• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.257-260
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• 2006

This paper reports results of a study conducted to assess the effect of degree of corrosion of reinforcing steel bar on their mechanical properties. Reinforcing steel bars, 13mm in diameter, that were corroded by electrically accelerated corrosion method in concrete specimens were removed and tested in tension. Results indicated that the level of reinforcement corrosion influenced yield point, the tensile strength and elongation of steel bars.

• 전기학회논문지
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• 제56권2호
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• pp.338-342
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• 2007

The increase of activated carbon contents in fly ashes accelerate the corrosion of steel embedded in ordinary portland cement(OPC) mortar. Cement losses its identity of colour when the % of carbon is increased. More than 60[%] area was rusted when carbon content is increased beyond 8[%] for the exposure period of one year. Comparable corrosion rate with OPC was obtained up to 6[%] carbon level only. The tolerable limit of replacement for various admixed carbon system under aggressive alternate wetting and drying condition with 3[%] NaCl was found to be 6 to 8[%].

• 상하수도학회지
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• 제34권5호
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• pp.373-383
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• 2020

The purpose of this study was to evaluate the corrosion damage of large diameter metallic pipes buried in reclaimed land due to the corrosion effect by soil, and to propose a method of installing metal pipes in the reclaimed land. The results are as follow. First, the soil of the reclaimed land was gray clay, the soil specific resistance indicating soil corrosiveness was at least 120 Ω-cm, the pH was weakly acidic(5.04 to 5.60), the redox potential was at least 62 mV, the moisture content was at most 48.8%, and chlorine ions and sulfate ions were up to 4,706.1 mg/kg and 420 mg/kg. Therefore, the overall soil corrosivity score was up to 19, and the external corrosion effect seems to be very large. Second, the condition of straight part of pipes was in good condition, but most of KP joints were affected by corrosion at a severe level. The reason for this seems to be that KP joints accelerated corrosion due to stress and crevice corrosion in addition to galvanic corrosion in the same environment. Third, as a result of evaluating correlations of each item that affects the corrosion on the external part, the lower the soil resistivity and redox potential, the greater the effect on the KP joints corrosion, and the moisture content, chloride ion, and sulfate ion, the higher the value, the greater the effect on the corrosion of KP joints. In addition, among soil corrosion items, the coefficient of determination of soil resistivity with corrosion of KP joints was the highest with 0.6439~0.7672. Fourth, when installing metal pipes or other accessories because the soil of the reclaimed land is highly corrosive, it is necessary to apply a corrosion preventive method to extend the life of pipes and prevent leakage accidents caused by corrosion damage to the joint.

• Computers and Concrete
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• 제32권3호
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• pp.287-302
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• 2023

Corrosion of reinforcing bars in reinforced concrete structures due to chloride attack in environments containing chloride ions is one of the most important factors in the destruction of concrete structures. According to the abundant reports that the corrosion rate around the repair area has increased due to the macro-cell current known as the incipient anode, it is necessary to understand the effective parameters. The main objective of this paper is to investigate the effect of the kinetic parameters of corrosion including the cathodic Tafel slope, exchange current density, and equilibrium potential in repair materials on the total corrosion rate and maximum corrosion rate in the patch repair system. With the numerical simulation of the patch repair system and concerning the effect of parameters such as electromotive force (substrate concrete activity level), length of repair area, and resistivity of substrate and repair concrete, and with constant other parameters, the sensitivity of the macro-cell current caused by changes in the kinetic parameters of corrosion of the repairing materials has been investigated. The results show that the maximum effect on the macro-cell current values occurred with the change of cathodic Tafel slope, and the effect change of exchange current density and the equilibrium potential is almost the same. In the low repair extant and low resistivity of the repairing materials, with the increase in the electromotive force (degree of substrate concrete activity) of the patch repair system, the sensitivity of the total corrosion current reduces with the reduction in the cathode Tafel slope. The overall corrosion current will be very sensitive to changes in the kinetic parameters of corrosion. The change in the cathodic Tafel slope from 0.16 to 0.12 V/dec and in 300 mV the electromotive force will translate into an increase of 200% of the total corrosion current. While the percentage of this change in currency density and equilibrium potential is 53 and 43 percent, respectively. Moreover, by increasing the electro-motive force, the sensitivity of the total corrosion current decreases or becomes constant. The maximum corrosion does not change significantly based on the modification of the corrosion kinetic parameters and the modification will not affect the maximum corrosion in the repair system. Given that the macro-cell current in addition to the repair geometry is influenced by the sections of reactions of cathodic, anodic, and ohmic drop in repair and base concrete materials, in different parameters depending on the dominance of each section, the sensitivity of the total current and maximum corrosion in each scenario will be different.

