• Title/Summary/Keyword: Corrosive Materials

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Reconstructive surgery for corrosive esophageal stricture (부식성 식도협착에 대한 식도재건술: 344 수술)

  • 유회성
    • Journal of Chest Surgery
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    • v.16 no.4
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    • pp.584-593
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    • 1983
  • Esophageal reconstruction was performed in 344 patients with irreversible stricture of the esophagus resulting from caustic burns at National Medical Center from 1959 to 1982.There were 113 males and 231 females, and ranging from 2.5 to 58 years of age, and mean age was 26.5 years, and 25 cases were less than 10 years old. Caustic materials were 286 [83.2%] alkali and 50[14.5%] acid. The most frequent stricture site was upper thoracic esophagus as 56.7%, and the next was cervical as 31.4%, and lower, 11.9%. The stomach was involved in 10.8% totally, and hypopharyngeal stricture was also noticed in 3.2%, and in 3 cases, hypopharyngeal reconstruction was needed due to extensive scar change. In 329 of total 344 cases, colon interposition was performed without resection of the strictured esophagus except 4 cases which were complicated T-E fistula or perforation, and most of them, about 10-15 cm of terminal ileum with right half of the colon was used as the graft. The left colon with anti-peristalsis was used as graft only in 30 cases. The most common postoperative complication was anastomotic leak as 16.7% of total cases, and it was 12.5% from neck, 3.3% from ileocolostoma and 0.9% from cologastrostoma. Next common complication was neck stenosis [8.8%], aspiration pneumonia [6.4%], and graft necrosis [3.9%] in order. Overall operative mortality was 5.5% [14/329], and main causes of death were graft necrosis, sepsis due to anastomotic leak, gastric bleeding, and intestinal obstruction. Besides of colon interposition, according to shape or level of the stricture, plastic repair or segmental resection and direct anastomosis was done in 9, and 1 of them were complicated stenosis at the anastomotic site. In lower stricture, esophagogastrostomy was done in 10 cases, and 1 case expired due to hepatitis, and anastomotic stenosis was occurred in 2 cases at 1.5 months and 2.4 years later. During follow-up of 298 cases colon interposition from 6 months to 22 years, 82.6% was excellent, and 2.9% was complained of mild discomfort, and 4 cases were dead laterly, but 3 of them were not related to reconstruction.

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Themochemical Cycles for Hydrogen Production from Water (열화학적 수소 제조 기술)

  • Kim J.W.;Park C.S.;Hwang G.J.;Bae K.K.
    • Journal of Energy Engineering
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    • v.15 no.2 s.46
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    • pp.107-117
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    • 2006
  • The status of water splitting thermochemical cycle for hydrogen production was reviewed in this article. Mass production of hydrogen could be possible using the thermochemical process which is similar to the concept of conventional chemical reaction system if the high temperature heat source is available. The mediators (chemicals and reagents) should be used to split chemically stable water, and should be recycled in a closed cycle in order to be environmentally acceptable. Though there is no process to reach commercial stage, IS cycle, two-step cycles based on metallic oxide such as ZnO/Zn, $Fe_3O_4/FeO$ and the associated cycles are attracted due to their possibilities of application. Development of materials for high temperature and/or corrosive conditions during thermochemical process is still important topic in some thermochemical processes.

Surface Characteristic of Graphene Coated Stainless Steel for PEMFC Bipolar Plate (그래핀이 코팅된 스테인리스강의 고분자전해질 연료전지 분리판 적용을 위한 표면 특성)

  • Lee, Su-Hyung;Kim, Jung-Soo;Kang, Nam-Hyun;Jo, Hyung-Ho;Nam, Dae-Guen
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.226-231
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    • 2011
  • Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.

