• Title/Summary/Keyword: Cr layer

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Effect of Si on Corrosion of Fe-Cr and Fe-Cr-Ni Alloys in wet CO2 Gas

  • Nguyen, T.D.;Zhang, J.;Young, D.J.
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.127-131
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    • 2015
  • Model alloys Fe-9Cr, Fe-20Cr and Fe-20Cr-20Ni (wt. %) with 0.1 and 0.2 % Si were exposed to $Ar-20CO_2-20H_2O$ gas at $818^{\circ}C$. The undoped alloys formed a thick iron-rich oxide scale. The additions of Si reduced scaling rates of Fe-9Cr to some extent but significantly suppressed the formation of iron oxide scales on Fe-20Cr and Fe-20Cr-20Ni. Carburisation also occurred in all undoped alloys, but not in Si-containing Fe-20Cr and Fe-20Cr-20Ni. Protection against carburisation was a result of the formation of an inner scale layer of silica.

Interfacial Diffusion in Fe/Cr Magnetic Multilayers Studied by Synchrotron X-ray Techniques (방사광 x-선 기법에 의한 다층형 Fe/Cr 자성박막의 계면확산 연구)

  • 조태식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.2
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    • pp.223-227
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    • 2004
  • We have studied the interfacial diffusion of Fe/Cr multilayers using synchrotron x-ray techniques, such as x-ray reflectivity, extended x-ray absorption fine structures (EXAFS), and high-resolution x-ray scattering. The results of x-ray reflectivity indicated that the interfacial roughness of Fe/Cr multilayers increased with the Cr-layer thickness. The Fourier transform (FT) of EXAFS data clearly showed that the Fe atoms dominantly diffused into the stable Cr layers at the Fe/Cr interface. The results of high-resolution x-ray scattering supported the interfacial diffusion of Fe atoms. Out study revealed that the dominantly interfacial diffusion of Fe atoms into the Cr layers effects the interfacial roughness of the Fe/Cr multilayers.

Codeposition of Al and Cr by pack cementation (팩 세멘테이션에 의한 Al 및 Cr의 동시 코팅)

  • Sohn, Hee-Sik;Lee, Yoon-Je;Kim, Moon-Il
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.2
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    • pp.127-136
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    • 1995
  • The simultaneous addition of Al and Cr to the surface of Ni-and Fe-base alloy provides enhanced resistance to oxidation and corrosion in high temperatures. However, because of the large differences in thermodynamic stabilities of the volatile halides of Al and Cr, the codeposition of Al and Cr by halideactivated pack cementation is only possible for very specific, limited combinations of conditions. In this study, the experiments on the combinations of various metallic source powders and activators were conducted in order to obtain codeposition layers of Al and Cr on Ni with adequate composition by pack cementation. When Cr-Al masteralloy was used as a source powder, it was not easy to control Al and Cr content sensitively in the coating layers. On the other hand, when pure Cr and Al powder was used, ${\beta}$-NiAl layer containing about 20wt % Cr was obtained.

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VMn underlayer for CoCrPt Longitudinal Media

  • S. C. Oh;Lee, T. D.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.352-362
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    • 2000
  • In this study, effects of novel VMn underlayer on magnetic properties of CoCrPt/VMn longitudinal medium was studied and compared with those of CoCrPt/Cr medium. It was found that the VMn film had (200) preferred orientation and the lattice constant was about 0.2967 nm, which is slightly larger than that of the Cr, 0.2888 nm. The grain size of VMn film was 9.3 nm at 30 nm thickness, and this is about 38 % smaller than that of a similarly deposited Cr film. The CoCrPt/VMn films showed higher coercivity in comparison with the CoCrPt/Cr films. The coercivity increase seems to be attributed to the increased Co (11.0) texture, improved lattice matching between Co (11.0) and VMn (200), and lower stacking fault density. Mn must have diffused into the CoCrPt magnetic layer more uniformly rather than preferentially along grain boundaries this reduced Ms at higher substrate temperature

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Effect of Heat Treatment Characteristic on the Gas Nitriding of Stainless Steels (스테인리스강의 가스질화에 미치는 열처리 조건의 영향에 관한 연구)

