• Title/Summary/Keyword: Corrosion characteristics

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Characteristics of the Cyclic Hardening in Low Cycle Environmental Fatigue Test of CF8M Stainless Steel (CF8M 스테인리스 강 저주기 환경피로 실험의 주기적 변형률 경화 특성)

  • Jeong, Il-Seok;Ha, Gak-Hyun;Kim, Tae-Ryong;Jeon, Hyun-Ik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.2
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    • pp.177-185
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    • 2008
  • Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor (PWR). The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside a small autoclave. So the magnet type LVDT#s were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. Displacement of the fatigue specimen gauge length calculated by FEM (finite element method) used to modify the measured displacement and fatigue life at the shoulders. A series of low cycle fatigue life tests in air and PWR conditions simulating the cyclic strain hardening effect verified that the FEM modified fatigue life was well agreed with the simulating test results. The process and method developed in this study for the environmental fatigue test inside the small sized autoclave would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

Evaluation of the $\sigma$-Phase Degradation for Cast Stainless Steel CF8M by the Electrochemical Method (전기화학적 방법에 의한 주조 스테인리스강 CF8M $\sigma$상 열화평가)

  • Gwon, Jae-Do;Kim, Jung-Hyeong;Park, Jung-Cheol;Byeon, Jang-Hwan;Lee, U-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.23 no.11 s.170
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    • pp.2014-2021
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    • 1999
  • The present investigation is concerned with the degradation characteristics of cast stainless steel(CF8M), exposed to the $\sigma$-phase degradation at $700^{\circ}C$. In the present paper, the degradation of CF8 M at $700^{\circ}C$ is evaluated by a non-destructive test, DL-EPR(double loop electrochemical potentiokinetic reactivation). The surface of specimens is observed by using scanning electron microscopy after DL-EPR test. Also. chromium contents of matrix, grain boundary and ferrite phase are analyzed by electron probe X-ray micro analyzer. Through the experiments, the following results are obtained 1) The degree of sensitization(DOS) of CF8M aged up to 15hr at $700^{\circ}C$ is increased with acing time while that is decreased with aging time from 15hr to 150hr. 2) The impact energy decreases with increase of $\sigma$-phase while DOS increases with $\sigma$-phase until aging time reaches to 15hr. After the aging time. 15hr, the $\sigma$-phase and the rate of impact energy with respect to aging time decreases. Therefore the degradation behavior of the CF8M can be evaluated by comparing SEM micrographs and the value of DOS.

Development of Remote Field Eddy Current Pipeline Inspection System (원격장 와전류 배관 탐상 시스템 개발)

  • Jeong, Jin-Oh;Yi, Jae-Kyung;Kim, Hyoung-Jean
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.5
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    • pp.556-560
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    • 2001
  • Remote field eddy current testing (RFECT) with through-wall transmission characteristic is being applied to pipes ranging from small tubes of heat exchanger to natural gas supply pipelines. Cast iron pipes with nominal diameter of 100mm are used primarily as the waterline pipes. The leakage of water occurs due to defects in the pipes caused by vibration of automobiles and corrosion. But, the use of direct inspection methods such as insertion of inspection equipment inside the pipelines has been limited due to its lack of economical efficiency. Economical development of inspection equipments is possible since RFECT method can be easily employed for system integration and quantitative evaluation of both inside and outside defects. In this study, the development of underground pipeline inspection system was tarried out by using RFECT method in consideration of the characteristics of waterline network. This paper specifically describes the design and production of RFECT pipeline inspection pig using centralizer mechanism, development of remote field eddy current signal acquisition and processing software, and review of RFECT system operation procedures.

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Material Life Cycle Assessment of Extrusion Process of A7003 (A7003 알루미늄 합금 압출공정의 MLCA 산정기술)

  • Jo Huyng-ho;Cho Hoon;Kim Byung-min;Kim Young-jig
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.11a
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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Fabrication of Superconducting Joints between 61 Filaments of BSCCO 2223 Tapes (61심 BSCCO 2223 고온초전도 선재의 접합부 제조)

  • 김철진;박성창;유재무
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.137-144
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    • 1998
  • High-temperature superconducting joints between 61 filaments of Bi-2223 tapes were fabricated by chem-ical corrosion and repeated thermomechanical process. The silver sheath of the superconducting tape was chemically removed using chemical etchant(NH4OH:H2O2=1:1) from one side of each tape without altering the form of lap joint. The joined region was formed by uniaxial pressing and a series of thermomechanical process and then subjected to properties measurement and microstructural analysis. The critical current(Ic) variation and I-V characteristics along the joint were mesured with several configuration of proble points. Ic value of the transition region of the joint inthe multifilament tape which limit the total current carring capacity of the superconducting tape was higher than that of monofilament tape. But the transition ex-ponent n-value of the multi-filament tape was lower than that of monofilament wire due to the interaction of the individual superconducting core of the multi-filament. The critical current through the joint area was improved by respeated press and reaction annealing treatment.

