• Title/Summary/Keyword: Cr 층

Search Result 456, Processing Time 0.02 seconds

A Study on Catalysts for Simultaneous Removal of 1,2-Dichlorobenzene and NOx (1,2-Dichlorobenzene 및 질소산화물 동시제거를 위한 촉매연구)

  • Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
    • /
    • v.20 no.5
    • /
    • pp.522-526
    • /
    • 2009
  • The catalytic oxidation of 1,2-dichloribenzene (1,2-DCB) and simultaneous catalytic reduction of nitrogen oxides over the single catalyst has been investigated over various metals (Ru, Mn, Co and Fe) supported on $Al_2O_3$ and $CeO_{2}$. The activity of the different catalysts for catalytic oxidation of 1,2-dichloribenzene depended on the used metal, Ru/Co/$Al_2O_3$, Mn-Fe/CeO2 and Cr/$Al_2O_3$ (commercial catalysts) being the most actives ones. In the catalytic oxidation of chlorobenzene (CB), Ru/Co/$Al_2O_3$ is better than Pt-Pd/$Al_2O_3$, which is the well-known catalyst good for VOC oxidation. Furthermore, it has a good durability on the deactivation by $Cl_2$ and sulfur. For nitrogen oxides (NOx) removal, NOx conversion was 70% at $260^{\circ}C$.

The Perceived Discomfort in the Daily Activities of Korean Elderly (한국 고령층의 일상생활 활동 불편도 분석)

  • Lee, Dong-Hun;Na, Seok-Hee;Ahn, Eun-Seon;Chung, Min-K.
    • Journal of the Ergonomics Society of Korea
    • /
    • v.26 no.2
    • /
    • pp.67-79
    • /
    • 2007
  • The objective of this study is to investigate a perceived discomfort and cause of Korean elderly in various activities such as work and leisure as well as in daily activities. 120 subjects (30 female and 30 male for each age: the young and elderly) participated in the interview type of questionnaire. Each participant answered to 41 items of activities of daily living. The examination of each item was progressed with 3 steps: whether to do the activity or not, degree of activity discomfort, and the reasons or causes of discomfort. Borg's CR10 scale is used to measure the degree of discomfort of daily activities. As a result, there are differences for the proportion of performers between two age groups, except for essential activities such as individual maintenance and housekeeping. The elderly complained about their daily activities more than the young did, and the degree of discomfort of women was significantly larger than that of men with aging. There are seven items, the mean degree of discomfort of which is over three points for the elderly, and they showed significant difference between two age groups. It was the important reason that physical capacities such as muscle strength and suppleness are declined. The results showed the characteristics of Korean elderly in the whole daily activities. These will be used to understand various life styles of them and to propose a field or direction of study related to the aging.

Characteristics of PECVD-W thin films deposited on $Si_3N_4$ ($Si_3N_4$상에 PECVD법으로 형성한 텅스텐 박막의 특성)

  • 이찬용;배성찬;최시영
    • Journal of the Korean Vacuum Society
    • /
    • v.7 no.2
    • /
    • pp.141-149
    • /
    • 1998
  • The W thin films were deposited on Si3N4 by a PECVD technique. The effects of substrate temperature and gas flow ratio on the properties of the W films were investigated. The deposition of W films were limited by surface reaction at the temperature range of 150>~$250^{\circ}C$, W films had the deposition rate of 150~530 $\AA$/min and stress of 0.85~$14.35\times10 ^9 \textrm {dynes/cm}^2}$ at various substrate temperatures and $SiH_4/WF_6$ flow ratios. $SiH_4/WF_6$ flow ratio affected the deposition rate and stress of the W films, expecially, excessive flow of SiH4 abruptly changed the structure, chemical bonding, and stress of the W films. Among the deposited W films on TiN, Ti, Mo, NiCr and Al adhesion layer, the one on the Al had the best adhesion property.

  • PDF

Fabrication of 2-layer Flexible Copper Clad Laminate by Vacuum Web Coater with a Low Energy Ion Source for Surface Modification (저 에너지 표면 개질 이온원이 설치된 진공 웹 공정을 이용한 2층 flexible copper clad laminate 제작)

  • Choi, Hyoung-Wook;Park, Dong-Hee;Choi, Won-Kook
    • Korean Journal of Materials Research
    • /
    • v.17 no.10
    • /
    • pp.509-515
    • /
    • 2007
  • In order to fabricate adhesiveless 2-layer flexible copper clad laminate (FCCL) used for COF (chip on film) with high peel strength, polyimide (PI; Kapton-EN, $38\;{\mu}m$) surface was modified by reactive $O_2^+$ and $N_2O^+$ ion beam irradiation. 300 mm-long linear electron-Hall drift ion source was used for ion irradiation with ion current density (J) higher than $0.5\;mA/cm^2$ and energy lower than 200 eV. By vacuum web coating process, PI surface was modified by linear ion source and then 10-20 nm thick Ni-Cr and 200 nm thick Cu film were in-situ sputtered as a tie layer and seed layer, respectively. Above this sputtered layer, another $8-9{\mu}m$ thick Cu layer was grown by electroplating and subsequently acid and base resistance and thermal stability were tested for examining the change of peel strength. Peel strength for the FCCLs treated by both $O_2^+$ and $N_2O^+$ ion irradiation showed similar magnitudes and increased as the thickness of tie layer increased. FCCL with Cu (200 nm)/Ni-Cr (20 nm)/PI structure irradiated with $N_2O^+$ at $1{\times}10^{16}/cm^2$ ion fluence was proved to have a strong peel strength of 0.73 kgf/cm for as-received and 0.34 kgf/cm after thermal test.

