• Title/Summary/Keyword: Counter-ion

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Improvement of ESD (Electrostatic Discharge) Protection Performance of NEDSCR (N-Type Extended Drain Silicon Controlled Rectifier) Device using CPS (Counter Pocket Source) Ion Implantation (CPS 이온주입을 통한 NEDSCR 소자의 정전기 보호 성능 개선)

  • Yang, Jun-Won;Seo, Yong-Jin
    • Journal of Satellite, Information and Communications
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    • v.8 no.1
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    • pp.45-53
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    • 2013
  • An electrostatic discharge (ESD) protection device, so called, N-type extended drain silicon controlled rectifier (NEDSCR) device, was analyzed for high voltage I/O applications. A conventional NEDSCR device shows typical SCR-like characteristics with extremely low snapback holding voltage. This may cause latch-up problem during normal operation. However, a modified NEDSCR device with proper junction/channel engineering using counter pocket source (CPS) ion implantation demonstrates itself with both the excellent ESD protection performance and the high latch-up immunity. Since the CPS implant technique does not change avalanche breakdown voltage, this methodology does not reduce available operation voltage and is applicable regardless of the operation voltage.

Enhancement of Performance of Dye-Sensitized Solar Cell by Reducing the Interface Resistance (계면저항 감소를 통한 염료감응형 태양전지 성능 향상)

  • Kim, Hwi-Dong;Kim, Ki-Hoon;Ahn, Ji-Young;Kim, Soo-Hyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.360-363
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    • 2009
  • In order to improve the overall power conversion efficiency, it is very important to reduce the interface resistance of dye-sensitized solar cells (DSSCs). In this approach, tiny $TiO_2$ nanoparticles with the primary size of 10~20nm were synthesized and deposited between FTO glass and preformed $TiO_2$ layer by $TiOCl_2$ treatment, and also Pt catalysts were deposited on the counter electrode by both ion-sputter and thermal deposition to reduce the electrolyte-counter electrode interface resistance. The influence of these processes on the performace of DSSCs were discussed in terms of fill factor, short circuit current, and conversion efficiency.

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The Influence of Simple Electrolyte on the Behaviour of Some Acid Dyes in Aqueous Media

  • M. M. El-Fass;N. A. Badawy;A. A. El-Bayaa;N. S. Moursy
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.458-461
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    • 1995
  • The influence of adding counter-ion such as Na+ on the dimerization of the two sulphonated azo dyes, C.I. Acid Red 14 and C.I. Acid Red 17 in aqueous media has been studied spectrophotometrically. The observed hypochromic effect on increasing the amount of salt has been described. The dye concentration range where the dimerization equilibrium is applicable was chosen. No metachromatic behaviour was observed on changing the dye concentration and the amount of salt. This behaviour was attributed to the ability of the counter-ion to disrupt the structure of water as well as reducing the electrostatic repulsion forces between dye anions which will lead to the increase of aggregation tendency of the dye species.

Study on electrical charge distribution of aerosol using a Gerdien ion counter (Gerdien 이온측정기를 이용한 에어로졸의 하전 특성 분석에 관한 연구)

  • Joe, Yun-Haeng;Shim, Joonmok;Shin, Il-Kyoung;Yook, Se-Jin;Park, Hyun-Seol
    • Particle and aerosol research
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    • v.14 no.1
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    • pp.17-24
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    • 2018
  • Since the motion of the charged particle strongly depends on its charge characteristics, information on charge distributions of target particles is one of the important variables in aerosol research. In this study, charged distribution of atomized NaCl particles were measured using a Gerdien type ion counter. Two kinds of particle charging conditions were used in this study. First, atomized NaCl particles were passed through an aerosol neutralizer to have a Boltzmann charge distribution, and then its charge distribution was measured. In this case, the portion of uncharged particles was compared with the portion obtained from the Boltzmann charge distribution for verifying the suggested experimental method. Second, same experiment was conducted without the aerosol neutralizer to measure the charge distribution of atomized and un-neutralized NaCl particles. In the conclusion, the portion of uncharged, negatively charged and positively charged particles were 19%, 62% and 20%, respectively, for neutralized particles. The atomized particles, which was generated without the aerosol neutralizer, also had almost a zero charge state, but the standard deviation in charge distribution was larger than that of neutralized particles. The test method proposed in this study is expected to be used in various aerosol research fields because it can obtain simple information on the particle charge characteristics more easily and quickly than the existing test methods.

Determination of Total Glycyrrhetic Acid in Glycyrrhizae Radix by Second Derivative UV Spectrometry

  • Song, Seung-Bae;Choi, Jung-Kap;Yoo, Gyurng-Soo
    • Archives of Pharmacal Research
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    • v.13 no.2
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    • pp.174-179
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    • 1990
  • Second derivative (D2) spectrometry using ion-pair extraction technique was development for the determination of total glycyrrhetic acid (GA) in Glycyrrhizae Radix, Glycyr-rhizin (G) obtained from Glycyrrhizae Radix was hydrolyzed into GA in 2 N-HCI and methanol (1:1) and extracted from aqueous phase in the form of an ion-pair complex with tetrapentylammonium bromide (TPA) as a counter ion. Maximum D2 amplitude (Z value) was obtained when 1000-fold or greater molar ratio of TPA was used at pH 11. Reaction an effective extraction solvent of the ion-pair complex. The linearity of standard curve of ion-pair GA was obtained in the range of 4.120 $\mu$g/ml as GA. Assayed contents of GA in dry powder by D2 UV spectrometry and HPLC method were 5.31 $\pm$ 0.04% and 5.20 $\pm$ 0.008%, respectively.