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A Study on PM10 Control in Subway Tunnels Using Natural Polysaccharide Dust Collecting Agent (천연 다당류 먼지포집제를 이용한 지하철 터널 내 PM10 제어에 대한 연구)

  • Lee, Han-Seob;Hwang, Su-Jin;Hwang, Hyun-Seok
    • Journal of Environmental Health Sciences
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    • v.43 no.2
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    • pp.122-129
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    • 2017
  • Objectives: Most of the $PM_{10}$ in subway stations is spread by the train-induced wind from the tunnels. Therefore, in order to improve air quality in subway stations, it is important to remove the $PM_{10}$ from the tunnels. After the installation of PSD (platform screen doors), the influence of train-induced wind and $PM_{10}$ at the platform has decreased, but is estimated to have increased in subway tunnels. This study was conducted to investigate the control of $PM_{10}$ in subway tunnels by applying a 500-fold diluted solution mixed with a humectant using a natural polymer. Methods: For this purpose, we tested the dust reduction effect in a laboratory and corrosion test and water pollution using fish and aquatic plants for the natural dust collecting agent. In the tunnel of a subway station, we used the natural dust collecting agent over 15 days. The study was carried out on $PM_{10}$ control during operation, which accounts for more than 70% of subway dust. Results: As results, the natural dust collecting agent exhibited an excellent dust control effect, and it was safe for water quality and soil. It showed the effect of controlling $PM_{10}$ in the subway tunnel by 49.5- 64.7% over 15 days. The use of the dust collecting agent for the control of $PM_{10}$ could be confirmed in the subway. Conclusion: It is necessary to clearly explain the major portions of chemical components contained in $PM_{10}$ to figure out the characteristics of $PM_{10}$ and to develop effective reduction measures to decrease the adverse effects of $PM_{10}$ in the subway.

Study on the Electrode Characteristics for the Alkaline Water Electrolysis (알칼리 수전해용 전극에 관한 연구)

  • Choi, Ho-Sang;Yim, Doo-Soon;Rhyu, Cheol-Hwe;Kim, Jae-Chul;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.117-124
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    • 2012
  • Alkaline electrolysis needs the electrode having a low overvoltage and good corrosion resistance in alkaline solution such as KOH and NaOH, for the oxygen and hydrogen production. The commercial materials such as SUS(stainless steel)-316, Ni and NiFe were evaluated for the electrode in alkaline electrolysis. The test solution for the alkaline electrolysis used 1~9M NaOH and 1~9M KOH. The voltage increased with an increase of current density in each solution. As for the 15wt.% (about 5M) NaOH, the voltage of the tested electrode under the current density of 1.8A/$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: Ni${\fallingdotseq}$NiFe$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: NiFe${\fallingdotseq}$SUS-316. From the results, it was estimated that NiFe and Ni was suitable as the electrode for the alkaline water electrolysis using NaOH and KOH electrolyte.

Net Shaping Process to Minimize Cutting amount of Turbocharger Control Plate (터보차저 컨트롤 플레이트의 절삭량 최소화를 위한 정형공정)

  • Yoon, Pil-Hwan;Lee, Seon-Bong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.4
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    • pp.53-61
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    • 2017
  • Turbocharger is a device for increasing the power of a vehicle engine. The control plate is the main component for fixing the vane of the turbocharger. Now, the control plate is made of austenite steel cutting after the casting process. It has excellent corrosion, heat resistance and mechanical characteristics of material. However, present the process is made by cutting after casting. when cutting is processed after casting, so materials, processing time, and processing energy are lost. Therefore, this study proposes a process to powder compact use of stainless steel Deklak2 and to minimize amount of cutting through net shape process. The mechanical properties of Deklak2 were verified by tensile test, hardness test and relative density measurement, and the governed equation was defined. Also, the curvature radius 1, 2 and the density, affects the shape, were selected as the design parameters, and the best process conditions was proposed through the Taguchi method and the evaluation of SN ratio. And then prototype molds were fabricated and compared with the results of the finite element analysis for the verification, and it was found that the tendency of relative density and dimension was coincided. Therefore, it was found that the amount of cutting can be minimized by only the net shape process after the sintering process and it can be applied to mass production.

Characteristics of LDPE resin film depending on RP contents (적인 함유량에 따른 LDPE 수지 film의 특성연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6655-6665
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    • 2015
  • Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

Etching characteristics of Al-Nd alloy thin films using magnetized inductively coupled plasma

  • Lee, Y.J.;Han, H.R.;Yeom, G.Y.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.56-56
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    • 1999
  • For advanced TFT-LCD manufacturing processes, dry etching of thin-film layers(a-Si, $SiN_x$, SID & gate electrodes, ITO etc.) is increasingly preferred instead of conventional wet etching processes. To dry etch Al gate electrode which is advantageous for reducing propagation delay time of scan signals, high etch rate, slope angle control, and etch uniformity are required. For the Al gate electrode, some metals such as Ti and Nd are added in Al to prevent hillocks during post-annealing processes in addition to gaining low-resistivity($<10u{\Omega}{\cdot}cm$), high performance to heat tolerance and corrosion tolerance of Al thin films. In the case of AI-Nd alloy films, however, low etch rate and poor selectivity over photoresist are remained as a problem. In this study, to enhance the etch rates together with etch uniformity of AI-Nd alloys, magnetized inductively coupled plasma(MICP) have been used instead of conventional ICP and the effects of various magnets and processes conditions have been studied. MICP was consisted of fourteen pairs of permanent magnets arranged along the inside of chamber wall and also a Helmholtz type axial electromagnets was located outside the chamber. Gas combinations of $Cl_2,{\;}BCl_3$, and HBr were used with pressures between 5mTorr and 30mTorr, rf-bias voltages from -50Vto -200V, and inductive powers from 400W to 800W. In the case of $Cl_2/BCl_3$ plasma chemistry, the etch rate of AI-Nd films and etch selectivity over photoresist increased with $BCl_3$ rich etch chemistries for both with and without the magnets. The highest etch rate of $1,000{\AA}/min$, however, could be obtained with the magnets(both the multi-dipole magnets and the electromagnets). Under an optimized electromagnetic strength, etch uniformity of less than 5% also could be obtained under the above conditions.

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