• Title/Summary/Keyword: Cr:ZnS

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Characterization and Corrosion Behaviour of Zn-Sn Binary Alloy Coatings in 0.5 M H2SO4 Solution

  • Fatoba, O.S.;Popoola, A.P.I.;Fedotova, T.
    • Journal of Electrochemical Science and Technology
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    • v.6 no.2
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    • pp.65-74
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    • 2015
  • This work examines the characterization and corrosion behaviour of laser alloyed UNSG10150 steel with three different premixed composition Zn-Sn binary powders using a 4.4 kW continuous wave (CW) Rofin Sinar Nd:YAG laser processing system. The steel alloyed samples were cut to corrosion coupons, immersed in sulphuric acid (0.5 M H2SO4) solution at 30℃ using electrochemical technique and investigated for its corrosion behaviour. The morphologies and microstructures of the developed coated and uncoated samples were characterized by Optic Nikon Optical microscope (OPM) and scanning electron microscope (SEM/EDS). Moreover, X-ray diffractometer (XRD) was used to identify the phases present. An enhancement of 2.7-times the hardness of the steel substrate was achieved in sample A1 which may be attributed to the fine microstructure, dislocations and the high degree of saturation of solid solution brought by the high scanning speed. At scanning speed of 0.8 m/min, sample A1 exhibited the highest polarization resistance Rp (1081678 Ωcm2 ), lowest corrosion current density icorr (4.81×10−8A/cm2 ), and lowest corrosion rate Cr (0.0005 mm/year) in 0.5 M H2SO4. The polarization resistance Rp (1081678 Ωcm2 ) is 67,813-times the polarization of the UNSG10150 substrate and 99.9972% reduction in the corrosion rate.

Composition of Chemical Components and Amount of Natural Supplies by Precipitation in Chinan Area of Chonbuk Province (전북 진안지역 강우의 화학성분 조성 및 천연공급량)

  • Han, Kang-Wan;Cho, Jae-Young;Son, Jae-Gwon
    • Korean Journal of Environmental Agriculture
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    • v.17 no.4
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    • pp.291-295
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    • 1998
  • Changes of chemical components and natural supplies by precipitation at agricultural zone in Chinan area of Chonbuk province from May 1, 1997 to April 30, 1998 were investigated. pH of precipitation ranged $6.44{\sim}7.24$ and EC showed $14.23{\sim}30.67{\mu}S/cm$. The $total{\sim}N$, NH4-N and NO3-N were $1.43{\sim}10.14$, $0.57{\sim}4.39$, and $0.18{\sim}1.69㎎/L$ respectively. The content of total-P showed $0.015{\sim}0.087㎎/L$ but ortho-P was not detected. The content of suspended solid, $Ca^{++}$, $Mg^{++}$, $Na^+$ and $K^+$ showed $3.6{\sim}15.3$, $0.37{\sim}1.66$, $0.17{\sim}0.52$, $0.22{\sim}0.87$, and $0.17{\sim}0.58㎎/L$. The content of SO42- and Cl- showed $3.37{\sim}014.47㎎/L$ and $1.02{\sim}7.24㎎/L$ respectively. Only Cu and Zn of heavy metals were detected $0{\sim}0.019㎎/L$ and $0.009{\sim}0.098㎎/L$ but Cd, Cu, Ni and Cr were not detected. Natural supplies of chemical components were 39.48㎏/ha/yr of total-N, 21.82㎏/ha/yr of $NH_4-N$, 6.90㎏/ha/yr of $NO_3-N$ and 0.68㎏/ha/yr of total-P. Also $Ca^{++}$, $Mg^{++}$, $Na^+$, $K^+$, $SO_4^{2-}$ and $Cl^-$ were supplied 14.46, 5.00, 7.26, 5.46, 98.76 and 31.16㎏/ha/yr respectively. Only of heavy metals were supplied 0.024㎏/ha/yr of Cu and 0.044㎏/㏊/yr of Zn.

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A Survey of the Kumho River Pollution (금호강 오염의 종합적 조사)

  • Bae, Zun-Ung;Lee, Sang-Hak;Lee, Sung-Ho
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.54-66
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    • 2002
  • In order to study systematic survey of Kumho river pollution, water analysis for 24 items was conducted at 16 sites surrounding the Kumho river system for 3 times from May 2000 to February 2001. Analytical items for the study of water quality are as follows; water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol, T-P, ${PO_4}^{3-}-P$, T-N, $NH_3-N$, ${NO_2}^--N$, ${NO_3}^--N$, Cu, Zn, Cr, Cd, Mn, Fe, Pb and As. The mean values obtained for water temperature, pH, BOD, COD, DO, SS, electrical conductivity, oil & grease, ABS, phenol T-P, T-N, Cu, Zn, Fe and Mn showed $17.84^{\circ}C$, 8.04, $2.54{\mu}g/mL$, $5.64{\mu}g/mL$, $7.07{\mu}g/mL$, $8.75{\mu}g/mL$, $600.4{\mu}S/cm$, $0.19{\mu}g/mL$, $0.015{\mu}g/mL$, $0.29{\mu}g/mL$, $0.21{\mu}g/mL$, $5.22{\mu}g/mL$, $0.005{\mu}g/mL$, $0.007{\mu}g/mL$, $0.044{\mu}g/mL$ and $0.001{\mu}g/mL$ respectively. As, Cd, Cr and Pb are not detected. The mean concentration of phenol, $NH_3-N$ and $NO_2-N$ were found to be increased compared to the prior study for 3 years from January 1997 to December 1999, that of BOD, COD, SS, oil & grease and ABS were found to be decreased and the others are nearly constant. The effect of Kumho river to the Nakdong river pollution are as follows. The mean concentration of BOD changed from $1.07{\mu}g/mL$ to $1.42{\mu}g/mL$ before and after of introducing of Kumho river water respectively. The mean concentration of COD, electrical conductivity, oil & grease, ABS, phenol, T-N and T-P changed from $1.99{\mu}g/mL$, $221{\mu}S/cm$, $0.15{\mu}g/mL$, $0.006{\mu}g/mL$, $0.06{\mu}g/mL$, $2.21{\mu}g/mL$ and $0.08{\mu}g/mL$ to $2.44{\mu}g/mL$, $392{\mu}S/cm$, $0.16{\mu}g/mL$, $0.015{\mu}g/mL$, $0.07{\mu}g/mL$, $2.81{\mu}g/mL$ and $0.19{\mu}g/mL$ respectively.

Stability against surge stress of ZPCCE-Based Varistors (ZPCCE계 바리스터의 써지 스트레스에 대한 안정성)

  • Yoo, Dae-Hoon;Kim, Myung-Jun;Park, Jong-Ah;Nahm, Choon-Woo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1706-1708
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    • 2004
  • This paper reports the stability against surge of ZnO-$Pr_6O_{11}$-CoO-$Cr_2O_3-Er_2O_3$-based varistors sintered at different sintering temperatures. As sintering temperature increases, the varistor voltage decreased in the range of 412${\sim}$266 V and the nonlinear exponent decreased in the range of 61${\sim}$50. Meanwhile, the stability against surge with surge peak current of 100 $A/cm^2(8{\times}20{\mu}s)$ exhibited to be good on the whole.

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A Study on the Effect of Heavy Metals on Embryos Formation of Sea Urchins (중금속이 성게의 배아형성에 미치는 영향에 관한 연구)

  • 유춘만
    • Journal of Environmental Health Sciences
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    • v.24 no.3
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    • pp.6-10
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    • 1998
  • This study was attempted to carry out the effects of heavy metals when sea urchins (Hemicentrotus pulcherrimus, Anthocidaris crassispina, Scahhechinus brevis) formed early embryos. Results of the experiment for the effects of heavy metals on the development of sea urchins, in most sea urchins, the ranking of heavy metals according to decreasing effects upon fertilization and development of urchin eggs was follows: Hg, Cu, Zn, CA, Ni, Cr, Pb, As,and Fe. In addition, in most heavy metals, the ranking of experimental animals according to decreasing effects upon fertilization and development of urchin eggs in the same concentration of heaw metals was follows: H. pulcherrimus, A. crassispina, and S. brevis.

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A Study on the Relation between Riverbed Structure and Pollutant Concentration in Downstream of Nakdong River (낙동강 하류의 하상구조와 오염물질과의 상관관계 연구)

  • 황선출;정성욱
    • Journal of Environmental Science International
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    • v.5 no.4
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    • pp.481-494
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    • 1996
  • This study was performed to investigate the relationship between concentrations of heavy metals in sediment and the depths of 27 sampling sites along the West Nakdong river in downstream of Nakdong River. The deepest site was Kangdong bridge nearby 20ft. From here, the depth was shallowed to Chidong gradually. In each site the smaller mesh was, the liger concentration of heavy metal becomed. Concentration of Zn, Cd, Cr and Cu at inflow point of Shinoe stream was 576.016 ppm, 262.307 ppm, 68.674 ppm and 61.634 ppm, respectively, the concentration was the higest at this point. From here, it was lowered gradually. The concentration of heavy metal at inflow point of Joman river was 155.328 ppm, 56.485 ppm, 25.200 ppm and 31.172 ppm, respectively, those concentrations were liger than other points with the exception of Shinoe stream. Therefore, woman river and Shinoe stream were the major source of pollution in West Nakdong river. Among two sources Shinoe stream was more important source of pollution. West Nakdong river has become lake by Noksan floodgate because it's pollution has had influence on Bonglim.