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Analysis of Kasugamycin in Pesticide Formulations by Reversed-Phase Ion Pair Liquid Chromatography (역상 이온쌍 액체크로마토그래피에 의한 농약 제품 중 Kasugamycin의 분석)

  • Kim, Taek-Jae;Kim, Kyong-Sun;Yoon, Chae-Hyuk;Joo, Jin-Bok;Kim, Chung-Hyo
    • Analytical Science and Technology
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    • v.10 no.5
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    • pp.343-349
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    • 1997
  • Analytical method using the reversed phase ion-pair chromatography (RP-IPC) for the determination of kasugamycin(5-amino-2-methyl-6-(2,3,4,5,6-pentahydroxy cyclohexyloxy)tetrahydropyran-3-yl-amino-${\alpha}$-imino acetic acid), pesticide as fungicide bactercide has been established. The retention behavior of kasugamycin in the RP-IPC was examined with respect to the effect of concentrations of organic modifiers, pH of eluent and types and concentrations of the counter ions as ion-pair reagent. This method developed by the optimum factors, can be used for the application of the quality control in the crude product and its formulation.

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Extraction Equilibria and Solvent Sublation for Determination of Ultra Trace Bi(Ⅲ), In(Ⅲ) and TI(Ⅲ) in Water Samples by Ion-Pairs of Metal-2-Naphthoate Complexes and Tetrabutylammonium Ion

  • Kim, Young-Sang;Choi, Yoon-seok;Lee, Won
    • Bulletin of the Korean Chemical Society
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    • v.23 no.10
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    • pp.1381-1391
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    • 2002
  • The solvent sublation using ion pairs of metal-2-naphthoate(2-HNph) and tetrabutyl ammonium ($TBA^+$) ion has been studied for the concentration and determination of ultra trace Bi(III), In(III) and Tl(Ⅲ) ions in water samples. The partition coefficients ($K_p$) and the extraction percentages of 2-HNph and the ion pairs to methyl isobutyl ketone (MIBK) were obtained as basic data. After the ion pair $TBA^+$·M$(Nph)_4^-$ was formed in water samples, the analytes were concentrated by the solvent sublation and the elements were determined by GF-AAS. The pH of the sample solution, the amount of the ligand and counter ion added and stirring time were optimized for the efficient formation of the ion pair. The type and amount of optimum surfactant, bubbling time with nitrogen and the type of solvent were investigated for the solvent sublation as well. 10.0 mL of 0.1 M 2-HNph and 2.0 mL of 0.1 M $TBA^+$ were added to a 1.0 L sample solution at pH 5.0. After 2.0 mL of 0.2%(w/v) Triton X-100 was added, the ion pairs were extracted into 20.0 mL MIBK in a flotation cell by bubbling. The analytes were determined by a calibration curve method with measured absorbances in MIBK, and the recovery was 80-120%.

Recent Developments in Characterization of Ion-Exchange Membrane Processes: Impedance Spectroscopy for a Concentration Polarized Boundary Layer

  • Park, Jin-Soo;Moon, Seung-Hyeon
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.03a
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    • pp.1-11
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    • 2004
  • Ion-exchange membranes have been widely used in various applications such as diffusion dialysis, electrolysis, electrodialysis, fuel cell etc [1-2]. When an electric current passes through the membrane system, the current is carried by both positive and negative ions in the bulk solution phases, whereas it is carried mainly by the counter-ions in the membrane. (omitted)

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Characteristics of Selectivity in Anion Exchanges (음이온 선택도 특성)

  • 이석중;안현경;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.3
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    • pp.194-197
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    • 2002
  • Ion exchange is a chemical reaction between the ions in solution phase and ions in solid phase and is widely used in softening, demineralization, removal and collection of specific ions, and ion migration in the ground water. The ion selectivity depends on the charge and the hydrated radius of ion. The objective of this study was to examine the applicability of anion selectivity obtained from the ion exchange equilibrium OH/sup -/ < F/sup -/ < HCO/sup -/ < Cl/sup -/ < Br/sup -/ ≤ NO₃/sup -/ < SO₄/sup 2-/ to the column ion exchange. The column ion exchange was facilitated in the lower charge of counter-ion in the background electrolyte.

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Effect of True Partition Coefficient on the Determination of Extraction Coefficient of Ion-Pair Complexes (이온대 화합물의 참분배계수가 축출정수 결정에 미치는 영향)

  • 심창구
    • YAKHAK HOEJI
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    • v.27 no.2
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    • pp.125-131
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    • 1983
  • Whether ($AB_{w}$) may be neglected against ($A_{w}^{+}$) in the calculation of the extraction coefficient of ion-pairs was criticized by both experiments and theoretical consideration, where ($AB_{w}$) and ($A_{w}^{+}$) mean the molar concentration of ion-pair AB and cation $A^{+}$ in the aqueous phase. Ion-pair complexes were partitioned between phosphate buffer (pH 7.4) and n-octanol. Tetrabutylammonium, isopropamide and methylene blue were selected as cations and benzoic acid, p-toluenesulfonic acid, salicylic acid and taurodeoxycholic acid were selected as counter ions (anions). As a result, conventional methods which assume no existence of ($AB_{w}$) were proven to lack generality. The equation proposed in my earlier report was confirmed to be valid as a general method.

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