• Corrosion Science and Technology
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• v.12 no.1
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• pp.27-33
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• 2013

According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.113-118
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• 2003

Processible polyaniline (PAM) dispersions consisting of polyaniline micro-particles, cyclohexanone, and a polymeric surfactant were prepared in a micro-milling machine with various mixing conditions. The electrochemical properties of the dispersion film coated on Pt electrode were investigated by cyclic voltammetry (CV). The electrochemistry of the PAM dispersion coatings was basically similar to a pure PAM coating based on the results of CV. The results of polarization measurements and open circuit potential measurements carried out in $3\;wt.\%$ NaCI solution showed increase in corrosion potential when the PANI dispersion coatings applied on steel surface. Variation of open circuit potential $(OCP,\;V_{OC})$ of the dispersion coating/steel electrodes was observed, which differed with milling conditions. The results demonstrated practical use of the conducting polymer dispersion as a coating material for corrosion prevention of steel.

• Corrosion Science and Technology
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• v.14 no.1
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• pp.1-11
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• 2015

Local wall thinning and integrity degradation caused by several mechanisms, such as flow accelerated corrosion (FAC), cavitation, flashing and/or liquid drop impingements, are a main concern in carbon steel piping systems of nuclear power plant in terms of safety and operability. Thinned pipe management program (TPMP) had been developed and optimized to reduce the possibility of unplanned shutdown and/or power reduction due to pipe failure caused by wall thinning in the secondary side piping system. This program also consists of several technical elements such as prediction of wear rate for each component, prioritization of components for inspection, thickness measurement, calculation of actual wear and wear rate for each component. Decision making is associated with replacement or continuous service for thinned pipe components. Establishment of long-term strategy based on diagnosis of plant condition regarding overall wall thinning is also essential part of the program. Prediction models of wall thinning caused by FAC had been established for 24 operating nuclear plants. Long term strategies to manage the thinned pipe component were prepared and applied to each unit, which was reflecting plant specific design, operation, and inspection history, so that the structural integrity of piping system can be maintained. An alternative integrity assessment criterion and a computer program for thinned piping items were developed for the first time in the world, which was directly applicable to the secondary piping system of nuclear power plant. The thinned pipe management program is applied to all domestic nuclear power plants as a standard procedure form so that it contributes to preventing an accident caused by FAC.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.11
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• pp.919-925
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• 2016

In this study, the Lamb wave mixing technique, which is basised on advanced research on the nonlinear bulk wave mixing technique, is applied for corrosion detection. To demonstrate the validity of the Lamb wave mixing technique, an experiment was performed with normal and corroded specimens. Comparison group in an experimentation are selected to mode and frequency with dominant in-plane displacement and out-of-plane displacement of Lamb waves. The results showed that the Lamb wave mixing technique can monitor corrosion defects, and it has a trend similar to that of the conventional Lamb wave technique. It was confirmed that the dominant displacement and mode matching the theory were generated. Flaw detectability is determined depending on displacement ratio instead of using the measurement method and mode selection.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.6
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• pp.37-45
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• 2015

In this experimental study, effect of milled glass fibers was investigated on corrosion resistance of PSC grout mortar. In order to check whether the mortar mixture with milled glass fibers satisfy the required properties as a PSC grout, time of flow, bleeding and compressive strength measured. The corrosion resistance were investigated through chloride ion migration test, mortar absorption test and surface resistivity measurement. It is confirmed that all proportions with milled glass fibers have better corrosion resistance than that with only OPC binder. Time of flow was reduced but the bleeding was increased to unacceptable level by using milled glass fibers. Consequently, the mix proportion with milled glass fibers for a PSC grout should be modified to have lower water/binder ratio.

• Corrosion Science and Technology
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• v.6 no.5
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• pp.261-268
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• 2007

Embedded sensors were used as an in-situcorrosion-sensing device for aircraft and vehicular structures protected by organic coatings. Results are presented changes associated with a standard Airforce aircraft coating and a standard Army vehicle coating were monitored by embedded sensors. These coatings consisted of a polyurethane topcoat and an epoxy primer, however are formulated to provide different characteristics. The ac-dc-ac testing method was used to accelerate the degradation of these coatings while being immersed in a NaCl medium. Electrochemical impedance spectroscopy and electrochemical noise measurement experiments were used to monitor the induced changes. A comparison of the results between coatings subjected to the ac-dc-ac exposure and coatings subjected to only constant immersion in the NaCl medium is presented. The results were used to demonstrate the effectiveness of the ac-dc-ac method at accelerating the degradation of an organic coating without observably changing the normal mechanism of degradation. The data highlights the different features of the coating systems and tracks them while the coating is being degraded. The aircraft coating was characterized by a high-resistant topcoat that can mask corrosion/primer degradation at the primer/substrate interface whereas the vehicle coating was characterized by a low-resistant topcoat with an effective corrosion inhibiting primer. Details of the ac-dc-ac degradation were evaluated by using an equivalent circuit to help interpret the electrochemical impedance data.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.3
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• pp.87-95
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• 2020

