• Computers and Concrete
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• v.26 no.4
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• pp.367-375
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• 2020

Today, the use of special technologies in the admixture of concrete has made tremendous progress, but the problem that has always existed in the construction of concrete members is the brittleness and lack of loading bearing after cracking, which leads to reduced strength and energy absorption. One of the best ways to fix this is to reinforce the concrete with steel fibers. Steel fibers also control cracks due to dry shrinkage, reduce structural crack width, and improve impact resistance. In this study, recycled steel fibers from worn tires have been used in the manufacture of concrete samples, the secondary benefits of which are the reduction of environmental pollution. One of the disadvantages of steel fiber reinforced concrete is the corrosion of steel fibers and their deterioration in harsh environments such as coastal areas. Corrosion caused by chlorine ions in metal fibers causes deterioration and early decommissioning of structures in corrosive environments. In this study, the effect of the dosage of steel fibers (dosages of 15, 30, and 45 kg of fibers per cubic meter of concrete) and aspect ratio of fibers (aspect ratio of 25 and 50) on compressive and flexural strength of concrete samples are investigated. In the following, the effect of fiber corrosion on the results of the mechanical properties of concrete samples is examined. The results show that the increase in fiber causes a relative increase in compressive strength, and a significant increase in flexural strength, and corrosion of steel fibers without reducing workability reduces compressive strength and flexural strength by up to 6 to 11%, respectively.

• Corrosion Science and Technology
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• v.13 no.5
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• pp.178-185
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• 2014

Alloy 617 is considered as a candidate Ni-based superalloy for the intermediate heat exchanger (IHX) of a very high-temperature gas reactor (VHTR) because of its good creep strength and corrosion resistance at high temperatures. Helium is used as a coolant in a VHTR owing to its high thermal conductivity, inertness, and low neutron absorption. However, helium inevitably includes impurities that create an imbalance in the surface reactivity at the interface of the coolant and the exposed materials. As the Alloy 617 has been exposed to high temperatures at $950^{\circ}C$ in the impure helium environment of a VHTR, the degradation of material is accelerated and mechanical properties decreased. The high-temperature strength, creep, and corrosion properties of the structural material for an IHX are highly important to maintain the integrity in a harsh environment for a 60 year period. Therefore, an alloy superior to alloy 617 should be developed. In this study, the mechanical and high-temperature corrosion properties for Ni-Cr alloys fabricated in the laboratory were evaluated as a function of the grain boundary strengthening and alloying elements. The ductility increased and decreased by increasing the amount of Mo and Cr, respectively. Surface oxide was detached during the corrosion test, when Al was not added to alloy. However the alloy with Al showed improved oxide adhesive property without significant degradation and mechanical property. Aluminum seems to act as an anti-corrosive role in the Ni-based alloy.

• Korean Journal of Materials Research
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• v.15 no.3
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• pp.155-160
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• 2005

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is very corrosive fir typical structural materials. So, it is essential to choose the optimum material f3r the process equipment handling molten salt. In this study, the corrosion behavior of Al-Y coated Haynes 263 in a molten salt of $LiCl-Li_2O$ under oxidation atmosphere was investigated at $650^{\circ}C$ for $72\~168$ hours. The corrosion rate of Al-Y coated Haynes 263 was low while that of bare Haynes 263 was high in a molten salt of $LiCl-Li_2O$. Al-Y coated Haynes 263 improved the corrosion resistance better than bare Haynes 263 alloy. An Al oxide layer acts as a protective film which Prohibits Penetration of oxygen. Corrosion Products were formed $Li(Ni,Co)O_2$ and $LiTiO_2$ on bare Haynes 263, but $LiAlO_2,\;Li_5Fe_5O_8\;and\;LiTiO_2$ on Al-Y coated Haynes 263.

• Korean Journal of Materials Research
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• v.16 no.9
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• pp.557-563
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• 2006

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, MA 754, X-750 and 718 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for $72{\sim}216$ hours. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3,\;NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3\;and\;Li_2Ni_8O_{10}$ while $Cr_2O_3,\;NiFe_2O_4\;and\;CrNbO_4$ were produced from Inconel 718. Also, corrosion products of Inconel X-750 were found to be $Cr_2O_3,\;NiFe_2O_4\;and\;(Cr,Nb,Ti)O_2$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, 718, X-750 showed uniform corrosion behavior.

• Composites Research
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• v.25 no.2
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• pp.46-53
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• 2012

Using pultrusion process, FRP composite structural members having various cross-section shapes can be produced with unlimited lengths. Because of such reasons, these members are suitable for the application in the construction field. Especially, this material is highly appreciated if the material is to be used in the corrosive environments such as aquatic or oceanic environments due to its high corrosion resistance. However, design criteria for the FRP structural member are not developed yet. So, the research on the development of design guideline is needed ungently. In order to use the pultruded structural FRP member efficiently, the members are composed of thin plate components, and thus, the member is prone to buckle easily and the buckling is one of the governing strength limit states for the design. In this paper, we present the analytical study results pertaining to the buckling behavior of I-shape FRP compression member. In addition, design procedure and flow-chart are also proposed based on the study results including previous experimental results. Proposed design procedure is similar to that in ANSI/AISC 360-10 with minor modification. Therefore, it is convinced that the structural design of pultruded FRP compression member could be done easily by following design procedure proposed in this paper.