  • Kim, H.G.;Hwang, G.S.;Sun, C.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.16 no.2
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    • pp.78-82
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    • 2003
  • Nitrided compound layer and diffusion layer structure were observed by SEM. The compound layer and the constituent of nitrided surface of STS 304, STS 316, STS 410 and SACM 645 steel were analysed using EMPA and XRD respectively. The depth of nitriding layer that is obtained from similar nitriding condition decrease in the order of SACM 645 > STS 410 > STS 316 > STS 304. Result of phase transformation of the nitrided at $550^{\circ}C$ by XRD analysis were as follows; The austenitic stainless steel was mainly consist of $Cr_2N$ accompanying with $Fe_4N$ and $Fe_{2-3}N$ phase and martensitic stainless steel was mainly consist of present $Fe_{2-3}N+Cr_2N$ phase, but SACM 645 steel was $Fe_{2-3}N$ phase present only.

Prepared Thin films by Two-Step Methode For Perpendicular magnetic recording Media (Two-Step 방식을 이용한 수직자기기록용 박막의 제작)

  • Park, W.H.;Son, I.H.;Shin, S.K.;Lee, D.J.;Park, Y.S.;Kim, K.H.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.6-8
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    • 2002
  • In order to prepare magnetic recording layer with a good quality crystallographic characteristic. We prepared $Co_{77}Cr_{20}Ta_3$ layer for perpendicular magnetic recording media on slide glass substrate by Two-Step Methode. The thickness of magnetic layer was fixed 100 nm and buffer layer were varied from 10 to 50 nm, and input current was varied from 0.2[A] to 0.5[A]. The surface morphology and crystal orientation of the CoCrTa films were examined with XRD. Prepared thin films showed improvement of dispersion angle of c-axis orientation ${\Delta}{\theta}_{50}$ caused by inserting buffer layer.

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Effect of Boronizing on Inconel 625 Superalloy for Improving Mechanical Properties (보로나이징처리에 따른 Inconel 625 초합금강의 기계적 특성 향상)

  • Kim, Dae-Wook;Kim, Yu-Sung;Lee, In-Sik;Cha, Yeo-Hun;Jeong, Kyeong-Hoon;Cha, Byung-Chul
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.316-320
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    • 2019
  • The effect of boronizing on mechanical properties including wear behavior and hardness of Inconel 625 superalloy were investigated. The cross-section observation demonstrated that boronized samples were composed of multi-phase boride layer (CrxBx, Ni2B), diffusion layer, and substrate. The boride and diffusion layers were increased with increasing treatment temperature and holding time. However, CrxBx layer was partially peeled off when it treated 1000℃. Subsequently, boride layer was completely separated from substrate with increasing temperature and time. A partial peeling of CrxBx layer is not noticeably degraded mechanical properties. In particular, friction coefficient and wear resistance were enhanced in lack of CrxBx phase. Therefore, these results suggest that a Ni2B phase mainly contribute to wear behavior on boronized Inconel 625 superalloy.

Behaviors of Cavitation Damage in Seawater for HVOF Spray Coated Layer with WC-10Co4Cr on Cu Alloy (WC-10Co4Cr으로 초고속 화염용사 코팅된 Cu 합금의 해수내 캐비테이션 손상 거동)

  • Han, Min-Su;Kim, Min-Sung;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.45 no.6
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    • pp.264-271
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    • 2012
  • Due to the good corrosion resistance and machinability, copper alloy is commonly employed for shipbuilding, hydroelectric power and tidal power industries. The Cu alloy, however, has poor durability, and the seawater application at fast flow condition becomes vulnerable to cavitation damage leading to economic loss and risking safety. The HVOF(High Velocity Oxygen Fuel) thermal spray coating with WC-10Co4Cr were therefore introduced as a replacement for chromium or ceramic to minimize the cavitation damage and secure durablility under high-velocity and high-pressure fluid flow. Cavitation test was conducted in seawater at $15^{\circ}C$ and $25^{\circ}C$ with an amplitude of $30{\mu}m$ on HVOF WC-10Co4Cr coatings produced by thermal spray. The cavitation at $15^{\circ}C$ and $25^{\circ}C$ exposed the substrate in 12.5 hours and in 10 hours, respectively. Starting from 5 hours of cavitation, the coating layer continued to show damage by higher than 160% over time when the temperature of seawater was elevated from $15^{\circ}C$ to $25^{\circ}C$. Under cavitation environment, although WC-10Co4Cr has good wear resistance and durability, increase in temperature may accelerate the damage rate of the coating layer mainly due to cavitation damage.