The Study on the Removal Process of Heavy Metals from Mine Drainage Using Coal Bottom Ash (석탄 바닥회를 이용한 광산배수의 중금속 제거 공정 연구)

  • Kim, Hye Rim;Lee, Jung Mi;Han, In Kyu
    • Resources Recycling
    • /
    • v.29 no.6
    • /
    • pp.41-47
    • /
    • 2020
  • This study was carried out to utilize the coal bottom ash generated in a circulating fluidized bed combustion boiler as a treatment agent for heavy metal ions, and experiments were conducted to remove heavy metal ions from the acid mine drainage. The batch experiments were conducted to investigate the influence of dosage of ash, initial concentration of solution on the removal capacity of heavy metal ions (Cu, Cd, Cr, Pb). The results of the experiment showed that the total removal capacity of heavy metals was 30.8 mg/L and 46.4 mg/g, respectively, under the condition that the concentration of coal ash was added as 15 g/L of heavy materials and 10 g/L of light materials. After that, a long-term column experiment was performed to determine the maximum removal capacity of heavy metal ions (Cu, Cd, Cr, Pb, As), and the removal capacity for each metal component was investigated. After approximately 60 days of operation, the maximum removal capacity of heavy metals was 23.6 mg/g at pH 9.25.

Petrology of the Basalts in the Seongsan-Ilchulbong area, Jeju Island (제주도 성산일출봉 일대 현무암에 대한 암석학적 연구)

  • Koh, Jeong-Seon;Yun, Sung-Hyo;Jeong, Eun-Ju
    • Journal of the Korean earth science society
    • /
    • v.28 no.3
    • /
    • pp.324-342
    • /
    • 2007
  • This study reports petrography and geochemical characteristics of the basalt lava flows in Seongsan-Ilchulbong area, the easternpart of Jeju island, Korea, to understand the evolutionary processes of magma. Basalt lavas are classified into the Pyoseon-ri basalt and the Seongsan-ri basalt. The Pyoseon-ri basalt is dark-gray colored with many vescicles, and mainly consists of olivine, feldspar and rarely of clinopyroxene as phenocrysts. The Seongsan-ri basalt is largely aphanitic basalt and bright-gray colored, divided into two lava-flow units: lower lava flow (B1) and upper lava flow (B2) by the intercalated yellowish lapillistone and paleosol. The lavas plotted into sub-alkaline tholeiitic basalt and alkaline basalt series. The tholeiitic basalts have characteristically higher $SiO_2,\;FeO^T$, and CaO contents, but lower $TiO_2,\;K_2O,\;P_2O_5$ and other incompatible elements compared to the alkali basalts. The tholeiitic basalts have higher $SiO_2$ to the same MgO contents than the alkalic basalts. The contents of Ni, Cr, and MgO show a strong positive correlation, which indicates that low-MgO phases like plagioclase and titanomagnetite were important during the differentiation of magma. The contents of incompatible elements against that of Th show a strong positive correlation. The chondrite-nomalized REE patterns of tholeiitic and alkalic basalts are subparallel each other. LREEs contents of the former are lower than, but HREEs contents are similar to the latter. They both are similar to their K/Ba ratios. The primitive-mantle normalized spider diagram demonstrates that the contents of Ba and Th of all basaltic magma are enriched, and yet Cr, Ni are depleted. The tholeiitic and alkalic basalts may be originated from a different degree of the partial melting of the same mantle material source, and one shows a higher degree of the partial melting than the other.

Vacuum Web-coater with High Speed Surface Modification Equipment for fabrication of 300 mm wide Flexible Copper Clad Laminate (FCCL) (초고속 대면적 표면 처리 장치가 부착된 300 mm 폭 연성 동박적층 필림 제작용 진공 웹 코터)

