• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.4
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• pp.45-53
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• 2023

In this study, to analyze the correlation of surface chloride and corrosion amount level according to the installation location of steel members exposed to the marine environment, the surface chloride and mean corrosion depth were evaluated by member units for box girder members of the offshore steel bridge and box specimens. The surface chloride was measured monthly using the Bresle method for one year. The corrosion amount was evaluated by converting the weight loss due to corrosion products generated in the monitoring steel plate into mean corrosion depth. As a measurement result of the surface chloride and corrosion amount, relative differences in surface chloride and mean corrosion depth were appeared depending on the shape or installation location of the steel members. Moreover, even if members of the same shape were installed in the same bridge, it was confirmed that the corrosion amount was increased locally and rapidly. The tendency of corrosion amount depending on the surface chloride was evaluated to analyze the correlation between surface chloride and corrosion amount, and the relation equations that can asseses the corrosion amount depending on the surface chloride were analyzed. From the results of the correlation between surface chloride and corrosion amount, it was found that the corrosion amount of the steel member affected by the surface chloride was varied up to about 1.15 times depending on the structural detail.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2006.11a
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• pp.177-180
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• 2006

This study is to make a basic study if solid zinc (Zn) can be used for buried reference electrode, so we examined the adequacy of zinc as reference electrode by using zinc which showed regular electrode for buried period. The deference of electric potential if zinc electrode for corrosion factor such as soil resistivity or pH didn't show fixed trend and there was no clear trend on the change of measurement period. From field test, it is known that the natural electric potential difference of CSE electrode and zinc electrode is 1,100mV, but the electric potential of zinc electrode for CSE electrode in the natural soil and copying soil was 1,094~1,158mV. There was no fixed trend on the change of measurement period and electric potential difference of zinc electrode for corrosion factors such as soil resistivity or pH. Consequently, there was 40~60mV of electric potential difference in every copying soil during the experiment measurement.

• Journal of the Korean institute of surface engineering
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• v.49 no.1
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• pp.26-31
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• 2016

In this paper, the characteristics of a cavitation-erosion damage behavior on the STS 304 and hot-dip aluminized STS 304 under cavitation environment in sea water solution was investigated. The electrochemical experiments were carried out by potential measurement, anodic/cathodic polarization test, Tafel analysis, and also galvanostatic experiment in current density variables for the samples. The apparatus of cavitation-electrochemical experiment was manufactured in compliance with modified ASTM G-32 standard, with the conditions of sea water temperature of $25^{\circ}C$ and the measurement, amplitude of $30{\mu}m$. The damage behavior was analyzed by an observation of surface mophologies and a measurement of damage depth by a scanning electron microscope(SEM) and a 3D microscope, respectively, after electrochemical test. After polarization experiment under cavitation environment, much higher damage depths for the hot-dip aluminized STS 304 were observed comparing to the untreated STS 304. In addition, higher corrosion current density in hot-dip aluminized STS 304 presented than that of untreated STS 304 as a result of Tafel analysis.

• Korean Journal of Metals and Materials
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• v.48 no.6
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• pp.523-532
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• 2010

Co-application of organic coating and cathodic protection has not provided enough durability to low-alloyed steels inseawater ballast tank (SBT) environments. An attempt has made to study the effect of alloy elements (Al, Cr, Cu, Mo, Ni, Si, W) on general and localized corrosion resistance of steels as basic research to develop new low-allowed steels resistive to corrosion in SBT environments. For this study, we measured the corrosion rate by the weigh loss method after periodic immersion in synthetic seawater at $60^{\circ}C$, evaluated the localized corrosion resistance by an immersion test in concentrated chloride solution with the critical pH depending on the alloy element (Fe, Cr, Al, Ni), determined the permeability of chloride ion across the rust layer by measuring the membrane potential, and finally, we analyzed the rust layer by EPMA mapping and compared the result with the E-pH diagram calculated in the study. The immersion test of up to 55 days in the synthetic seawater showed that chromium, aluminium, and nickel are beneficial but the other elements are detrimental to corrosion resistance. Among the beneficial elements, chromium and aluminium effectively decreased the corrosion rate of the steels during the initial immersion, while nickel effectively decreased the corrosion rate in a longer than 30-day immersion. The low corrosion rate of Cr- or Al-alloyed steel in the initial period was due to the formation of $Cr_2FeO_4$ or $Al_2FeO_4$, respectively -the predicted oxide in the E-pH diagram- which is known as a more protective oxide than $Fe_3O_4$. The increased corrosion rate of Cr-alloyed steels with alonger than 30-day exposure was due to low localized corrosion resistance, which is explained bythe effect of the alloying element on a critical pH. In the meantime, the low corrosion rate of Ni-alloyed steel with a longer than 30-day exposure wasdue to an Ni enriched layer containing $Fe_2NiO_4$, the predicted oxide in the E-pH diagram. Finally, the measurement of the membrane potential depending on the alloying element showed that a lower permeability of chloride ion does not always result in higher corrosion resistance in seawater.