• 한국구조물진단유지관리공학회 논문집
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• 제27권4호
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• pp.45-53
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• 2023

본 연구에서는 해양환경에 노출된 강부재의 표면염분과 부식량의 상관관계를 분석하기 위하여 해상강교량의 보강형 거더 부재와 강박스 실험체를 대상으로 표면염분량과 평균부식두께를 부재단위로 평가하였다. 표면염분은 월단위로 1년간 Bresle method를 활용하여 계측하였고, 부식량은 실험용 모니터링 강판에 발생한 부식생성물로 인한 중량감소량을 평균부식두께으로 환산하여 분석하였다. 표면염분과 부식량을 계측한 결과, 강부재의 형상이나 설치위치에 따라 상대적인 표면염분량과 평균부식두께의 차이가 나타났으며, 동일한 교량 내에 설치된 동일한 형상의 부재라도 부식량이 국부적으로 급격히 증가하는 것을 확인하였다. 표면염분과 부식량의 상관관계를 분석하기 위하여 표면염분에 따른 부식량 발생 경향을 평가하였으며, 부식량을 평가할 수 있는 평가식을 부재의 형상별로 분석하였다. 표면염분과 부식량의 상관관계 분석 결과, 표면염분의 영향으로 강부재에서 발생하는 부식량은 부재의 형상에 따라 약 1.15배까지 변화하는 것으로 나타났다.

• Corrosion Science and Technology
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• 제4권4호
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• pp.155-163
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• 2005

Heavy duty coating are required to have minimum durable period of 15 years under average usage environment because these paints are coated with purpose of anti-corrosion, antifouling, plastering etc. Onto steel structures constructed upon land and sea and other ferrous structures of electric power generation plants, electricity transmission towers, large structures of various plants, etc. Therefore we tried to estimate heavy duty coating longevity through reliability evaluation method and used combined cyclic anti-conrrosion test method composed of drying, moisturizing and salt spray as for accelerated life test to estimate longevity. Accelerated life test hours to heavy duty coating of first grade (with longevity not less than 15 years) specification may be obtained from troubleless test hours $t_n=\frac{B_p}{n^{1/\beta}}\left[\frac{1n(1-CL)}{1n(1-p)} \right]^{1/\beta}=19.671$ (yr) where shape parameter $\beta=1.1$, confidence level CL=80 %, warranty life $B_{10}=15$ yr and sampling size n=10 (2 sets). Because acceleration factor {AF} found by accelerated test is 41.7, accelerated life test hours required may be represented about 4,132 hr so that if this amount of hours is converted to number of cycles(6 hr/cycle) of complex cycle corrosion resistance test then the amount is tantamount about 690 cycles. That means if there does not occur trouble failure (with defect factor sum not more than 20) during when there is performed 690 cycles of combined cyclic anti-corrosion test to heavy duty coating specimen then it signifies that there can be warranted longevity $B_{10}$ of 15 yr under condition of confidence level CL=80 %.

