• Title/Summary/Keyword: Corrosive Resistance

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Electrochemical Adsorption Properties and Inhibition of Zinc Corrosion by Two Chromones in Sulfuric Acid Solutions

  • Fouda, Abd El-Aziz S.;Nazeer, Ahmed Abdel;Saber, Ahmed
    • Journal of the Korean Chemical Society
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    • v.58 no.2
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    • pp.160-168
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    • 2014
  • The electrochemical behavior and corrosion inhibition of zinc in 0.5 M $H_2SO_4$ in the absence and presence of some chromones has been investigated using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. The presence of these investigated compounds in the corrosive solutions decrease the weight loss, the corrosion current density, and double layer capacitance but increases the charge transfer resistance. Polarization studies were carried out at room temperature, and showed that all the studied compounds act as mixed type inhibitors with a slight predominance of cathodic character. The effect of temperature on corrosion inhibition has been studied and the thermodynamic activation and adsorption parameters were determined and discussed. The adsorption of the investigated compounds on zinc was found to obey Langmuir adsorption isotherm.

Diffusion of Ion in Hardened Cement Paste Containing Slag-Siliceous Powder (I) Diffusion of Cl- Ion (슬래그-규산질 미분말을 함유하는 시멘트 경화체중에서의 이온의 확산 (I) Cl-이온의 확산)

  • 민경소;김태현;최상흘;한기성
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.282-288
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    • 1987
  • Diffusion of Cl- ion in hardened cement paste with slag and siliceous powder such as silica fume and white carbon was investigated. The addition of admixtures reduces the content of Ca(OH)2, which is the main cause of pore formation by corrosive action of sea-water. The addition of admixtures makes the hardened cement paste dense, thereby restricting the diffusion of Cl- ion and improving the resistance to sea-water. Apparence diffusion coefficient of Cl- ion in hardened ordinary portland cement paste was 3.7${\times}$10-8$\textrm{cm}^2$/sec, while that for the hardened cement paste with the admixture was 1.2∼3.2${\times}$10-8$\textrm{cm}^2$/sec.

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A Study on Effect of Shielding Gas on the Mechanical Properties of Inconel 625 FCAW Weldments (인코넬 625 FCAW 용접부 물성에 미치는 보호가스의 영향에 대한 연구)

  • Kim Chan;Kim Dae Sun;An Do Gyeong;Park Gyeong Dong
    • Proceedings of the KWS Conference
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    • v.43
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    • pp.191-193
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    • 2004
  • Inconel 625 is useful in variety of industrial applications because of the resistance to attack in various corrosive media at temperatures from $200^{circ}C$ to over $1090^{circ}C$, in combination with good low- and high-temperature mechanical strength. Recently, this material is also used widely in offshore process piping in order to extend the maintenance term and improve the quality of anti-corrosion. Nowadays, the flux cored wire is developed and applied for the better productivity in several welding position including the vertical position. In this study, the weldability and weldment characteristics of inconel 625 are considered in FCAW weld associated with the several shielding gases in viewpoint of welding productivity.

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Experimental Study on Slenderness Effects in Concrete-Filled Glass Fiber Reinforced Polymer Composite Columns (콘크리트 충전 유리섬유 복합소재 기둥의 세장비 특성에 관한 실험적 연구)

  • Choi, Sok-Hwan;Lee, Sung-Woo;Sohn, Ki-Hoon;Lee, Myung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.585-590
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    • 2001
  • The structural characteristics of concrete-filled glass fiber reinforced polymer tubes were studied. The concept of concrete-filled composite columns was introduced to overcome the corrosion problems associated with steel and concrete piles under severe environments. Other benefits of composite columns include low maintenance cost, high earthquake resistance, and long expected endurance period. Several experiments were conducted; 1) compression test for short-length composite columns, 2) uniaxial compression tests on a total of 7 columns with various slenderness ratios. Short-length columns give higher strength and ductility revealing high confinement action in concrete. Failure strengths, failure patterns, confinement effects, and stress-strains relations were analyzed for slender columns. Current study will show the feasibility of concrete-filled glass fiber reinforced polymer composite columns in corrosive environments, and will provide an experimental database for columns that are externally reinforced by multidirectional fibers.

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Formation of TiC Composite Layer on Ductile Iron by Laser Surface Modification (레이저 처리에 의한 구상흑연주철의 TiC 복합화에 관한 연구)

  • Kim, Woo-Yeol;Park, Heung-Il
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.593-603
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    • 1998
  • Commercial ductile iron was coated with titanium and aluminum powders by low pressure plasma spraying and then irradiated with a $CO_2$ laser to produce anti-corrosive TiC composite layer. TiC carbides were precipitated homogeneously in a laser alloyed layer by in-situ reaction between carbon existed in the base metal and titanium with thermal sprayed coating. The formation of gas pores and brittle limited mixing zone with ledeburite microstructure in TiC composite layer were surpressed by the complementary alloying of aluminum. The hardness of TiC composite layer obtained by addition of titanium and aluminum was between 600 and 660 Hv, which was three times as high as the hardness of ferritic ductile iron. From the results of isothermal oxidation at 1123k for 24 hours in air, high temperature oxidation resistance of the TiC composite layer with aluminum was improved and doubled when compared with the TiC composite layer without aluminum.