An Experimental Study on the Fire Risk Assessment & Calculation Breakthrough Time through Permeation Test of Chemical Protective Clothing (화학보호복의 화재위험성 및 화학적 투과시험을 통한 파과시간산정에 관한 실험적 연구)

  • Ko, Jae-Sun;Park, Pyoung-Kyu
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.21-30
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    • 2010
  • We have test chemical resistance and flame retardant properties of chemical protective clothing Fabrics by the ASTM and ISO standard methods. The flame retardant test results show that polyethylene is poor in flame resistance but fluoroelastomer add to decabrom is excellent in flame resistance. Especially, nowadays heat protective clothing for firefighters, which is aluminized film layers laminated to aramid fabric, show the excellent flame resistance. However, the chemical resistance test results show that aluminium is high corrosive in 4M NaOH solution alone. The problem of corrosion can be overcome by employing multiple barrier film. Also, based on the result of flame retardant test, duel skin of polymer barrier film add to aluminum film and single skin of fluorinated rubber with flame retardant materials seems to be fit for the chemical protective clothing. Also the thermal protection and heat transfer test results show that TPP and HTI is increased assured that the continued study on fire risk assessment & chemical resistance of chemical protective clothing fabrics will contribute to the upgrade the performances of chemical protective clothing fabrics.

Pro-environmental Maintenance and Management of Tour Cave : The Currents, Problems and Alternatives in Korea (관광동굴의 환경친화적 관리 방안에 관한 연구)

  • 유영준;이경호
    • Journal of the Speleological Society of Korea
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    • v.59
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    • pp.21-36
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    • 1999
  • Most scholars calssify caves into natural resource, but caves possess values of natural and human resource, mix up the features of natural resources and human resources. Now, caves are distributed 260 in Korea. Seongryu Cave is showed in 1967 for the first time, till 1997 12 caves is opened to tourist. But since 1996 the 12 show caves of all is not launched the safety and environment-protection check-up adduced reason for IMF. Then caves must maintain environment of the normal temperature, humidity and dark. But the environment of caves are destroyed by tourism development. Thus to maintain environment of caves, it used to consider the counterplan as follows in restraint of the environmental change. Firstly, in case of development work to open caves, it must keep up with the prototype. Secondly, it must establish a freight depositary to prevent the influence of the caves's stain and damage due to tourist's objects. Thirdly, to maintain the normal temperature and humidity, it must install artificial poultice equipment of the inner parts of caves. Fourthly, in order to prevent the occurrence of $CO_2$, it must assessment of the optimum number of the greatest stayer. Fifthly, the control of closure for a given period of time is useful of the restoration to the cave's original state. Sixthly, by means of make narrow entrance, it should not influence the outer's air on the inner parts on caves. Seventhly, to keep the temperature of the inner part of caves, the lightening should be maintained moderately considering the convenience of a tour. Eightly, when water-proof cables for the lightening bulbs are connected each other, silicon tape is suitable and circuit breakers should be installed at the diverging points of the cables. Ninthly, the direction and angle of the lightening must be changed periodically to prevent green-pollution at the lightening spot. Lastly, when facilities and arrangements are equipped, corrosive materials should be excluded if circumstances allow.

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Evaluation of a Sodium-Water Reaction Event Caused by Steam Generator Tubes Break in the Prototype Generation IV Sodium-cooled Fast Reactor

  • Ahn, Sang June;Ha, Kwi-Seok;Chang, Won-Pyo;Kang, Seok Hun;Lee, Kwi Lim;Choi, Chi-Woong;Lee, Seung Won;Yoo, Jin;Jeong, Jae-Ho;Jeong, Taekyeong
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.952-964
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    • 2016
  • The prototype generation IV sodium-cooled fast reactor (PGSFR) has been developed by the Korea Atomic Energy Research Institute. This reactor uses sodium as a reactor coolant to transfer the core heat energy to the turbine. Sodium has chemical characteristics that allow it to violently react with materials such as a water or steam. When a sodium-water reaction (SWR) occurs due to leakage or breakage of steam generator tubes, high-pressure waves and corrosive reaction products are produced, which threaten the structural integrity of the components of the intermediate heat-transfer system (IHTS) and the safety of the primary heat-transfer system (PHTS). In the PGSFR, SWR events are included in the design-basis event. This event should be analyzed from the viewpoint of the integrities of the IHTS and fuel rods. To evaluate the integrity of the IHTS based on the consequences of the SWR, the behaviors of the generated high-pressure waves are analyzed at the major positions of a failed IHTS loop using a sodium-water advanced analysis method-II code. The integrity of the fuel rods must be consistently maintained below the safety acceptance criteria to avoid the consequences of the SWR. The integrity of the PHTS is evaluated using the multidimensional analysis of reactor safety-liquid metal reactor code to model the whole plant.