• Proceedings of the KSR Conference
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• 2011.10a
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• pp.931-938
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• 2011

Nondestructive inspection(NDI) is a testing procedure used to easily inspect an object for internal defects, abnormalities, shape, and structure, etc. without destroying it. Typical candidates for NDI include buildings, railways, aircraft, bridges, underground pipelines and various types of factory equipment. Recent advances in nondestructive evaluation(NDE) technologies have led to improved methods for quality control and in-service inspection, and the development of new options for material diagnostics. Under frame side sill in rolling stocks is designed for preventing corrosion in order to meet mechanical requirements. However during long operation time, there are corrosion in the under frame side sill caused by environmental effect, vibration and etc. This paper introduces the methods of a survey and assessment on NDI applications in Electric Multiple Units(EMU). The main objective of this paper was to obtain information on various applications and evaluation of NDI technology in EMU.

• Nuclear Engineering and Technology
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• v.49 no.7
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• pp.1463-1471
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• 2017

In order to monitor the pipe thinning caused by flow-accelerated corrosion (FAC) that occurs in coolant piping systems, a shear horizontal ultrasonic pitch-catch waveguide technique was developed for accurate pipe wall thickness monitoring. A clamping device for dry coupling contact between the end of the waveguide and pipe surface was designed and fabricated. A computer program for multi-channel on-line monitoring of the pipe thickness at high temperature was also developed. Both a four-channel buffer rod pulse-echo type and a shear horizontal ultrasonic waveguide type for high-temperature thickness monitoring system were successfully installed to the test section of the FAC proof test facility. The overall measurement error can be estimated as ${\pm}10{\mu}m$ during a cycle from room temperature to $200^{\circ}C$.

• Proceedings of the KIEE Conference
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• 2005.07d
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• pp.2616-2618
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• 2005

Time-frequency analysis (TFA) method was applied to identify the integrity of the internal local surface of a pipe where some chemical corrosions are likely to occur by acid mixed in the coolant of nuclear power plants. The spalling out of internal material pieces by corrosion induces some transient signals and the change of structural vibration of a local point in the pipe. It is therefore possible to detect the corrosion detachment through the measurement of the transient acoustic signals or the vibration signals. In this presentation, the TFA was configured on the vibrational signal data of the pipe and it is identified that the TFA can Provide an important information, i.e., the amplitude fluctuations in the instantaneous frequency of each characteristic frequency.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.47-52
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• 2003

23 cap beams on the 1 Km length jetty bridge in Shin-da power plant (Taipower co., Taiwan) utilize far-end telecontrol cathodic protection technology which is the first case ever used in Taiwan. The system comprises cathodic protection system and te1econtrol monitoring system. The control and monitoring such as protection current adjustment, protection potential and depolarization measurement of the 23 cap beams can be adjusted through system telecontrol operations. Thereby allows monitoring and control of the 23 anode zones in a convenient and cost effective way. This system is at present still in its best running condition since Sept. 1997 when it was completed. All the 23 cap beams can achieve the 100 mV depolarization potential criteria of protection. It meet the specifications of reinforced concrete cathodic protection standard and proved to be very excellent.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.32 no.2
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• pp.157-163
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• 1996

To ceramic film, $SiO_2$ and $Al_2O_3$, coated on pure Fe and stainless steel(SUS41O) by RF magnetron sputtering, the adherence between mm and substarte was studied. The adherence index (${\chi}$) was determined by the measure of micro hardness test. Also, the corrosion resistance on oxide coatings was studied using electrochemical measurement. The main results obtained are as the following: 1) In the micro-hardness test, with $1{\mu}m$ thickness mm, it has only one the value of ${\chi}$. Above $2{\mu}$thickness fIlm, however, get another value of ${\chi}$as the cracks in fIlm. 2) The oxide fIlm adhere well on the mild materials such as pure steel than high intensity materials like stainless. 3) Alumina($Al_2O_3$) coated materials have better corrosion resistance than silica($SiO_2$)coated materials

• Journal of Electrochemical Science and Technology
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• v.1 no.2
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• pp.112-116
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• 2010

Fractal property of the passivated steel surface was investigated on the basis of scaling analysis with a special focus on its relationship with corrosion resistance. For this purpose, the surface of stainless steel was intentionally oxidized under a variety of passivation conditions and its scaling property was analyzed by a triangulation method. The morphology of the passivated steel surface was satisfactorily evaluated with fractal dimension. From the chronoamperometry and impedance measurement, it proved that lower fractal dimension leads to more enhanced corrosion resistance. The higher passivity of the steel surface with lower fractal dimension was discussed in terms of active area and structural imperfection.