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폐 석탄광산 배수처리 시 발생되는 슬러지를 이용한 오염토양 중금속 고형화 처리 기술 연구

  • Choe, Myeong-Chan;Im, Jeong-Hyeon;Son, Yeong-Gyu;Jang, Min;Sim, Yeon-Sik;Kim, Ji-Hyeong
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.472-475
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    • 2008
  • 중금속으로 오염된 토양을 안정화하고자 석탄 광산 배수 처리 시 발생되는 슬러지를 이용하여 중금속 용출 실험을 실시하였다. 용출 실험을 위하여 슬러지를 무게비율로 0%, 1%, 3%를 완전혼합하고, 3%슬러지를 오염토양과 층을 이루어 용출 실험을 실시하였다. 유입 pH를 5.5-6.2와 3-4로 조절하여 용출실험을 실시한 결과 Cu, Zn, Pb, Cr의 용출 농토는 3% M<3% S<1% M<0% 순으로 나타났다. 오염토양 무게 비율로 3% 슬러지를 완전혼합 시 중금속 용출 실험 결과 20년 기준 안정성을 확보할 수 있었다.

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A Study on the Water Quality of Domestic Mineral Water (Saeng Su) (국내 보존음료수(생수)의 성분에 관한 연구)

  • 류의형;이중근;김성조
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.41-45
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    • 1990
  • This study was performed to analyze for the mineral water (Saeng Su) from 12 pure beverage Co. products, which was obtained during March to May in 1988. The results were as follows: 1. The analytical results of contaminant materials in all the samples were suitable for drinking water standard. The mean value of NH$_{3}$-N, NO$_{3}$-N, Cl-and KMnO$_{4}$ consumption were ND, 49mg/l, 1.08mg/l and 8.14mg/l, respectively. 2. Total bacterial counts were 3/cc in average and Coliforms was negative in all samples. 3. The analytical results of Heavy metals were not detected or detected in a small amount, and the contents were different from each company. The CN, Hg, P were not detected in all the samples and the mean value of Cu, Fe, Mn were 0.0087mg/l, 0.0303mg/l, 0.018mg/l, respectively and it's contents were low. 4. The mean value of Pb, Zn, Cr$^{+6}$, As and Cd were 0.016mg/l, 0.015mg/l, 0.0025mg/l. 0.0059mg/l and 0.0011mg/l respectively.

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Improvement of Resonance Characteristics by Post-Annealing in FBAR Devices

  • Lee, Jae-Young;Mai, Linh;Yoon, Gi-Wan
    • Journal of information and communication convergence engineering
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    • v.5 no.4
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    • pp.320-323
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    • 2007
  • This paper presents the resonance characteristics of the ZnO-based FBAR devices with multilayered Bragg reflectors with Cr adhesion layer inserted between $SiO_2$ and W layers. Due to the post- annealing, the return loss ($S_{11}$) and series/parallel quality factor are significantly improved when compared with the non-post annealing. This post-annealing method seems to be a very efficient way to improve the resonance characteristics of FBAR devices.

Distributions and Correlation of Heavy Metals Sediment, Soil, Weeds and Vegetables on Lower Nakdong River (낙동강 하류 유역의 저니토, 토양, 잡초 및 채소 중의 중금속의 분포와 상관관계)

  • Jeong, Gi-Ho;Kim, Moon-Soon;Jeong, Jong-Hak
    • Journal of Environmental Science International
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    • v.5 no.6
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    • pp.801-812
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    • 1996
  • We investigated concentrations of heavy metals(Cr, Cd, Zn, Fe, Pb, Cu, and Mnl and correlations between concentrations of heavy metals in the sediment, soil, weeds, and vegetables on the lower Nakdong river. Concentrations of heavy metals on the lower Milyang river was generally lower than those of other sampling area. In the soil, concentration of Pb is generally larger than that of other heavy metals. Generally, concentrations of heavy metals in the sediment show decreasing tendency 8s the sampling area moves toward downstream of the river, but those of in the soil and weeds show increasing tendency. There is no significant correlation between concentration of heavy metals in the soil-sediment, soil-vegetables, sediment-weeds, or vegetables-weeds. Only concentrations of Pb in the vegetables and those of in the weeds show very high correlation.

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