Characteristics of Non-Point Pollution from Road Surface Runoff

  • Lee, Chun-Sik;Jang, Seong-Ho
    • Journal of Environmental Science International
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    • v.19 no.6
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    • pp.665-670
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    • 2010
  • Pollutants from urban pavement consists various kinds of substances which are originated from dry deposition, a grind out tire, corrosive action of rain to pavement and facilities and raw materials of the road etc.. These are major pollutants of urban NPS (Non-point source) during rainfall period. However there is not enough information to control such pollutants for appropriate management of natural water quality. In this study of transportation areas, three monitoring stations were set up at trunk road, urban highway and national road in Gyeongnam province. Runoff flow rate was measured at every 15minutes by automatic flow meters installed at the end of storm sewer pipe within the road catchment area for water quality analysis. Data was collected every 15 minutes for initial two hours of rainfall. Additional samples were collected 1-4 hours interval till the end of rainfall. The monitoring parameters were $COD_{Mn}$, SS, T-N & T-P and heavy metals. The average EMCs of TSS and $COD_{Mn}$ were 62.0 mg/L and 24.2 mg/L on the city trunk road, which were higher than those of urban highway and national road, indicating higher pollutant loads due to activities in the city downtown area beside the vehicle. On the other hand, the average EMC of T-N and T-P were in the range of 2.67-3.23 mg/L and 0.19-3.21 mg/L for all the sampling sites. Heavy metals from the roads were mainly Fe, Zn, Cu and Mn, showing variable EMCs by the type of road. From the TSS wash-off analysis in terms of FF(first flush) index, first flush phenomenon was clearly observed in the trunk road(FF : 0.89-1.43). However, such mass delivery behavior was not apparently shown in urban highway(FF : 0.90-1.11) and national road(FF : 0.81-1.41).

Evaluation of steel corrosion and Concrete Freeze-Thaw durability on the Liquid non-chloride deicer (액상 비염화물계 제설제의 강재 부식성 및 콘크리트 동결융해 내구성 평가)

  • Lee, Beung-Duk;Kim, Hyun-Joong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.529-532
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    • 2008
  • Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. In severe cases, scaling can result in dislodgement of coarse aggregate. This research estimates that pH and test of specific pollutants, dynamic modulus of elasticity for freeze-thaw test of concrete were higher than those NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w), also weight losses for scaling test of concrete were much lower than those of NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w).

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Comparative Study on Freeze-Thaw Durability of General Concrete and Pavement Concrete (일반콘크리트와 포장콘크리트의 동결융해 내구성에 대한 비교 연구)

  • Kim, Hyun-Joong;Lee, Beung-Duk;Lee, Ju-Gang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.561-564
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    • 2008
  • Concrete scaling is the progressive surface deterioration of susceptible subjected to freeze-thaw cycling in the presence of moisture. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. In this study, Use of (40, 27, 21MPa) pavement concrete analyze freeze-thaw test and scaling on the chlorides present.

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ICCP Control and Monitoring System for Ships

  • Oh, Jin-Seok;Moon, Serng-Bae
    • Journal of Navigation and Port Research
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    • v.30 no.4
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    • pp.291-294
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    • 2006
  • Corrosion is never avoided in the use rf materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic Protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. This thesis is about the ICCP control and monitoring system, which brings protection against the corrosion of the ship's hull in the sea environments. The test system for ICCP is composed of a power supply, anode, reference electrode and controller. The test system is composed power supply, anode, ref electrode, shunt and etc. The protection current is sent to the protection area though anode. Reference electrode senses whether or not the detected potential is within a range of protection of test equipment and then it is automatically controlled to increase or decrease the amount of protective current to be sent to the anode by controller. The monitoring system with LabView is also detected in order to check the normal state of the system at operation period, because an operator does not always watch over this system and thus the system cannot operate well because rf his or her negligent management. This paper was studied the variation of potential and current density with environment factors, velocity and time, and the experimental results will be explained Also, It is suggested that this system can accommodate a ship's automation for SCMS(Ship Control and Management System) and will be very useful.