• Title/Summary/Keyword: Corrosive Materials

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Study on the corrosion of A/C condenser in the ship (선박용 해수 열교환방식 A/C 응축기의 부식원인)

  • Baek, S.M.;Yang, J.H.;Kim, K.J.;Moon, K.M.;Lee, M.H.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.283-284
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    • 2006
  • The ship performs heat exchange using seawater to keep main engine and auxiliary machinery at optimum temperature. In heat exchanger, refrigerant located outside of copper tube is cooled by seawater flowing through inside of copper tube. On the other hand, seawater erosion and corrosion nay occasionally cause the corrosion of the copper tube in A/C(Air Conditioner) condenser. This corrosion of copper tube makes seawater and refrigerant mixed, seriously damaging A/C system. In this study, accordingly, the exact ive mechanism of the corrosion on the condenser entailing serious problems occasional is investigated through the electrochemical polarization experiments on the condenser's component materials. According to the experiments, the corrosive procedures on the copper tube was verified by the fact that passive film of the copper tube surface which is destroyed by the pressure of sucked seawater, is damaged by the corrosive ingredients in the seawater.

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Clinical Experience of Stenotic Anastoma of Neck after Reconstuctive Surgery for Corrosive Esophageal Stricture (재수술을 요한 식도재건술 환자의 원인분석과 임상적 고찰)

  • 안욱수
    • Journal of Chest Surgery
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    • v.25 no.2
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    • pp.183-187
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    • 1992
  • Reconstructive surgery for corrosive esophageal stricture was performed in 392 patients at National Medical Center from 1959 to 1990 Between Jan. 1971 and Dec. 1990, 23 cases were experienced stenotic anastoma of neck after reconstructive surgery for corrosive esophageal stricture. The major procedure of esophageal reconstruction was colon interposition without resection of the strictured esophagus except jejunal interposition in 1 case. There were 12 males % 11 females, and mean age was forty years. The caustic materials were 16[70%] alkali and 7[30%] acid. Half of the cases had hypopharyngeal injury. After reconstructed surgery, dysphagia was developed immediate in 65%, from 2 months to 5 months in 31%, and from years in 4%[1 case]. The complications were anastomatic leakage in 13 cases, anastomatic stenosis in 8 cases, graft gangrene in 1 case, and cancer development in 1 case. The therapeutic procedures were end-to-end anstomolis & partial resection of stenotic anastoma in 18 cases, bourgination in 2 cases, and coin interposition with graft removal in 3 cases. The therapeutic results were excellent in 16 cases, mild discomfort in 3 cases, poor in 3 cases, and death in 1 cases.

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Applicability on Water Treatment Structure of Anti-corrosive Sheet Molding Compound Panel (고분자수지계 패널형 방수방식재의 수처리구조물 적용성에 관한 실험적연구)

  • Seo, Hyun Jae;Park, Jin Sang;Bae, Kee Sun;Oh, Sang Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.161-163
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    • 2011
  • Due to various kind of waterproof materials and methods, which is difficult to select the most appropriate to waterworks. The materials used to prevent the deterioration of the service life is short, because of the chemical erosion. So, in the 2010 Office of Waterworks Seoul Metropolitan Government has set new standards. Recently, SMC panel is a trend that is being applied to water treatment facilities. However, SMC panel has not yet implemented a performance evaluation. Therefore, this study to confirm that satisfaction for the Office of Waterworks Seoul Metropolitan Government of the performance requirements, when the applied the SMC panel to water treatment structure.

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Fracture behavior using AE method and reliability assessment of CFRP based on absorbed moisture (흡습된 CFRP의 AE에 의한 파과거동과 신뢰성 평가)

  • 남기우;김선진
    • Journal of Ocean Engineering and Technology
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    • v.10 no.4
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    • pp.38-50
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    • 1996
  • Recently carbon fiber reinforced plastic (CFRP) has been used structural materials in corrosive environment such as for water, chemical tank and pipes. However, mechanical properties of such materials may be change when CFRP and exposed to corrosive environment for long periods of time. The degradation behavior of carbon fiber/epoxy resin composite material in distilled water is investigated using acoustic emission (AE) technique, Fracture toughness tests are performed on the compact tension specimens that are pilled by two types of $[O_2/9O_2]_{3s}$ and $[O/9O]_6s$. During the testes, AE test was carried out to monitor the damage of CFRP by moisture absorption. The data was treated by 2-parameter Weibull distribution and the fracture surface was observed by scanning electron microscope.

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Corrosion Characterestic of Rolling Stock Structural Steel by Environmental Degradation (환경열화에 의한 철도차량 구조용강의 부식 특성)

  • Kim Yong-Ki;Chang Se-Ky;Oh Chang-Rok;Goo Byeong-Chun
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.680-685
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    • 2004
  • The effects of acid rain and salt content on corrosion behavior were investigated with rolling stock structural steels be caused by environmental. Since these materials are exposed to the corrosive environments like polluted air, acid rain and sea water, it is important to investigate corrosion behaviour in various corrosive environments. The aqueous corrosion of the characteristic materials in aerated acid rain and neutral solution were studied by using immersion tests, electrochemical measurements and analytical techniques. In order to examine corrosion characteristic, structural steels were electrochemically evaluated with respect to the dissolved oxygen content, pH, chloride ion concentration.