  • Choi, H.W.;Park, D.H.;Kim, J.H.;Choi, W.K.;Sohn, Y.J.;Song, B.S.;Cho, J.;Kim, Y.S.
    • Journal of the Korean Vacuum Society
    • /
    • v.16 no.2
    • /
    • pp.79-90
    • /
    • 2007
  • Prototype of $800{\ell}$ vacuum web coater (Vic Mama) consisting of ion source with low energy less than 250 eV for high speed surface modification and 4 magnetron sputter cathodes was designed and constructed. Its performance was evaluated through fabricating the adhesiveless flexible copper clad laminate (FCCL). Pumping speed was monitored in both upper noncoating zone pumped down by 2 turbo pumps with 2000 l/sec pumping speed and lower surface modification and sputter zone vacuumed by turbo pumps with 450 1/sec and 1300 1/sec pumping speed respectively. Ion current density, plasma density, and uniformity of ion beam current were measured using Faraday cup and the distribution of magnetic field and erosion efficiency of sputter target were also investigated. With the irradiation of ion beams on polyimide (Kapton-E, $38{\mu}m$) at different fluences, the change of wetting angle of the deionized water to polyimide surface and those of surface chemical bonding were analyzed by wetting anglometer and x-ray photoelectron spectroscopy. After investigating the deposition rate of Ni-Cr tie layer and Cu layer was investigated with the variations of roll speed and input power to sputter cathode. FCCL fabricated by sputter and electrodeposition method and characterized in terms of the peel strength, thermal and chemical stability.

Characteristics on the Removal of Emulsified Vegetable Oil in Wastewater using Bio logical Fluidized Bed (생물학적(生物學的) 유동층(流動層)을 이용(利用)한 수중(水中)의 식물성유(植物性油) 제거특성(除去特性))

  • Kim, Hwan Gi;Park, Ro Sam
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.10 no.3
    • /
    • pp.127-136
    • /
    • 1990
  • In this paper, the experimental study was carried out for the removal of olive oil in wastewater by the use of Biological Fluidized Bed(BFB) with the reticulated polypropylene sheets as media. The nonbiodegradable olive oil, one of the animal and vegitable oil, was used bacause of the relative simplicity of constitution. Biological degraciability and removal characteristics of emulsified olive oil were studied by batch and continuous experiments respectively. From the results of batch experiments, it was observed that the emulsified olive oli used in BFB reactor was absorbed by media and sludge in about 12 hours, and degradation of the absorbed olive oli was mostly completed for 24 hours. The functional relationship of Michaelis-Menten's Enzyme reaction equation exists between oil concentration and maximum specific rate of olive oil. From the continuous experiments for the removal of olive oil using BFB reactor, it was proved that the substrate removal rate coefficient $k=0.004d^{-1}$, which is the first order kinetics. It was apperared that oxygen utlization coefficients for synthesis(a') and endogeneous respiration(b') of microorganisms in the reactor are respectively 0.85mg $O_2/mg$ $COD_{cr}$ and 0.011mg $O_2/mg$ BVS. day.

  • PDF

Reliability of Cu Interconnect under Compressive Fatigue Deformation Varying Interfacial Adhesion Treatment (유연소자용 기판과의 접착 특성에 따른 구리 배선의 압축 피로 거동 및 신뢰성)

  • Min Ju Kim;Jeong A Heo;Jun Hyeok Hyun;So-Yeon Lee
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.30 no.4
    • /
    • pp.105-111
    • /
    • 2023
  • Electronic devices have been evolved to be mechanically flexible that can be endured repetitive deformation. This evolution emphasizes the importance of long-term reliability in metal wiring connecting electronic components, especially under bending fatigue in compressed environments. This study investigated methods to enhance adhesion between copper (Cu) and polyimide (PI) substrates, aiming to improve the reliability of copper wiring under such conditions. We applied oxygen plasma treatment and introduced a chromium (Cr) adhesion layer to the polyimide substrate. Our findings revealed that these adhesion enhancement methods significantly affect compression fatigue behavior. Notably, the chromium adhesion layer, while showing weaker fatigue characteristics at 1.5% strain, demonstrated superior performance at 2.0% strain with no delamination, outperforming other methods. These results offer valuable insights for improving the reliability of flexible electronic devices, including reducing crack occurrence and enhancing fatigue resistance in their typical usage environments.

A Study for Young and Middle Age People of Accommodation (청·장년층의 조절력에 관한 고찰)

  • Kim, Jeoung Hi
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.3 no.1
    • /
    • pp.129-136
    • /
    • 1998
  • I obtained result like these to practice accommodation test using Spherical Add method and Cross cylinder lens method. The 242 eyes(121 persons) in test was the young and middle age people and their age was from 19 to 41. 1. Using Spherical Add, I tested accommodation. The twenties's limits of accommodation were 9~13 Diopter, and thirties to fourties's limits of accommodation were 6~8.5 Diopter. 2. Using Cross cylinder lens in the test of accommodation twenties's average accommodation limits were appeared 6.13 Diopter~10.13 Diopter, thirties average accommodation limits were 5.75 Diopter~8.75 Diopter and fourties's average accommodation limits were 4.38 Diopter~7.25 Diopter. All men women have had more good accommodation of the horizontal direction than the vertical direction. 3. Using Spherical Add method and Cross cylinder lens method, the results of accommodation were shown like these. Accommodation that measured with spherical add method was more big than cross cylinder's accommodation measuring method. Finally I found the fact accommodation decreases as age goes.

  • PDF