• Korean Journal of Materials Research
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• v.17 no.7
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• pp.366-370
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• 2007

Silicon nitride ($Si_3N_4$) ceramics have been considered for various components of nuclear power plants such as the mechanical seal of a reactor coolant pump (RCP), the guide roller for a control rod drive mechanism (CRDM), and a seal support, etc. Corrosion behavior of $Si_3N_4$ ceramics in a high-temperature and high-pressure water must be elucidated before they can be considered as components for nuclear power plants. In this study, the corrosion behaviors of $Si_3N_4$ ceramics containing MgO and $Al_2O_3$ as sintering aids were investigated at a hydrothermal condition ($300^{\circ}C$, 9.0 MPa) in pure water and 35 ppm LiOH solution. The corrosion reactions were controlled by a diffusion of the reactive species and/or products through the corroded layer. The grain-boundary phase was preferentially corroded in pure water whereas the $Si_3N_4$ grain seemed to be corroded at a similar rate to the grain-boundary phase in LiOH solution. Flexural strengths of the $Si_3N_4$ ceramics were significantly degraded due to the corrosion reaction. Results of this study imply that a variation of the sintering aids and/or a control (e.g., crystallization) of the grain-boundary phase are necessary to increase the corrosion resistance of $Si_3N_4$ ceramics in a high-temperature water.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.5
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• pp.1-7
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• 2008

A study of new materials that are light-weight, high in strength has become vital to the machinery of auto industries. But then, there are a lot of problems with developing such materials that require expensive tools, and a great deal of time and effort. Therefore, the improvement of fatigue strength and fatigue life are mainly focused on by adopting residual stress. And Influence of corrosive condition for corrosion fatigue crack was investigated, after immersing in 3.5%NaCl, $10%HNO_3$+3.5%HF, $6%FeCl_3$. The immersion period was performed for 365days. The compressive residual stress was imposed on the surface according to each shot velocity based on shot peening, which is the method of improving fatigue life and strength. Fatigue life shows more improvement in the shot peened material than in the un peened material in corrosion conditions. The threshold stress intensity factor range was decreased in corrosion environments over ambient. Compressive residual stress of surface on the Shot-peen processed operate resistance force of fatigue crack propagation. The fatigue crack growth rate of the Shot-peened material was lower than that of the un peened material. Also m, fatigue crack growth exponent and number of cycle of the shot peened material was higher than that of the un peened material. That is concluded from effect of da/dN.

• Korean Journal of Materials Research
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• v.28 no.5
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• pp.286-294
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• 2018

Hot-press forming(HPF) steel can be applied successfully to auto parts because of its superior mechanical properties. However, its resistances to aqueous corrosion and the subsequent hydrogen embrittlement(HE) decrease significantly when the steel is exposed to corrosive environments. Considering that the resistances are greatly dependent on the properties of coating materials formed on the steel surface, the characteristics of the corrosion and hydrogen diffusion behaviors regarding the types of coating material should be clearly understood. Electrochemical polarization and impedance measurements reveal a higher corrosion potential and polarization resistance and a lower corrosion current of the Al-coating compared with Zn-coating. Furthermore, it was expected that the diffusion kinetics of the hydrogen atoms would be much slower in the Al-coating, and this would be due mainly to the much lower diffusion coefficient of hydrogen in the Al-coating with a face-centered cubic structure. The superior surface inhibiting effect of the Al-coating, however, is degraded by the formation of local cracks in the coated layer under severe stress conditions, and therefore further study will be necessary to gain a clearer understanding of the effect of cracks formed on the coated layer on the subsequent corrosion and hydrogen diffusion behaviors.

• Nuclear Engineering and Technology
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• v.34 no.1
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• pp.42-59
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• 2002

In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

• Korean Journal of Metals and Materials
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• v.46 no.9
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• pp.577-584
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• 2008

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, Inconel MA 754, Nimonic 80A and Nimonic 90 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for 72~216 hrs. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3$, $NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3$ and $Li_2Ni_8O_{10}$ while $Cr_2O_3$, $LiFeO_2$, $(Cr,Ti)_2O_3$ and $Li_2Ni_8O_{10}$ were produced from Nimonic 80A. Also, corrosion products of Nimonic 90 were found to be $Cr_2O_3$, $(Cr,Ti)_2O_3$, $LiAlO_2$ and $CoCr_2O_4$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, Nimonic 80A, Nimonic 90 showed uniform corrosion behavior.