• Title/Summary/Keyword: Corrosion characteristic

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A Study on the Mechanical Characteristic in Al 6061 Alloys welded by Friction Stir Welding (Al 6061 합금의 마찰교반접합시 접합부의 역학적 특성에 관한 연구)

  • 방한서;김흥주;고민성;장웅성
    • Journal of Welding and Joining
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    • v.20 no.3
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    • pp.105-108
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    • 2002
  • Al-alloy is utilized widely as a light-weight material to an automobile, a vessel and many kind of equipment, due to the light-weight and its characteristics that is a good tensile strength, elongation and tenacity for bearing heavy load and weight. Al-alloy has the good property of hot working, cold working and corrosion-resistant. But the exiting fusion welding by using Al has some economical and technical problems, but on the other hand, Friction Stir Welding (FSW) that is new joining method can settle the disadvantages that occur to the fusion welding and Is being applied and extended into the various industry fields. On this study, To analyze accurately the mechanical properties of joining area by FSW in Al 6061 alloy by using finite analysis program with finite element method. The size of HAZ and the thermal distribution is simulated and the mechanical properties around the FSW joining area to the Al-alloy 6061 is examined.

Feature, Problem find the Hereafter of Chrome-Containing Refractory (크롬계 내화물의 특징과 문제점 및 장래)

  • Yamaguchi, Akira
    • Ceramist
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    • v.9 no.6
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    • pp.12-17
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    • 2006
  • One of characteristic of $Cr_2O_3-containing$ refractory is excellent resistance to corrosion. However, there is a problem that hexa-valent chromium, which is noxious to the human body, is easily formed by reaction between the refractory and slag with CaO, $Na_2O$ and/or $K_2O$. In this article, the reason why the $Cr_2O_3-containing$ refractory has excellent corrosion resistance qualities, he conditions under which hexa-valent chromium formed, methods for suppressing generation of hexa-valent chromium and the possibility of the refractory components excluding $Cr_2O_3$ for the furnace are described as a base of development of further excellent refractories.

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EFFECTS OF ALLOYING ELEMENTS ON VARIOUS PROPERTIES OF DENTAL SILVER-PALLADIUM ALLOYS (치과용(齒科用) 은(銀)-파라디움합금(合金)의 합금원소(合金元素)가 제성질(諸性質)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Kim, Chun-Jin;Park, Nam-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.22 no.1
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    • pp.95-108
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    • 1984
  • Even though the tarnishing and corrosion problems characteristic with dental silver-palladium alloy are not yet fully solved, it is recently widely used because of its low cost. However the effects of major alloying elements on the various properties of this system are not fully understood. The object of this research is to clarify the effects of In and Zn additives on the corrosion and tarnishing resistances and precipitation hardening behavior of this sytem, using electrodynamic polarization, immersion, and Vicker's microhardness test and X-ray diffraction and electron probe micro analysis methods. The obtained results were as follows: I. As indium content is increased, both the corrosion resistance in Cl-solution and microhardness are also increased while the tarnishing resistance is decreased. 2. As Zinc content is increased, the corrosion resistance is decreased, but tarnishing resistance is increased 3. At 70Ag-25Pd-2.5Zn-2.5In composition, the precipitation harding behavior was mot significant. The optimum aging temperature was $450^{\circ}C$ and the time was 2 hrs. The resulting specimen of this work carried 180VHN. 4. Under the heat treatment, the changes in the mechanical property are due to the changes in the shape and composition of dendrite matrix, namely, it is because of the precipitation hardening behavior which has been proved by electron probe micro analysis and optical microscopic finding.

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Development and Application of Electrode for a New Secondary Aqueous Cell (새로운 수용성 2차 전지용 전극의 개발과 응용)

  • Hwang, Kum-Sho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.41 no.2
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    • pp.165-170
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    • 2005
  • Al-Zn alloy/$MnO_2$, seawater cell was considered as a primary aqueous cell with an average voltage range from 1.0 to 1.1V, and the electrolyte of seawater was uptaken into the cell. Eventually, the capacity of its usage will be used for long-term. However, the more use of this cell, the higher corrosion phenomenon of the electrode occurred. Due to its corrosion phenomenon, one main default has been observed with gradual decrease during a discharge process. In this research, a common-used active material for anode was $LiNiO_2$. An active material for cathode, $Zn_{X}FeS_2$ was synthesized in high temperature by uptaken a small amount of 1.3 wt% of ZnS into $FeS_2$, one of the transition-metal dichalcogenides in high temperature. Consequently, based on their usages shown above, this secondary aqueous lithium cell could be more developed. This cell was shown as remarkable charge/discharge performance during the charge/discharge processes. This cathode with active material was given a considerable efficiency of inserting $Li^+$ ions. Moreever, in accordance with the characteristic of the crystal structure for $Zn_{x}FeS_2$, a small amount of ZnS was added which made it possible to reduce prominently velocity of corrosion during the charge/discharge cycle. By applying those merits, Al-Zn alloy/$MnO_2$ seawater cell will be used as a fundamental data in order to transform into a secondary aqueous cell.

A Study on the Removal Method of Radioactive Corrosion Product using its Magnetic Property (방사성 부식생성물의 자기적 성질을 이용한 제거방법에 대한 연구)

  • 송민철;공태영;이건재
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.73-79
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    • 2003
  • In a pressurized water reactor, radioactive corrosion products (CRUD) in primary coolant system are one of the major sources for the occupational radiation exposure of the personnel in a nuclear power plant. Through the recent trend of long term fuel cycle in a nuclear power Plant, radioactive corrosion products deposited in reactor core for a long time are also the cause of Axial Offset Anomaly (AOA) having m effect on reactor power by the hideout of boron. CRUD consist primarily of magnetite, nickel ferrite, cobalt ferrite, and so on. They have the characteristic of strong magnetism. Therefore it is performed the conceptual design to develop the filter which removes the CRUD by magnetic field that is generated by an arrangement of permanent and electric magnets. Contrary to the conventional filter, the proposed filter does not interrupt the fluid flow, so there is little pressure drop and it can be used continuously. It is expected to be applied as one of the technologies for removal of the CRUB.

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A STUDY ON THE CORROSION BEHAVIOUR OF AMALGAMS BY USING OF POTENTIOSTATIC POLARIZATION METHOD (정전압 분극곡선법에 의한 아말감의 부식 거동에 관한 연구)

  • Shin, Dong-Hoon;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.12 no.1
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    • pp.39-49
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    • 1986
  • The purpose of this study was to observe characteristic properties through the polarization curves and SEM images from 4 different types of amalgam obtained by using the potentiostats (Princeton EG & G) & SEM (Jeol/35), and to investigate the degree of corrosion on the oxidation peak of the each phase of amalgam. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of the mechanical amalgamator (Shofu Co.), the triturated mass was inserted into the cylindrical metal mold which was 12mm in diameter and 10.0mm in height and was condensed by using routine manner. The specimen was removed from the mold and stored at room temperature for about 24 hours. The standard surface preparation was routinely carried out. Anodic polarization measurement was employed to confirm the corrosion behaviour of the amalgams in a 0.9% saline solution (P.H: 6.8-7.0) at $37^{\circ}C$. The initial rest potential (corrosion potential) was determined after 30 minutes of immersion of specimen in electrolyte, and the potential scan was begun at the point of 100mV cathodic from the corrosion potential. The scan rate was 0.17mV/sec. in the study to observe the degree of corrosion of each phase. SEI and EPMA images on the determined oxidation peaks of each amalgam were observed. The results were as follows: 1. In the four anodic polarization curves, low copper amalgams have three oxidation peaks and high copper amalgams have two oxidation peaks, -270mV, +26mV and +179mV(SEC) in the low copper lathe cut, and -300mV, +39mV and +163mV(SEC) in the low copper spherical. -4mV and +154mV(SEC) in the Dispersalloy, and +17mV and +180mV(SEC) in the Tytin as high copper amalgams. 2. ${\gamma}_2$ phase in the low copper amalgam and ${\eta}$ phase in the high copper amalgam were the most corrodible phases and Ag-Cu eutectic in high copper amalgam was the most slowly corroded phase. 3. Low copper amalgam was more susceptible in corrosion than high copper amalgam.

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Study on Characteristics and Features of Re-corrosion on Archaeological Iron Nails after Conservation Treatments (철제관정의 보존처리 후 재부식 양상 및 특성 연구)

  • Lee, Hyeyoun;Park, Hyungho;Kim, Sujung;Yu, Jaeeun
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.343-351
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    • 2012
  • Excavated archaeological iron objects are prevented from being corroded going through desalination which slow down being corroded. However archaeological iron objects are liable to be corroded due to the high ionization tendency even though they are stored in environment restricted from corrosion factors. Iron objects could be deteriorated more than just excavated. Therefore this study investigated about the characteristic of re-corrosion and the effect on objects. In study, archaeological iron nails in storage for 4 years after conservation treatments were tested. Optical microscopy and X-ray photography for appearance, XRD, SEM-EDS, Raman spectroscopy for chemical composition, IC for chloride ions concentration inside iron nails were used. As results, iron nails carried out conservation treatments measured a high concentration of chloride ions after the long storage period. The form of objects were not in good condition such as broken or destroyed when the high chloride ions concentration was detected. In addition, the yellow and red powdery corrosion product were detected on the boundary between corrosion products and substrates and they were identified as akaganeite which is symptom of active corrosion.

Chloride Threshold Value for Steel Corrosion considering Chemical Properties of Concrete (콘크리트의 화학적 특성을 고려한 철근 부식 임계 염소이온 농도)

  • Song, Ha-Won;Jung, Min-Sun;Ann, Ki Yong;Lee, Chang-Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.75-84
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    • 2009
  • The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

Characteristic of Chloride ion Diffusion in Mortar According to the Substitution Ratios of the Additive (혼합재 치환율에 따른 모르타르의 염소이온 확산 특성)

  • 양승규;정연식;이웅종;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.17-22
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    • 2002
  • Chloride ions have a tendency to penetrate into concrete and proceed the corrosion by depassivating rebar surface. Thus the deteriorated concrete is subject to experience severe degrading of durability under marine environment. Physical properties of mortar, such as, compressive strength and penetration depth of chloride ion were investigated. And to investigate the effect of containing SG, FA in mortar, the diffusion coefficient of chloride was measured through an electro - migration test. The diffusion coefficient of chloride was decreased with the increase of replacement ratio of SG compared with plain specimen.

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A study about an old age car performance characteristic (노후차량 성능 특성에 관한 연구)

  • Hong Yong-Ki;Kwon Sung-Tae
    • Proceedings of the KSR Conference
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    • 2005.11a
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    • pp.332-337
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    • 2005
  • In order to investigate performance changes, the acceleration, vibration, and braking performance tests were carried out on the electric multiple units (EMUs) with over 20 years operation. According to the testing results, in vibration and braking performance, the similar performance results were obtained as compared with newly manufactured EMUs. However, in terms of acceleration performance, below reference value (3.0 km/h/s) has been obtained. This is mainly due to performance deterioration including traction motor. The precision diagnosis evaluation of deteriorated EMUs will be provided through the overall evaluation of corrosion testing and structural performance of car body.

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