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Dystopia in the Science Fiction Film: Blade Runner and Adorno's Critique of Modern Society

  • Park, Seung-Hyun
    • International Journal of Contents
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    • v.8 no.3
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    • pp.94-99
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    • 2012
  • Science fiction films touch coming-future themes, particularly those referring specifically to futuristic technology and its influence over human life. Dealing with the resistance of the replicants in the approaching millennium, Blade Runner brings the feat of modern civilization into doubt through the image of the dystopian future. In Blade Runner, a city is filled with waste, pollution, and dirt and a corrosive rain falls from the polluted clouds. Adorno criticizes contemporary society and its civilization. Characterizing advanced capitalist society by its total administration penetrating into every sphere of life, he contends that modern society promotes alienation, atomization, conformism, and fatalism. Blade Runner provides a chance to contemplate the problems of modern society, proposed by Adorno's critical works. Therefore, this paper attempts to analyze futuristic characteristics described in the film with Adorno's critique of modern society.

Evaluation Methods of Flame Retardants for Wooden Cultural Properties

  • Son, Dong Won;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.5
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    • pp.590-596
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    • 2014
  • Wooden cultural heritages of Korea have been destroyed by fire in many cases. As a result, a number of methods to protect wooden cultural properties against fire were introduced. A way of protecting wooden cultural properties installations of fire equipments such as sprinkler, fire alarm system, or fire extinguisher. Another way of protecting wooden cultural properties is to treat them with flame retardants for their safety. Development of a very effective flame retardant with a good performance without affecting danchung and wood quality is required. At the same time, methods of evaluating flame retardant treated woods should be devised to assess their efficacy. In this study, combustion characteristics using cone-calorimeter, limit oxygen index, moisture absorption, iron corrosive and weathering were analyzed to evaluate the flame resistance efficacy and performance of flame retardants treated woods. The evaluation methods of flame retardants for wooden cultural heritage were suggested.

Experimental Evaluation of the Effect of Steel-Seal and Hydro-Seal in Reinforced Concrete Structures (STEEL-SEAL 및 HYDRO-SEAL의 철근콘크리트 구조무에 미치는 영향에 대한 실험적 연구)

  • 전환석;이강균;배수호;정영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.287-292
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    • 1997
  • Recent economic growths have accelerating much construction activities of various infrastructures, such as Express railway, Long-span bridges, Multi-story Buildings and etc. Reinforcement steel corrosion to be inevitably caused under the progress of these construction activities have been on and off serious problems in the site, which could incur another tragedic accident to us suffering from safety-ignorance disease. Thus, it is strongly requested to develop probable innovative products which could remove corrosive materials on rebars and also protect steel corrosion of reinforced concrete structures in the construction site. Hydro-Seal and Steel-Seal could solve these problems currently faced with in the construction site. The objective of this research is to experimentally evaluated the effect of Hydro-Seal and Steel-Seal in reinforced concrete structures, of which usage might affect the bond strength between steel and concrete, long-term compressive strength of concrete, corrosion resistance and etc. Related test results show that appropriate dosage of Hydro-Seal and Steel-Seal in reinforced concrete structures didnot affect physical properties of reinforced concrete structures.

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An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe by each Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Moon, Kyung-Man
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2006.11a
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    • pp.185-188
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    • 2006
  • The sea water pipe of engine room in all kinds of ships is being surrounded with severe corrosive environment. Therefore it's leakage part due to corrosion is inevitably prevented by various welding method. In this case corrosion property of welded zone may be considerably different by each welding materials. In this study corrosion resistance of the welded zone of sea water pipe with some welding materials such as shielded metal arc welding materials, inert gas arc welding materials was investigated with electrochemical method.

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THE APPLICATION OF ALUMINUM SHEET FOR THE PROTECTIVE HEAT SHIELD (ALLMINUM PROTECTIVE HEAT SHIELD 적용연구)

  • 이중윤;이호기;이경남
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1996.10a
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    • pp.166-173
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    • 1996
  • There are kinds of materials for protective heat shield, i.e.Zn-coated steel, AI-coated steel and aluminum alloy sheets. This study compare formability, corrosion resistance, heat protectability, weight, and cost of these materials for heat protective shield. Generally aluminum alloy sheets are less formable than steel sheets, but A1100 alloy sheet shows almost same press quality of steel parts, using the press dies which producing steel parts. The heat shields using aluminum alloy sheet and steel sheet show almost same heat protectibility. It is the conclusion that Zn-coated merit, and AI-coated steel sheet and aluminum alloy sheet can be used to protect functional corrosion in severely corrosive market area. The material cost of AI-coated steel sheet and aluminum alloy sheet for a mid-size car is almost same, so aluminum alloy sheet is more recommendable in the point of weight reduction of vehicle.

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