• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
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• pp.983-988
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• 2000

Anchoring systems with structural stability and endurance have been one of the most important elements for PSC structures, especially for the structures using non-corrosive FRP tendons. FRP tendons are in increasing use for underground and coastal structures constantly contacted with fresh water or sea water because of their superiority to metallic ones in corrosion-resistance. In this study new non-metallic anchoring system for FRP tendons has been tested and investigated. The newly developed anchoring system utilizes FRP pipes and HEM (Highly Expansive Mortar). The major factors considered in this experiment were expansive pressure of HEM during its hydration and the strength of GFRP(Glass Fiber Reinforced Plastic) Pipe. Anchoring forces of the new anchoring system were investigated from the pull-out testes. The authors analyzed pull-out procedures of the FRP tendons in the various pipe filled with HEM and suggested an improved idea to develop novel non-metallic anchoring system for FRP tendons

• Corrosion Science and Technology
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• 제6권2호
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• pp.74-76
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• 2007

The increasing interest in the corrosion properties of weld joints in the corrosive environment is placing stringent demands on the manufacturing techniques and performance requirements, and the manufacture employs the high quality and efficiency welding process to produce welds. Welding plays an important role in the fabrication of chemical plants, nuclear power plant, ship construction, and this has led to an increasing attention to the corrosion resistant weld joints. This paper covers a recent technical trends of welding technologies for corrosion resistance properties including the COMPENDEX DB analysis of welding materials, welding process, and welding fabrications.

• 한국표면공학회지
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• 제52권3호
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• pp.111-116
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• 2019

Chromium was coated on a steel substrate by the Cr(III) electroplating method, and corroded at $500-900^{\circ}C$ for 5 h in $N_2/0.1%H_2S-mixed$ gas to study the high-temperature corrosion behavior of the Cr(III) coating in the highly corrosive $H_2S-environment$. The coating consisted of (C, O)-supersaturated, nodular chromium grains with microcracks. Corrosion was dominated by oxidation owing to thermodynamic stability of oxides compared to sulfides and nitrides. Corrosion initially led to formation of the thin $Cr_2O_3$ layer, below which (S, O)-dissolved, thin, porous region developed. As corrosion progressed, a $Fe_2Cr_2O_4$ layer formed below the $Cr_2O_3$ layer. The coating displayed relatively good corrosion resistance due to formation of the $Cr_2O_3$ scale and progressive sealing of microcracks.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.52-53
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• 2020

The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

• 콘크리트학회논문집
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• 제15권1호
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• pp.117-124
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• 2003

최근 강모래의 고갈로 인하여 해사의 사용이 증대되고 있는 실정에 있다. 그러나 해사는 철저하게 제염처리 하여 사용하지 않으면 철근 콘크리트 구조물의 철근에 막대한 영향을 미칠 수 있다. 본 연구에서는 제염처리하지 않은 해사를 시멘트 콘크리트에 직접 사용하여도 철근의 부식을 억제할 수 있는 방청재료를 개발하기 위한 연구의 일환으로서, 기존의 에폭시 철근과 비교하여 경제적이고 방식 성능면에서 우수한 재료로서 폴리머 시멘트 슬러리를 이용하고자 하였다. 각종 폴리머를 사용하고 여러 가지 부식촉진 실험을 통하여 도장하지 않은 철근과 도장한 철근과의 성능을 비교평가하였다. 연구결과, 폴리머 시멘트 슬러리로 도장한 철근은 도장하지 않은 철근에 비해 염화나트륨 수용액에 대한 침지 및 분무시험과 시멘트 콘크리트 속에서의 부식에 관한 실험에 있어서도 매우 우수한 방식성능을 발휘하였다. 다양한 부식촉진 실험결과, 철근의 부식은 염분, 중성화 및 촉진양생에 의해 크게 영향을 받으며, 복합적인 인자가 작용될 때, 더욱더 심한 부식이 발생하였다. 이러한 부식을 폴리머 시멘트 슬러리에 의한 도장으로 억제할 수 있는데, 폴리머 시멘트 슬러리의 매트릭스에 존재하는 폴리머 필림의 연속된 막에 의해 염화물 이온의 침투가 차단되었기 때문이며, 폴리머 시멘트 슬러리의 완벽한 방식효과는 도장두께로 조절할 수 있을 것이다.