As an experimental study on the corrosion behavior of steel materials to which ATMS method using EIS was applied in concrete, immersion of Ca(OH)₂ saturated aqueous solution and NaCl aqueous solution simulating the environment inside concrete The corrosion behavior was tested. The equivalent circuit was derived through the analysis of the Nyquist plot, and the interfacial resistance and the polarization resistance of the Ca(OH)₂ aqueous solution were compared, and Al ATMS was the best interfacial resistance and Zn ATMS was the best polarization resistance. After burying ATMS steel material of cement mortar, the initial immersion impedance measurement value was the highest in the Zn ATMS test body in the impedance measurement by the immersion time by immersing it in the NaCl aqueous solution. Al ATMS test piece has the highest impedance and is highly reliable. This is because Al, which has a high ionization tendency, is continuously oxidized in a strong alkaline environment to form a film and protect the steel from permeation of chlorine ions.

• Journal of Conservation Science
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• v.34 no.6
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• pp.503-515
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• 2018

Stupa of State Preceptor Jigwang at Beopcheonsa temple site, Wonju, was conserved and restored in 1957. It was necessary to assess the degree of damage to the used mortar and to provide objective data on the necessity of its removal. Therefore, the HCP(half-cell potential) measurement used in concrete fields was applied. Multi-regression analysis of HCP data, following the rapid corrosion test of the roofstone mortar used by the rebar, resulted in a high correlation of HCP values(0.86), depending on the amount of corrosion and cover depth used for the steel bar. As a result, high correlation values(0.86) for the coefficients of determination were derived. The showed that the measurement of the wet conditions -431 to -663 mV on the roofstone indicated a corrosion damage rate of 90% or more after removal and restoration.

• Nuclear Engineering and Technology
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• v.52 no.9
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• pp.2119-2129
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• 2020

Flow-accelerated corrosion (FAC), liquid droplet impingement erosion (LDIE), cavitation and flashing can cause continuous wall-thinning in nuclear secondary pipes. In order to prevent pipe rupture events resulting from the wall-thinning, most NPPs (nuclear power plants) implement their management programs, which include periodic thickness inspection using UT (ultrasonic test). Meanwhile, it is well known in field experiences that the thickness measurement errors (or deviations) are often comparable with the amount of thickness reduction. Because of these errors, it is difficult to estimate wall-thinning exactly whether the significant thinning has occurred in the inspected components or not. In the previous study, the authors presented an approximate estimation procedure as the first step for thickness measurement deviations at each inspected component and the statistical & quantitative characteristics of the measurement deviations using plant experience data. In this study, statistical significance was quantified for the current methods used for wall-thinning determination. Also, the authors proposed new estimation procedures for determining local wall-thinning to overcome the weakness of the current methods, in which the proposed procedure is based on analysis of variance (ANOVA) method using subgrouping of measured thinning values at all measurement grids. The new procedures were also quantified for their statistical significance. As the results, it is confirmed that the new methods have better estimation confidence than the methods having used until now.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.09a
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• pp.677-694
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• 2009

While the budget has been allocated more for repairs and reinforcements, casualties are gradually increased due to slope disaster. Slope disaster causes road damaged as well as casualties. It also causes significant social and economic loss. The measurement device, which is installed inside ground of slope like inclinometer, has the high loss rate when slope is being slided. The electric type and the vibrating wire type have low durability because of corrosion. To cover the demerit of the present slope monitoring, the measurement method using the Multi-Antenna GPS has been developed. The Multi-Antenna GPS has been installed in the local slope as the regular monitoring system for slope. Although the initial cost of the Multi-Antenna GPS for installation is high, the additional cost is low. So it is the suitable method for large slope. The regular monitoring system using the Multi-Antenna GPS is the suitable measurement method for watching slope collapse, which is occurred widely, because it is economical, has high durability, and collects data with high resolution.