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Development of anti-corrosive coating technique for alloy plated steel sheet using silane based organic-inorganic hybrid materials (Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발)

  • Park, Jongwon;Lee, Kyunghwang;Park, Byungkyu;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.295-303
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    • 2013
  • Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.

A Study on the Profile Change Measurement of Steam Generator Tubes with Tube Expansion Methods

  • Kim, Young-Kyu;Song, Myung-Ho;Choi, Myung-Sik
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.5
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    • pp.543-551
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    • 2011
  • Steam generator tubes for nuclear power plants contain the local shape transitions on their inner or outer surface such as dent, bulge, over-expansion, eccentricity, deflection, and so on by the application of physical force during the tube manufacturing and steam generator assembling and by the sludge (that is, corrosion products) produced during the plant operation. The structural integrity of tubes will be degraded by generating the corrosive crack at that location. The profilometry using the traditional bobbin probes which are currently applied for measuring the profile change of tubes gives us basic information such as axial locations and average magnitudes of deformations. However, the three-dimensional quantitative evaluation on circumferential locations, distributional angle, and size of deformations will have to be conducted to understand the effects of residual stresses increased by local deformations on corrosive cracking of tubes. Steam generator tubes of Korean standard nuclear power plants expanded within their tube-sheets by the explosive expansion method and suffered from corrosive cracks in the early stage of power operation. Thus, local deformations of steam generator tubes at the top of tube-sheet were measured with an advanced rotating probe and a laser profiling system for the two cases where the tubes expanded by the explosive expansion method and hydraulic expansion. Also, the trends of eccentricity, deflection, and over-expansion of tubes were evaluated. The advanced eddy current profilometry was confirmed to provide accurate information of local deformations compared with laser profilometry.

Evaluation of Corrosion Protection for Epoxy and Urethane Coating by EIS under Various Cyclic Corrosion Tests

  • Hyun, Jonghun;Shon, Minyoung
    • Corrosion Science and Technology
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    • v.10 no.3
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    • pp.95-100
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    • 2011
  • Protective coatings play an important role in the protection of metallic structures against corrosive environment. The main function of anticorrosive coating is to prevent the materials from corrosive agents, such as water, oxygen and ions. In the study, the corrosion protection properties of urethane and epoxy coating systems were evaluated using EIS methods exposed to the corrosion acceleration test such as Norsok M501, Prohesion and hygrothermal cyclic test. AFM analysis of the coating systems was carried out to monitor the change of roughness of coatings. Urethane coating system was more stable than the epoxy coating under given cyclic conditions. Water uptake into the urethane coatings was less than that into the epoxy coating. The urethane coating system showed better corrosion protection than epoxy coating system based on the changes of the impedance modulus at low frequency region with exposure time. Consequently, the corrosion protection properties of the epoxy and urethane coatings was well correspond with their surface roughness changes and water uptakes.

A Study on the Corrosion and Fatigue of Structural Materials for Rolling Stock (철도차량 구조재료의 부식 및 피로 특성 연구)

  • Jang Se-Ky;Kim Yong-Ki;Coo Byeong-Choon
    • Journal of the Korean Society for Railway
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    • v.8 no.4
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    • pp.299-307
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    • 2005
  • In general, structural integrity of rolling stock structures should last more than 25 years. During the lifetime corrosive degradation occurs. For structural design and diagnosis, quantitative relationship between corrosive degradation and variation of mechanical properties such as tensile strength and fatigue strength is needed. In this study, first of all we established the atmospheric corrosion test procedure. At regular intervals using specimens of SM490A and SS400 on the atmospheric corrosion test bed, we carried out tensile and fatigue tests. The fatigue strength decreases as the atmospheric corrosion period increases. In addition we studied the effect of post-weld heat treatment on the tensile and fatigue behaviour and performed electrochemical corrosion tests.

Improvement of the Corrosion Fatigue Life of Metal Material by Shot Peening (쇼트피닝가공에 의한 금속재료의 부식피로수명 개선)

  • Nam Ji-Hun;Kou Dae-Lim;Lee Kook-Jin;Lee Dong-Sun;Cheong Seong-Kyun
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.716-721
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    • 2004
  • Corrosion highly affects to reduce lifetime and performance of machinery metallic components. The effects of shot peening on the fatigue life of metal material under corrosive environment are investigated in this paper. Experimental results show that the fatigue limit of shot peened specimen increases about 52$\%$. That means the fatigue life of metallic components is highly extended by shot peening. The corrosion greatly reduces the fatigue strength depending on the corrosive condition from one week up to one year. In case of shot peened specimen, the corrosion does not reduce the fatigue strength and fatigue life up to six months. It means that shot peening has superior effectiveness to reduce the influence of corrosion to the metallic materials.

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