• Bulletin of the Korean Chemical Society
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• 제16권11호
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• pp.1109-1112
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• 1995

Bis(silyl)alkylbenzenes such as bis(1-sila-sec-butyl)benzene (1) and 2-phenyl-1,3-disilapropane (2) were prepared in high yields by reduction of the corresponding chlorosilanes with LiAlH4. The dehydropolymerization of 1 and 2 was carried out with group 4 metallocene complexes generated in situ from Cp2MCl2/Red-Al and Cp2MCl2/n-BuLi (M=Ti, Hf), producing two phases of polymers. The TGA residue yields of the insoluble polymers were in the range of 64-74%. The molecular weights of the soluble polymers produced ranged from 700 to 5000 (Mw vs polystyrene) and from 500 to 900 (Mn vs polystyrene). The dehydropolymerization of 1 and 2 seemed to initially produce a low-molecular-weight polymer, which then underwent an extensive cross-linking reaction of backbone Si-H bonds, leading to an insoluble polymer.

• Journal of Welding and Joining
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• 제30권2호
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• pp.70-75
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• 2012

In this study, effect of nitrogen volume in the shielding gas of Ar-$N_2$ mixing gas on the bead shape, hardness and microstructure of GTA welds of 3mm thick Commercial Pure Ti was investigated. As the nitrogen volume increased, the welding current for full penetration was reduced and hardness in the fusion zone significantly increased compared with that of the base metal, but there is no difference in the hardness of HAZ. Microstructure in the fusion zone with pure Ar gas changed from equiaxed alpha of the base metal to serrated alpha. On the other hand, microstructure using Ar-$N_2$ mixing gas changed to acicular alpha. With the increasing of nitrogen content, the amount of acicular alpha increased and the size of that was fine.

• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.233-237
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• 2005

Cyclopentadiene compounds, 2-[CR'R(OMe)]-1,3-Me$_2C_5H_3$ (R, R' = 2,2'-biphenyl, 2) and 2-[CR'R(OSiMe$_3$)]-1,3-Me$_2C_5H_3$ (R, R' = 2,2'-biphenyl, 3; R = ph, R' = ph, 4; R = 2-naphthyl, R' = H, 5) are readily synthesized from 2-bromo-3-methoxy-1,3-dimethylcyclopentene (1). Reaction of the cyclopentadienes with Ti(NMe$_2$)$_4$ in toluene results in clean formation of the cyclopentadienyl tris(dimethylamido)titanium complexes, which are transformed to the trichloride complexes, 2-[CR'R(OMe)]-1,3-Me$_2C_5H_2$}TiCl$_3$ (R, R' = 2,2'-biphenyl, 6) and {2-[CR'R(OSiMe$_3$)]-1,3-Me$_2C_5H_2$}TiCl$_3$ (R, R' = 2,2'-biphenyl, 7; R = ph, R' = ph, 8; R = 2-naphthyl, R' = H, 9). Attempts to form C1-bridged Cp/oxido complexes by elimination of MeCl or Me$_3$SiCl were not successful. X-ray structures of 6, 7 and an intermediate complex {2-[Ph$_2$C(OSiMe$_3$)]-1,3-Me$_2C_5H_2$}TiCl$_2$(NMe$_2$) (10) were determined.

• 한국염색가공학회지
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• 제33권4호
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• pp.238-249
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• 2021

In this study, the effect on flame retardancy and various physical properties when TiO₂ was added with a citric acid/phosphate complex acid catalyst together with Pyrovatex CP new (N-methylol dimethylphosphonopropionamide), a phosphorus-based flame retardant, was studied on cotton fibers. SEM-EDS analysis was performed to confirm the surface characteristics and surface element analysis of the flame-retardant treated cotton fibers, and a vertical carbonization test was performed to confirm the char formation capability and flame retardancy according to the phosphoric acid ratio. By comparing the LOI index before and after washing 10 times, the washing durability of the flame retardant solution containing the phosphoric acid catalyst and TiO₂ was tested by LOI index after ten washing cycles. In addition, the influence of the flame-retardant processing on the physical properties were compared including thermogravimetric analysis (TGA), tear strength and whiteness.

• 한국세라믹학회지
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• 제39권5호
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• pp.460-466
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• 2002

티타늄 임플란트의 표면을 열산화법을 이용하여 티타늄의 표면 위에 생체활성을 갖는 $TiO_2$ 박막을 생성시켜 다양한 의료분야의 응용 가능성을 검토하였다. 시판되고 있는 순수한 티타늄 디스크를 세척 공정을 거친 후, 공기와 아르곤 분위기에서 500, 550, 600, 650, 700${\circ}C$의 온도로 10분간 각각 열산화 처리를 실시하였다. 열처리된 시편의 인산칼슘 결정의 형성 능력을 시험하기 위하여 36.5${\circ}C$의 Eagle's minimum essential medium 용액에서 15일 동안 침적시험을 행하였다. 침적하기 전과 후의 시편의 표면 형상과 표면 조성을 Field Emission-Scanning Electron Microscopy(FE-SEM)와 Energy Dispersive X-ray Spectrometry(EDS)로 각각 분석하였다. In vitro 시험에서 미세한 $TiO_2$ 결정이 생성된 박막의 표면에는 탄소가 함유된 인산칼슘 결정이 생성됨을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제26권10호
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• pp.1620-1622
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• 2005

