• Title/Summary/Keyword: Corrosion Protection

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The effect of inhibitors affecting to corrosion behaviors and hydrogen embrittlement behaviors due to over-propection of a 4340 steel in 3% NaCl solution (3% NaCl용액중에 있어서 4340강의 부식거동과 과방식에 의한 수소포화거동에 미치는 인히비타의 영향)

  • 문경만;백태실;이상태
    • Journal of Advanced Marine Engineering and Technology
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    • v.13 no.4
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    • pp.54-62
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    • 1989
  • When some kinds of inhibitors, i.e. $1{\times}10{-3}mol/l$ arsenic trioxide, 0.2 mol/l 2-mercaptoethanol, 0.2mol/l thiourea were added to 3% NaCl solution, there were some considererable effects to decrease corrosion current density in natural potential condition and the effect fo solution temperature increasing corrosion rate was smaller than that of no addition to 3% NaCl solution. However the susceptibility of hydrogen embrittlement due to over-protection in case of cathodic protection was much greater than that of no addition, especially was the greatest in case of addition of 2-mercaptoethanol. Therefore adding inhibitors for anti-corrosion effect, it is suggested that selection of the optimum protection potential is important from the view point of prevention against hydrogen embrittlement due to over-protection in case of cathodic protection.

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Optimum Cathodic Protection for Stainless Steel Shaft of Small-Size Boat (소형선박용 스테인리스강 축의 음극방식 응용)

  • Bae, I.Y.;Park, J.D.;Kang, D.S.;Lee, M.H.;Kim, K.J.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.232-233
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    • 2005
  • Stainless steel has been stably used closed by passivity oxidation films($Cr_2O_3$) is made by neutral atmospheric environment. However, passivity oxidation films of the surface of stainless steel occasionally comes to be destroyed in seawater which is influenced by an environment having halogen ion like $Cl^-$, then, localization corrosion comes to occur. Stainless steel 304 for shaft system material of the small-size FRP fishing boat on seawater environments made an experiment on simulation of sacrifical anode(Al, Zn). Through these experiment and study, following results have been obtained ; According to the field inspection and corrosion simulation, the corrosion on the 2nd class stainless steel shaft(STS 304) in FRP fishing boat has been verified to occur by crevice corrosion and galvanic corrosion etc.. According to the comparison and analysis of Stainless steel 304 shaft materials after simulation leaving unprotected and applying cathodic protection, unprotected shaft specimen of stainless steel 304 was severely corroded, but, protected shaft specimen was not totally corroded. This result is assumed to be made by the facts that anodic reaction, $Fe{\rightarrow}Fe^{2+}$ + $2e^-$, has been restricted by the cathodic protection current of sacrificial anode material.

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Effect of Additional Ag Layer on Corrosion Protection of Cu-Electrodeposited AZ31 Mg Alloy

  • Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.97-97
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    • 2017
  • This study investigated the corrosion protection by electrodeposited copper layer on AZ31 Mg alloy with and without additional silver layer by immersion test, salt spray test, OCP transient and potentiodynamic polarization experiment. The single electrodeposited Cu layer on AZ31 Mg alloy showed a nodular structure with many imperfections of crevices between the nodules, which resulted in the fast initiation of pitting corrosion within first few hours of immersion. Double-layer coating of Cu and outer Ag layer slightly increased the initiation time for pitting corrosion. Triple-layer coatings of Cu/Ag/Cu exhibited the most efficient corrosion protection of AZ31 Mg alloy, compared to the single- and double-layer coatings. Surface morphology of the outer Cu layer in the triple-layer was changed from the nodular structure to fine particle structure with no crevices due to the presence of an additional Ag layer. Thus, the improved corrosion resistance of AZ31 Mg alloy by electrodeposited Cu/Ag or Cu/Ag/Cu layers is readily ascribed to the decreased number of imperfections in the electrodeposited layers due to the additional silver layer. It is concluded that the additional silver layer provides many nucleation sites for the second Cu plating, resulting in the formation of finer and denser structure than the first Cu electrodeposit.

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Practical Experiences with Corrosion Protection of Water Intake Gates in Mekong River

  • Phong, Truong Hong;Tru, Nguyen Nhi;Han, Le Quang
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.328-331
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    • 2008
  • Corrosion behaviour of water intake gate steel structures with different protective measures was investigated. Five material alternatives were taken for investigation, including: imported and recycled stainless steel, carbon steel with hot zinc spraying, painting and composite coatings. Results of corrosion rate for carbon steel, SUS 304, hot zinc spray coats in three water systems of Mekong river basin (saline, blackish and fresh) were also presented. Corrosion rate of carbon steel decreased with decreasing salinity in the investigated water environments. Meanwhile, these values for zinc coated steel, behaved by another way. Environmental data for these systems were filed and discussed in relation with corrosion characteristics. Method of Life Cycle Assessment (LCA) was applied in materials selection for water intake gate construction. From point of Life Cycle Cost (LCA) the following ranking was obtained: Zinc sprayed steel < Recycled stainless steel < Composite coated steel < Painting steel < SUS 304 From investigated results, hot zinc spray coating has been applied as protective measure for steel structures of water intake systems in Mekong river basin.

An Experimental Study on the Application of Cathodic Protection By Applying Zn-Al Metal Spray to an RC Structure (철근콘크리트 구조물에 Zn-Al 금속용사 전기방식 공법의 적용성에 관한 실험적 연구)

  • Han, Man-Hae;Yoo, Jo-Hyeong;Lim, Young-Chul;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.5
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    • pp.21-29
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    • 2010
  • Cathodic Protection has been introduced as a method of protecting metals under the ground or sea from corrosion. Since 1970, it has been applied to reinforced concrete structures as a corrosion protection method. After 1990, it became used around the world, and its usability has been well confirmed. But this method has some problems in terms of construction and economy. To solve these problems, a Cathodic Protection Method using a highly-durable metal spray was developed. First, the specimen was covered with anodic materials (Zn, Al) by using metal spray. The corrosion protection performance was confirmed by measuring the corrosion current of the specimen. Through the experiment, it is possible to confirm that the Cathodic Protection Method using a high metal spray provides effective protection against corrosion to reinforced concrete structures.

Engineering Technology Far-end Telecontrol Cathodic Protection on the Structure of Jetty Bridge Cap Beams

  • Liu, Yi-Hsiung;Lim, Pau-Yee;Shih, Chien-Chis
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.47-52
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    • 2003
  • 23 cap beams on the 1 Km length jetty bridge in Shin-da power plant (Taipower co., Taiwan) utilize far-end telecontrol cathodic protection technology which is the first case ever used in Taiwan. The system comprises cathodic protection system and te1econtrol monitoring system. The control and monitoring such as protection current adjustment, protection potential and depolarization measurement of the 23 cap beams can be adjusted through system telecontrol operations. Thereby allows monitoring and control of the 23 anode zones in a convenient and cost effective way. This system is at present still in its best running condition since Sept. 1997 when it was completed. All the 23 cap beams can achieve the 100 mV depolarization potential criteria of protection. It meet the specifications of reinforced concrete cathodic protection standard and proved to be very excellent.

Effects of Weld Fume on the Corrosion Protection of Epoxy Coated on Carbon Steel

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.10 no.3
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    • pp.80-86
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    • 2011
  • Welding was widely used in shipbuilding industries as a joining method. In present study, the effects of welding fume contaminated on steel surface on corrosion protection were examined by water ballast simulation test and condensation chamber test. