• Title/Summary/Keyword: Corrosion characteristic

Search Result 204, Processing Time 0.029 seconds

The Characteristic Study of Plasma Electrolytic Oxidation in AZ31B Magnesium Alloy

  • Yu, Jae-Yong;Choi, Soon-Don;Yu, Jae-In;Yun, Jae-Gon;Ko, Hoon;Jung, Yeon-Jae
    • Journal of Electrical Engineering and Technology
    • /
    • v.10 no.4
    • /
    • pp.1746-1751
    • /
    • 2015
  • In this study low voltage Plasma Electrolytic Oxidation (PEO) was utilized to eliminate high voltage PEO drawbacks such as high cost, dimensional deformation and porosity. Low voltage PEO produces a thin coating which causes low corrosion resistance. In order to solve such problem, 0.1~0.6M pyrophosphates were added in a bath containing 1.4M NaOH, and 0.35M Na2SiO3. 70 V PEO was conducted at 25℃ for 3 minutes. Chemical composition, morphology and corrosion resistance of the anodized coating were analyzed. The anodized film was composed of MgO, Mg2SiO4, and Mg2O7P2. The morphology of film showed appropriately dense structure and low porosity in the anodized layers. It is found that low voltage Plasma Electrolytic Oxidation in cooperation with phosphating treatment can provide a good corrosion protection for the AZ31B magnesium alloy.

A study of the sulfide stress corrosion cracking characteristic of A106 Gr B steep pipe weldment (황화수소환경에서 A106 Gr-B 강 용접부의 응력부식균열 특성 평가)

  • Lee, Gyu-Young;Park, Kwang-Jin;Bae, Dong-Ho
    • Proceedings of the KSME Conference
    • /
    • 2007.05a
    • /
    • pp.114-119
    • /
    • 2007
  • Sulfide stress cracking (SSC) of materials exposed to oilfield environment containing hydrogen sulfide $(H_{2}S)$ has been recognized as a materials failure problem. Laboratory data and field experience have demonstrated that extremely low concentration of $H_{2}S$ may be sufficient to lead to SSC failure of susceptible materials. In some cases, $(H_{2}S)$ can act synergistically with chlorides to produce corrosion and cracking failures. SSC is a form of hydrogen embrittlement that occurs in high strength steels and in localized hard zones in weldment of susceptible materials. In the heat-affected zones adjacent to welds, there are often very narrow hard zones combined with regions of high residual stress that may become embrittled to such an extent by dissolved atomic hydrogen. On the base of understanding on sulfide stress cracking and its mechanism, SSC resistance for the several materials, those are ASTM A106 Gr B using in the oil industries, are evaluated.

  • PDF

Development of Moving Alternating Magnetic Filter Using Permanent Magnet for Removal of Radioactive Corrosion Product from Nuclear Power Plant

  • M. C. Song;Kim, S. I.;Lee, K. J.
    • Nuclear Engineering and Technology
    • /
    • v.34 no.5
    • /
    • pp.494-501
    • /
    • 2002
  • Radioactive Corrosion Products (CRUD) which are generated by the neutron activation of general corrosion products at the nuclear power plant are the major source of occupational radiation exposure. Most of the CRUD has a characteristic of showing strong ferrimagnetisms. Along with the new development and production of permanent magnet (rare earth magnet) which generates much stronger magnetic field than the conventional magnet, new type of magnetic filter that can separate CRUD efficiently and eventually reduce radiation exposure of personnel at nuclear power plant is suggested. This separator consists of inner and outer magnet assemblies, coolant channel and container surrounding the outer magnet assembly. The rotational motion of the inner and outer permanent magnet assemblies surrounding the coolant channel by driving motor system produces moving alternating magnetic fields in the coolant channel. The CRUD can be separated from the coolant by the moving alternating magnetic field. This study describes the results of preliminary experiment performed with the different flow rates of coolant and rotation velocities of magnet assemblies. This new magnetic filter shows better performance results of filtering the magnetite at coolant (water). How rates, rotating velocities of magnet assemblies and particle sizes turn out to be very important design parameters.

Electrochemical Characteristics of Arc Zn Thermal Spray Coating Layer in Sea Water (해수 내 아크 아연 용사코팅 층의 전기화학적 특성)

  • Park, Il-Cho;Seo, Gwang-Cheol;Lee, Gyeong-Woo;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
    • /
    • v.48 no.6
    • /
    • pp.343-348
    • /
    • 2015
  • In this paper, arc Zn thermal spray coating was carried out on the SS400 steel, and then various electrochemical characteristics and surface damage behavior of Zn thermal spray coating layer were analyzed. As the results, the potential of Zn thermal spray coating layer presented driving voltage above 300 mV compare to that of SS400 steel. The passivity characteristic in anodic polarization curve was not presented. It was adequate to as sacrificial anode material. In the surface damage after galvanostatic experiments, uniform corrosion tendency of Zn thermal spray coating layer was clearly observed with acceleration of the dissolution reaction. In conclusion, Zn thermal spray coating could be determined to represent the corrosion protection effect by stable sacrificial anodic cathodic protection method in seawater because it had sufficient driving voltage and uniform corrosion damage tendency for the SS400 steel.