• 한국건설순환자원학회논문집
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• 제2권2호
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• pp.93-99
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• 2014

이 연구는 플라이애쉬와 고로슬래그를 치환한 방청 폴리머 보수모르타르의 개발을 위한 기초실험이다. 주요변수는 폴리머 수지 치환율, GGBS와 FA 치환율 및 방청제 치환율이다. 주요 측정항목은 초기슬럼프, 재령별 압축강도, 재령 28일 휨 강도, 건조수축 변형률이다. 실험 결과 모르타르의 압축강도 발현을 고려하였을 때 FA와 GGBS의 적정 치환율은 각각 10%와 20%로 추천될 수 있었다. 또한 방청체 치환은 모르타르의 압축강도를 감소시키는데, 적정 방청제 치환율은 1.5% 이하가 고려될 수 있었다. 한편 모르타르의 휨 강도는 ACI 318-11에서 제시하는 값인 $0.63{\sqrt{f_{ck}}}$보다 컸으며, 건조수축 변형률도 재령 10일 이후에는 ACI 209 예측값보다 낮았다.

• 대한금속재료학회지
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• 제46권3호
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• pp.125-130
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• 2008

Conventional plasma carburizing or nitriding for austenitic stainless steels results in a degradation of corrosion resistance. However, a low temperature plasma surface treatment can improve surface hardness without deteriorating the corrosion resistance. The 2-step low temperature plasma processes (the combined carburizing and post nitriding) offers the increase of both surface hardness and thickness of hardened layer and corrosion resistance than the individually processed low temperature nitriding and low temperature carburizing techniques. In the present paper, attempts have been made to investigate the influence of the introduction of Ar gas (0~20%) in nitriding atmosphere during low temperature plasma nitriding at $370^{\circ}C$ after low temperature plasma carburizing at $470^{\circ}C$. All treated specimens exhibited the increase of the surface hardness with increasing Ar level in the atmosphere and the surface hardness value reached up to 1050 HV0.1, greater than 750 $HV_{0.1}$ in the carburized state. The expanded austenite phase (${\gamma}_N$) was observed on the most of the treated surfaces. The thickness of the ${\gamma}_N$ layer reached about $7{\mu}m$ for the specimen treated in the nitriding atmosphere containing 20% Ar. In case of 10% Ar containing atmosphere, the corrosion resistance was significantly enhanced than untreated austenitic stainless steels, whilst 20% Ar level in the atmosphere caused to form CrN in the N-enriched layer (${\gamma}_N$), which led to the degradation of corrosion resistance compared with untreated austenitic stainless steels.

• Corrosion Science and Technology
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• 제6권4호
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• pp.164-169
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• 2007

Hydrogen induced cracking (HIC) was studied phenomenologically and the effect of microstructure on HIC was discussed for the steels having two different levels of nonmetallic inclusions. Steels having different microstructures were produced by thermomechanically controlled processes (TMCP) from two different heats which had the different level of nonmetallic inclusions. Ferrite/pearlite (F/P), ferrite/acicular ferrite (F/AF), ferrite/bainite (F/B) were three representative microstructures for all tested steels. For the steels with higher level of inclusions, permissible inclusion level for HIC not to develop was different according to steelmicrostructure. On the contrary, HIC occurred also at the martensite/austenite (M/A) constituents regardless of steel microstructure when they accumulated to a certain degree. It was proved that M/A constituents were easily embrittled by hydrogen atoms. Steels having F/AF is resistant to HIC at a given actual service condition since they covers a wide range of diffusible hydrogen content without developing HIC.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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• pp.197-201
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• 2001

Measuring of the dissolved oxygen is widely used for the environmental control of natural waters, sewage waste treatment, medical and biochemical studies, soil husbandry, food and drug process control, and prevention of corrosion in boilers. Especially, a power plants need special management for preventing accidents from corrosion, therefore, it is essential to measure the concentration of dissolved oxygen in real-time. In this paper we present a method of measuring dissolved oxygen very accurately up to ppb units. This method, called polarographic method, is based on the measures of the electric current generated by the oxidation process in cathode and de-oxidation process in anode, assuming that the amount of the current is proportional to the density of dissolved oxygen.