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.199-199
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• 2016

Commercially pure titanium (cp-Ti) and Ti alloys (typically Ti-6Al-4V) display excellent corrosion resistance and biocompatibility. Although the chemical composition and topography are considered important, the mechanical properties of the material and the loading conditions in the host have, conventionally. Ti and its alloys are not bioactive. Therefore, they do not chemically bond to the bone, whereas they physically bond with bone tissue. The electrochemical deposition process provides an effective surface for biocompatibility because large surface area can be served to cell proliferation. Electrochemical deposition method is an attractive technique for the deposition of hydroxyapatite (HAp). However, the adhesions of these coatings to the Ti surface needs to be improved for clinical used. Plasma electrolyte oxidation (PEO) enables control in the chemical com position, porous structure, and thickness of the $TiO_2$ layer on Ti surface. In addition, previous studies h ave concluded that the presence of $Ca^{+2}$ and ${PO_4}^{3-}$ ion coating on porous $TiO_2$ surface induced adhesion strength between HAp and Ti surface during electrochemical deposition. Silicon (Si) in particular has been found to be essential for normal bone and cartilage growth and development. Zinc (Zn) plays very important roles in bone formation and immune system regulation, and is also the most abundant trace element in bone. The objective of this work was to study electrochemical characteristcs of Zn and Si coating on Ti-6Al-4V by PEO treatment. The coating process involves two steps: 1) formation of porous $TiO_2$ on Ti-6Al-4V at high potential. A pulsed DC power supply was employed. 2) Electrochemical tests were carried out using potentiodynamic and AC impedance methoeds. The morphology, the chemical composition, and the micro-structure an alysis of the sample were examined using FE-SEM, EDS, and XRD. The enhancements of the HAp forming ability arise from $Si/Zn-TiO_2$ surface, which has formed the reduction of the Si/Zn ions. The promising results successfully demonstrate the immense potential of $Si/Zn-TiO_2$ coatings in dental and biomaterials applications.

• 한국표면공학회지
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• 제48권2호
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• pp.38-42
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• 2015

Atomic layer deposition (ALD) is essential for the fabrication of nanoscale electronic devices because it has excellent conformality, atomic scale thickness control, and large area uniformity. Metal thin films are one of the important material components for electronic devices as a conductor. As the size of electronic devices shrinks, the thickness of metal thin films is decreased down to few nanometers, and the metal films become non-continuous due to inherent island growth of metal below a critical thickness. So, fabrication of continuous metal thin films by ALD is fundamentally and practically important. Since ALD films are grown through self-saturated reactions between precursors on surface, initial growth characteristics significantly depend on the surface properties and the selection of precursors. In this work, we investigated ALD Pt on $TiO_2$ substrate by using trimethyl-methyl-cyclopentadienyl-Platinum ($MeCpPtMe_3$) precursor and $O_3$ reactant. By using $O_3$ instead of $O_2$, initial nucleation rate of ALD Pt was increased on $TiO_2$ surface, resulting in formation of continuous thin Pt films. Morphologies of ALD Pt on $TiO_2$ were characterized by using Scanning Electron Microscope (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS). Crystallinity of ALD Pt on $TiO_2$ correlated with its growth characteristics was analyzed by X-Ray Diffraction (XRD).

• 한국분말재료학회지
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• 제18권6호
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• pp.488-495
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• 2011

This study was performed to fabricate the porous titanium foam by space holder method using NaCl powder, and to evaluate the effect of NaCl volume fractions (33.3~66.6 vol.%) on the porosities, compressive strength, Young's modulus and permeability. For controlling pore size, CP titanium and NaCl particles were sieved to different size range of 70~150 ${\mu}m$ and 300~425 ${\mu}m$ respectively. NaCl of green Ti compact was removed in water followed by sintered at $1200^{\circ}C$ for 2 hours. Total porosities of titanium foam were in the range of 38-70%. Pore shape was a regular hexahedron similar that of NaCl shape. Porous Ti body showed that Young's modulus and compressive strength were in the range of 0.6-6 GPa and 8-127 MPa respectively. It showed that pore size and mechanical properties of Ti foams was controllable by NaCl size and volume fractions.

• 대한금속재료학회지
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• 제50권2호
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• pp.176-182
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• 2012

The main purpose of this study was to evaluate the endurance against Al alloy melts and wear resistance of an in-situ synthesized titanium matrix composite (TMC) sleeve for aluminum alloy die-casting. The conventional die-casting shot sleeve material was STD61 tool steel. TMCs have great thermal stability, wear and oxidation resistance. The in-situ reaction between Ti and $B_4C$ leads to two kinds of thermodynamically stable reinforcements, such as TiBw and TiCp. To evaluate the feasibility of the application to a TMCs diecasting shot sleeve, the interfacial reaction behavior was examined between Al alloys melts with TMCs and STD61 tool steel. The pin-on-disk type dry sliding wear test was also investigated for TMCs and STD61 tool steel.