• Title/Summary/Keyword: Coupling Agent

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A Study on Particle Size with Polymerization Factor in Dispersion Copolymerization of Styrene/n-Butylmethacrylate and Alumina (스티렌/노말 부틸 메타크릴레이트와 알루미나의 분산 공중합에서 중합인자에 따른 입경변화 연구)

  • Bang, Hyun-Su;Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.230-240
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    • 2008
  • In order to synthesize polymer particle containing inorganic material, styrene and nbutylmetacrylate were copolymerized with alumina by dispersion polymerization. The ratio in weight of styrene to n-butyl methacrylate was 3:1. Poly(N-vinyl pyrrolidon) and 2,2'-azobis(isobutyronitrile) were added as stabilizer and as initiator, respectively. The change of particle size was investigated with concentration of initiator, the type of medium, the mixed solubility parameter (${\delta}_{mix}$) of medium, and coupling agent. The enhancement in concentration of initiator resulted in slight increase of particle size. The increase of polarizability in medium also yielded the increase of particle size. In case of changing the ratio of isopropanol to distilled water, we could find relationship of $[{\delta}_{mix}]^{-4.01}\;{\propto}$ particle size and $[{\delta}_{mix}]^{-0.83}\;{\propto}$ particle size distribution(PSD). The type and the concentration of coupling agent showed no effect on the particle size and PSD.

Surface and Chemical Properties of Surface-Modified UHMWPE Powder and Mechanical and Thermal Properties of Its Impregnated PMMA Bone Cement V. Effect of Silane Coupling Agent on the Surface Modification of UHMWPE Powder

  • Yang Dae Hyeok;Yoon Goan Hee;Shin Gyun Jeong;Kim Soon Hee;Rhee John M.;Khang Gilson;Lee Hai Bang
    • Macromolecular Research
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    • v.13 no.2
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    • pp.120-127
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    • 2005
  • Conventional poly(methyl methacrylate) (PMMA) bone cement has been widely used as an useful biopolymeric material to fix bone using artificial prostheses. However, many patients had to be reoperated, due to the poor mechanical and thermal properties of conventional PMMA bone cement, which are derived from the presence of unreacted MMA liquid, the shrinkage and bubble formation that occur during the curing process of the bone cement, and the high curing temperature ($above 100^{\circ}C$) which has to be used. In the present study, a composite PMMA bone cement was prepared by impregnating conventional PMMA bone cement with ultra high molecular weight polyethylene (UHMWPE) powder, in order to improve its mechanical and thermal properties. The UHMWPE powder has poor adhesion with other biopolymeric materials due to the inertness of the powder surface. Therefore, the surface of the UHMWPE powder was modified with two kinds of silane coupling agent containing amino groups (3-amino propyltriethoxysilane ($TSL 8331^{R}$) and N-(2-aminoethyl)-3-(amino propyltrimethoxysilane) ($TSL 8340^{R}$)), in order to improve its bonding strength with the conventional PMMA bone cement. The tensile strengths of the composite PMMA bone cements containing $3 wt\%$ of the UHMWPE powder surface-modified with various ratios of $TSL 8331^{R}$ and $TSL 8340^{R}$ were similar or a little higher than that of the conventional PMMA bone cement. However, no significant difference in the tensile strengths between the conventional PMMA bone cement and the composite PMMA bone cements could be found. However, the curing temperatures of the composite PMMA bone cements were significantly decreased.

Effect of pMDI as Coupling Agent on The Properties of Microfibrillated Cellulose-reinforced PBS Nanocomposite (pMDI 커플링제가 마이크로피브릴 셀룰로오스 강화 PBS 나노복합재료의 성질에 미치는 영향)

  • Jang, Jae-Hyuk;Lee, Seung-Hwan;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.483-490
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    • 2014
  • The effect of microfibrillated cellulose (MFC) content and coupling agent (polymeric methylene diphenyl diisocyanate, pMDI) on the properties of MFC-reinforced polybutylene succinate (PBS) nanocomposite. With increasing MFC content, tensile strength and elastic modulus were increased. More than 1.5 times in tensile strength of PBS/MFC(70/30) nanocomposite was improved by the addition of pMDI (1 phr), compared to the nanocomposite without pMDI. This trend was being significant in nanocomposite with higher MFC content. Thermal stability of the nanocomposite was increased by the addition of pMDI. These improvements is considered to be due to the improvement of MFC dispersion and interfacial adhesion between MFC and PBS matrix.