Effect of FTO coated on stainless steel bipolar plate for PEM fuel cells

  • Park, Ji-Hun;Jang, Won-Yeong;Byeon, Dong-Jin;Lee, Jung-Gi
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2009.05a
    • /
    • pp.55.2-55.2
    • /
    • 2009
  • A polymer electrolyte membrane (PEM) fuel cell has been getting large interest as a typical issue in useful applications. The PEMFC is composed of a membrane, catalyst and the bipolar plate. SnOx:F films on SUS316 stainless steel were prepared as a function of substrate with using electron cyclotron resonance-metal organic chemical vapor deposition (ECR-MOCVD) in order to achieve the corrosion-resistant and low contact resistance bipolar plates for PEM fuel cells. The SnOx:F films coated on SUS316 substrate at surface plasma treatment for excellent stability, before/after heat treatment for good crystalline structure and microwave power for were characterized by X-ray diffraction (XRD), auger electron microscopy (AES) and field emission-scanning electron microscopy (FE-SEM). The SnOx:F film coated on SUS316 substrate with various process parameters were able to observe optimum interfacial contact resistance (ICR) and corrosion resistance. It can be concluded that fluorine-doping content plays an important function in electrical property and characteristic of corrosion-protective film.

  • PDF

Pulsed laser surface modification for heat treatment and nano-texturing on biometal surface

  • Jeon, Hojeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2016.11a
    • /
    • pp.118.1-118.1
    • /
    • 2016
  • The laser surface modification has been reported for its functional applications for improving tribological performance, wear resistance, hardness, and corrosion property. In most of these applications, continuous wave lasers and pulsed lasers were used for surface melting, cladding, alloying. Since flexibility in processing, refinement of microstructure and controlling the surface properties, technology utilizing lasers has been used in a number of fields. Especially, femtosecond laser has great benefits compared with other lasers because its pulsed width is much shorter than characteristic time of thermal diffusion, which leads to diminish heat affected zone. Moreover, laser surface engineering has been highlighted as an effective tool for micro/nano structuring of materials in the bio application field. In this study, we applied femtosecond and nanosecond pulsed laser to treat biometals, such as Mg, Mg alloy, and NiTi alloy, by heating to improve corrosion properties and functionalize their surface controlling cell response as implantable biomedical devices.

  • PDF

Uniaxial Compressive Strength Characteristic of Shotcrete Immersed in Chemical Solution (화학적 침식에 의한 숏크리트의 압축강도 특성)

  • Lee, Gyu-Phil;Kim, Dong-Gyou;Bae, Gyu-Jin;Kim, Hong-Sam
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2005.03a
    • /
    • pp.1291-1298
    • /
    • 2005
  • Shotcrete for the support of tunnel can contact with groundwater. The hazardous components in the groundwater cause the corrosion of shotcrete. Also, the hazardous components may deteriorate the engineering properties of shotcrete, such as compressive strength, bond strength, and flexural strength. The more the effect of the hazardous components on the shotcrete may increase, the more the stability of tunnel structure may decrease. It was analyzed to find the hazardous components in the ground water. The uniaxial compressive strength test, XRD, SEM were conducted to evaluate the durability and corrosion of shotcrete. These tests were performed on shotcrete specimens at 2, 4, 8, and 16 weeks. The specimens were immersed in various chemical solutions including hazardous components after the specimens were made at the construction site.

  • PDF

Characteristic of Corrosion Fatigue of High Strength Steel for Marine Structures (해양 구조물용 고장력강의 부식피로특성)

  • ;T. Kubo;H. Misawa
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2003.06a
    • /
    • pp.409-412
    • /
    • 2003
  • Fatigue strength. especially crack initiation behavior of high strength steel under marine water environment was investigated. Marine structures were usually constructed by lot of weld joints and were designed by basis of the fatigue strength of weld joints. This study was carried out to mini. The fatigue initiation behavior is more important rather than crack propagation behavior under the design of marine structures, because it is very difficult to find out the crack propagation phenomena and repair the damaged part of welded joints in sea water Then, the new configuration specimen for fatigue crack initiation tests was proposed. Using this new specimen, it is easy to carry out the crack initiation tests with relatively low cycling loading and clearly find out a crack initiation fatigue life.

  • PDF

Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
    • /
    • v.4 no.2
    • /
    • pp.157-166
    • /
    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

A Study on the Mechanical Characteristic in Al 6061 Alloys welded by Friction Stir Welding (Al 6061 합금의 마찰교반접합시 접합부의 역학적 특성에 관한 연구)

  • 방한서;김흥주;고민성;장웅성
    • Journal of Welding and Joining
    • /
    • v.20 no.3
    • /
    • pp.105-108
    • /
    • 2002
  • Al-alloy is utilized widely as a light-weight material to an automobile, a vessel and many kind of equipment, due to the light-weight and its characteristics that is a good tensile strength, elongation and tenacity for bearing heavy load and weight. Al-alloy has the good property of hot working, cold working and corrosion-resistant. But the exiting fusion welding by using Al has some economical and technical problems, but on the other hand, Friction Stir Welding (FSW) that is new joining method can settle the disadvantages that occur to the fusion welding and Is being applied and extended into the various industry fields. On this study, To analyze accurately the mechanical properties of joining area by FSW in Al 6061 alloy by using finite analysis program with finite element method. The size of HAZ and the thermal distribution is simulated and the mechanical properties around the FSW joining area to the Al-alloy 6061 is examined.