• 한국해양공학회지
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• 제21권5호
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• pp.39-46
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• 2007

The sea water pipe of a ship's engine room is a severely corrosive environment caused by fast flawing sea water containing chloride ions and high conductivity. Therefore, leaking of sea water may occur as a result of local corrosion of the welded zone. Leaking is usually controlled by various welding methods. In this study, when the sea water pipe is welded with certain welding methods and welding electrodes, the corrosion resistance of WM (Welding metal) and HAZ (Heat affected zone) was investigated using electrochemical methods. Although the corrosion potential of the HAZ is higher than that of WM, the corrosion resistance of WM is superior to HAZ. However, when WM and HAZ are both opened to the sea water, the WM part with the anode was more seriously corroded than was the HAZ of the cathode by performance of a galvanic cell due to difference of the corrosion potential between HAZ and WM. In particular TIG welding showed relatively good results in corrosion resistance of both HAZ and WM compared to other welding methods.

• 한국산학기술학회논문지
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• 제16권10호
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• pp.6655-6665
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• 2015

할로겐계 난연제의 환경적 문제로 인한 규제가 강화되면서 비할로겐타입의 인계화합물을 기초로 한 난연제의 비중이 높아지고 있으며, 기능성 film 제조에 있어 난연 효과를 보이는 적인 첨가에 따라 수지의 물성 및 열적 특성이 확연히 달라진다. 난연 효과를 높이고자 난연제 과량 첨가시 수지의 물성은 크게 저하되며, 수축 또는 방청 등 기능성 film에 적용되기 어렵다. 본 연구에서는 적인MB의 함유량에 따른 LDPE film을 blow 타입의 사출공청을 통해 제조하였고, 이에 대한 난연성 시험과 인열 강도 및 수축률, 방청성 평가를 통해 적인-LDPE film의 기계적 특성 및 물성특성에 미치는 영향력과 함유량에 따른 적인난연 film의 특성연구를 그 목적으로 하였다. 난연성의 경우 VTM 0를 보였으며, 인열 강도의 경우 MD 및 TD의 경향성이 상반되는 것을 알 수 있었다. 수축률의 경우 함유량에 따른 특성은 보이지 않았으며, 방청성의 경우 국내 방청 수축 필름 신뢰성 규격의 기준인 0.05 % 보다 우수한 결과를 보였다.

• Journal of Welding and Joining
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• 제19권2호
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• pp.182-190
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• 2001

A marine structural material was well known to have high tensile strength, good weldability and proper corrosion resistance. Cu-containing high strength low alloy(HSLA) steel was recently developed for their purposes mentioned above. And the steel is free about preheating for welding, therefore it is reported that shipbuilding cost by using it can be saved more or less. However the marine structural materials like Cu-containing HSLA steel are being generally adopted with cathodic protection method in severe corrosive environment like natural sea water but the high strength steel may give rise to Hydrogen Embrittlement due to over protection at high cathodic current density for cathodic protection. In this study Cu-containing HSLA steel using well for marine atructure was investigated about the susceptibility of Hydrogen Embrittlement as functions of tensile strength, strain ratio, fracture time, and fracture mode, etc. and an optimum cathodic protection potential by slow strain rate test(SSRT) method as well as corrosion properties in natural sea water. And its corrosion resistance was superior to SS400 steel, but Hydrogen Embrittlement susceptibility of Cu-containing HSLA steel was higer than that of SS400 steel. However Hydrogen Embrittlement of its steel by SSRT method was showed with pheonomena such as decreasing of fracture time, strain ratio and fracture mode of QC(quasi-cleavage). Eventually it is suggested that an optimum cathodic protection potential not presenting Hydrogen Embrittlement of Cu-containing of HSLA steel by SSRT method was from-770mv(SCE) to - 900mV(SCE)under natural sea water.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.105-105
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• 2016

Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.

• Corrosion Science and Technology
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• 제23권2호
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• pp.154-165
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• 2024

Acetic acid and acetonitrile produced in the chemical process of petrochemical plants are used at high temperatures and pressures. They are exposed to harsh corrosive environments. The present investigation aimed to evaluate corrosion characteristics of metals with excellent corrosion resistance by performing immersion and electrochemical experiments with different composition ratios of acetic acid and acetonitrile in a high-temperature and high-pressure environment. Results of immersion experiment revealed that as acetic acid concentration increased, surface damage and corrosion also increased. In immersion experiments under all conditions, super austenitic stainless steel (UNS N08367) had the best corrosion resistance among various metals. The maximum damage depth under the most severe immersion conditions was observed to be 4.19 ㎛, which was approximately 25.25 ㎛ smaller than that of highly damaged stainless steel (UNS S31804). As a result of electrochemical experiments, electrochemical characteristics of various metals presented some differences with different composition ratios of acetic acid and acetonitrile. However, super austenitic stainless steel (UNS N08367) had the best corrosion resistance at a high pressure condition with a high concentration of acetic acid.