of the aluminum thisn films for the prevention of copper oxidation (구리 금속선의 산화 방지를 위한 알루미늄 박막의 산화 방지 특성)

  • 이경일;민경익;주승기;라관구;김우식
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.10
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    • pp.108-113
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    • 1994
  • The characteristics of the oxidation prevention layers for the copper metallization were investigated. The thin films such as Cr, TiN and Al were used as the oxidation prevention layers for copper. Ultra thin aluminum films were found to prevent the oxidation of copper up to the highest oxidation annealing temperature among the barrier layers examined in this study. It was found that oxygen did not diffuse into copper through aluminum films because of the aluminum oxide layer formed on the aluminum surface and the ultra thin aluminum film could be a good oxidation barrier layer for the copper metallization.

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Development of Organic-Inorganic Hybrid Dielectric for Organic Thin Film Transistors

  • Jeong, Sun-Ho;Kim, Dong-Jo;Lee, Sul;Park, Bong-Kyun;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1115-1118
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    • 2006
  • Using a thermally-crosslinkable organosiloxane-based organic-inorganic hybrid material, solution processable gate dielectric layer for organic thin-film transistors (OTFTs) have been fabricated. The hybrid dielectrics are synthesized by the sol-gel process, followed by the heat-treatment at $190{\bullet}\;.{\bullet}$ To investigate the electrical property of hybrid dielectric, leakage current behavior and capacitance were measured. To fabricate coplanar-type OTFTs, Au/Cr electrode was deposited onto the heavily doped silicon substrate with the organic-inorganic hybrid dielectric layer and then ${\alpha},{\omega}-dihexylquaterthiophene$ was drop-cast between source and drain electrical performance of the fabricated transistor.

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Development of advanced laser processing for the fabrication of HTS metallic tapes for power applications (전력용 고온초전도 금속테이프 제작을 위한 첨단 레이저공정 개발)

  • Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.688-691
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    • 1997
  • Good quality superconducting $YBa_2Cu_30_{7-{\delta}}$(YBCO) thin films were grown on Hastelloy (Ni-Cr-Mo alloys) with yttria-stabilized zirconia(YSZ) buffer layers by in situ pulsed laser deposition in a multi-target processing chamber. Generally, Hastelloy exhibits excellent resistance to corrosion, fatigue, thermal shock, impact, and erosion. However, it is difficult to make films on flexible metallic substrates due to interdiffusion problems between metallic substrates and superconducting overlayers. To overcome this difficulty, it is necessary to use YSZ buffer layer since it will not only limit the interdiffusion process but also minimize the surface microcrack formation due to smaller mismatch between the film and the substrate. In order to enhance the crystallinity of YBCO films on metallic substrates, YSZ buffer layers were grown at various temperatures different from the deposition temperature of YBCO films. On YSZ buffer layer grown at higher temperature than that for depositing YBCO film, the YBCO thin film was found to be textured with c-axis orientation by x-ray diffraction and had a zero-resistance critical temperature of about 85K.

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Effect of applying a DC voltage on the interfacial reactions at the zirconia to copper interface (접합계면반응에 미치는 직류전원부하의 영향)

  • Kim, Sung-Jin;Kim, In-Su;Oh, Myung-Hoon;Choi, Hwan
    • Proceedings of the KWS Conference
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    • 1996.05a
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    • pp.6-9
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    • 1996
  • The Joining of copper rod and zirconia tube was carried out in Ar gas atmosphere. There are two type of the joining. The one is the reaction bond consisting of Cu and zirconia was dominated by surface reaction wi th a undetctable very thin layer. It was found that copper elements were diffused to zirconia side, but that most of Z $r^{4+}$ ions were not diffused to copper side. This result means application of a DC voltage to migrate oxygen to the copper/zirconia interface can oxidize metal at the copper /zirconia interface, and the bonding reaction between zirconia and copper oxide may occur. The other is the reaction bonding was dominated by interdiffusion with a very thick interface layer. This result means application of a DC voltage can reduce zirconia at the interface. The bonding reaction is to be an alloying between Zr and Cr.

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세라믹 선재의 전기 구조적 특성

  • Lee, Sang-Heon;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.54-56
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    • 2005
  • Fabrication of c-axis oriented $(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ thick fabricated has been attempted using Ni substrates with the buffer layer of Cr or NiO. Coexistence of $(Hg_{0.75}Rc_{0.25})Ba_2Ca_3Cu_4O_y$ pellets wad found to stabilize $(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ phase of the tape. The c-axis oriented tapes were reproducibly obtained on the NiO/Ni substerate and they recorded high $B_{irr}$ at 77K.$(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ 1223.

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Effect of Sn and P on the shear strength of copper to stainless steel brazed joint (강과 스테인레스강 brazing 부의 전단 강도에 미치는 Sn, P의 영향 연구)

  • 정재필;이보영;강춘식
    • Journal of Welding and Joining
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    • v.7 no.3
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    • pp.36-43
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    • 1989
  • The furnace brazing in a Ar of copper to martensitic stainless steel(13.5Cr) using Cu-(5~8%)P-(0~8%)Sn powders was investigated. Shear strength, wettability, reacted layer, defect ratio at the stainless steel interface was evaluated. As Sn was added to the Cu-P powders, defect ratio and P content at the stainless steel interface decreased. And also as Sn was added, defect form at the stainless steel interface changed from the continuous layer to the discrete type, and shear strength of the brazed joint increased.