Effects of Process Variables and MAPP Coupling Agent on Properties of Wood Fiber-Polypropylene Fiber Composite by Turbulent Air Mixing (공정변수(工程變數)와 MAPP 결합제(結合劑)가 난기류(亂氣流) 혼합방식(混合方式)에 의하여 제조(製造)된 목섬유(木纖維)-폴리프로필렌섬유(纖維) 복합재(複合材)의 성질(性質)에 미치는 영향(影響))

  • Yoon, Hyoung-Un;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.1
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    • pp.76-86
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    • 1998
  • Effects of processing variables and MAPP (maleic anhydride polypropylene) coupling agent on the properties of composite were discussed for turbulent-air-mixed woodfiber-polypropylenefiber composites. In this research, density, composition ratio, and mat moisture content were established as processing variables, and emulsified MAPP prepared by direct pressure method was incorporated as the coupling agent. And the turbulent air mixer, which was improved in function through alteration of our previous fiber mixer, was used to mix wood fibers and polypropylene fibers. At the addition level of 1% MAPP, based on oven-dried wood fiber weight, woodfiber-polypropylenefiber composites generally showed enhanced the physical and mechanical properties. And composites with low to medium densities of 0.6 to 0.8g/$cm^3$ greatly increased in these property values than with high densities of 1.0g/$cm^3$ or more by adding 1 % MAPP. Thus, MAPP addition was thought to be an effective way of enhancing properties for nonwoven web composites. At the mat moisture contents of 5 to 20%, however, the physical and mechanical properties were not enhanced by adding 1% MAPP. In the composites containing 15% polypropylene fibers, the lowest thickness swelling and water absorption values were observed at the 1% MAPP level. The addition of more than 1% MAPP had the adverse effect on the physical and mechanical properties of composites.

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Improvement of Tensile Strength of Polyester Resin Using Silica/Chopped Glass Fiber Modified by Coupling Agent (실란 처리된 실리카 및 절단 유리섬유에 의한 폴리에스테르 수지의 인장강도 향상)

  • Lee, Jeon-Kyu;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.30-34
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    • 2012
  • For the purpose of development of polymeric material for marine applications, the effects of silica and chopped glass fiber on tensile strength of polyester resin were studied. A series of experiments were performed with different contents of silica and chopped glass fiber. Tensile strength of polyester resin was increased with the contents of unmodified glass fiber, and decreased with that of silica. The surfaces of silica and chopped glass fiber were modified with coupling agent at different concentrations, and the modification showed positive effect on the increase of tensile strength of polyester resin. Synergistic effect on the tensile strength of polyester resin was observed by modified silica and chopped glass fiber.

Modeling and coupling characteristics for an airframe-propulsion-integrated hypersonic vehicle

  • Lv, Chengkun;Chang, Juntao;Dong, Yilei;Ma, Jicheng;Xu, Cheng
    • Advances in aircraft and spacecraft science
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    • v.7 no.6
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    • pp.553-570
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    • 2020
  • To address the problems caused by the strong coupling of an airbreathing hypersonic vehicle's airframe and propulsion to the integrated control system design, an integrated airframe-propulsion model is established, and the coupling characteristics between the aircraft and engine are analyzed. First, the airframe-propulsion integration model is established based on the typical nonlinear longitudinal dynamical model of an air-breathing hypersonic vehicle and the one-dimensional dual-mode scramjet model. Thrust, moment, angle of attack, altitude, and velocity are used as transfer variables between the aircraft model and the engine model. The one-dimensional scramjet model can accurately reflect the working state of the engine and provide data to support the coupling analysis. Second, owing to the static instability of the aircraft model, the linear quadratic regulator (LQR) controller of the aircraft is designed to ensure attitude stability and height tracking. Finally, the coupling relationship between the aircraft and the engine is revealed through simulation examples. The interaction between vehicle attitude and engine working condition is analyzed, and the influence of vehicle attitude on engine safety is considered. When the engine is in a critical working state, the attitude change of the aircraft will not affect the engine safety without considering coupling, whereas when coupling is considered, the attitude change of the aircraft may cause the engine unstart, which demonstrates the significance of considering coupling characteristics.