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Analysis of Oxide Layers in Phase Boundary Crack of Cast Austenitic Stainless Steel (주조 오스테나이트 스테인리스강 상경계 균열부 산화물 분석)

  • Min-Jae Choi;Sung-Woo Kim
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.171-178
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    • 2023
  • For the phase boundary crack found in the gasket made of cast austenitic stainless steel in the nuclear power plant, the oxide layers were analyzed through SEM and TEM. The results showed that cracks initiated and propagated along the austenite/δ-ferrite phase boundary, the propagation path was changed to penetrate the inside of the phase. The oxide layer located at the periphery of the crack along the phase boundary was identified as a complex multi-layered spinel structure, and Cr-rich carbides were also detected in the oxide. The cracks that propagated inside the austenite matrix were attributed to the presence of high external stresses and impurities.

Study on Improvement of Surface Properties of SKD61 Powder on S45C Using Laser Cladding

  • Cheol-Woo Kim;Hyo-Sang Yoo
    • Archives of Metallurgy and Materials
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    • v.67 no.4
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    • pp.1465-1468
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    • 2022
  • In this study, we investigated the effect of cladding on structural carbon steel (S45C) using 5%Cr-1.5%Mo-Fe powder (SKD61), which is expected to show economically efficient production of die-casting parts. The process conditions were performed under argon atmosphere using a diode laser source with specialized wavelength of 900-1070 nm, and the output conditions were 3, 4, and 5 kW, respectively. After the cladding was completed, the surface coating layer's shape and the microstructure were analyzed. The hardness test was carried out with Micro Vickers hardness tester under 500 gram-force along the normal line at the interval of 0.2 mm from the surface to core direction on the cross-sectional area. In addition, polarization curve test of the surface coating layer was performed to investigate the corrosion resistance characteristics.

Effect of CeO$_2$ buffer layer on the crystallization of YBCO thin film on Hastelloy substrate (비정질 금속 기판상에 증착된 YBCO 박막의 결정성에 대한 CEO$_2$ 완충막의 효과)

  • Kim, Sung-Min;Lee, Sang-Yeol
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.392-396
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    • 1999
  • Superconducting YBa$_2Cu_3O_{7-{\delta}}$(YBCO) thin films were grown on Hastelloy(Ni-Cr-Mo alloys) with CeO$_2$ buffer layer in-situ by pulsed laser deposition in a multi-target processing chamber. To apply superconducting property on power transmission line, we have deposited YBCO thin film on flexible metallic substrate. However, it is difficult to grow the YBCO films on flexible metallic substrates due to both interdiffusion problem between metallic substrate and superconducting overlayers and non-crystallization of YBCO on amorphous substrate. It is necessary to use a buffer layer to overcome the difficulties. We have chosen CeO$_2$ as a buffer layer which has cubic structure of 5.41 ${\AA}$ lattice parameter and only 0.2% of lattice mismatch with 3.82 ${\AA}$ of a-axis lattice parameter of YBCO on [110] direction of CeO$_2$ In order to enhance the crystallization of YBCO films on metallic substrates, we deposited CeO$_2$ buffer layers with varying temperature and 02 pressure. By XRD, it is observed that dominated film orientation is strongly depending on the deposition temperature of CeO$_2$ layer. The dominated orientation of CeO$_2$ buffer layer is changed from (200) to(111) by increasing the deposition temperature and this transition affects the crystallization of YBCO superconducting film on CeO$_2$ buffered Hastelloy.

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Performance Evaluation of a Double Layer Biofilter System to Control Urban Road Runoff (I) - System Design - (이중층 토양 여과시설을 이용한 도로 강우 유출수 처리성능 평가 (I) - 시설 설계인자 결정을 중심으로 -)

  • Cho, Kang Woo;Kim, Tae Gyun;Lee, Byung Ha;Lee, Seul Bi;Song, Kyung Guen;Ahn, Kyu Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.599-608
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    • 2009
  • This manuscript covers the results of field investigation and lab-scale experiments to design a double-layered biofilter system to control urban storm runoff. The biofilter system consisted of a coarse soil layer (CSL) for filtration and fine soil layer (FSL) for adsorption and biological degradation. The variations of flow rate and water quality of runoff from a local expressway were monitored for seven storm events. Laboratory column experiments were performed using seven kinds of soil and mulch to maximize pollutants removal. The site mean concentration (SMC) of storm runoff from the drainage area (runoff coefficient: 0.92) was measured to be 203 mg/L for SS, 307 mg/L for $TCOD_{Cr}$, 12.3 mg/L for TN, 7.3 mg/L for ${NH_4}^+-N$, and 0.79 mg/L for TP, respectively. This study employed a new design concept, to cover the maximum rainfall intensity with one month recurrence interval. Effective storms for last ten years (1998-2007) in seoul suggested the design rainfull intensity to be 8.8 mm/hr Single layer soil column showed the maximum removal rate of pollutants load when the uniformity coefficient of CSL was 1.58 and the silt/clay contents of FSL was virtually 7%. The removal efficiency during operation of double layer soil column was 98% for SS and turbidity, 75% for TCODCr, 56% for ${NH_4}^+-N$, 87% for TP, and 73-91% for heavy metals. The hydraulic conductivity of the soil column, 0.023 cm/sec, suggested that the surface area of the biofilter system should be about 1% of the drainage area to treat the rainfall intensity of one month recurrence interval.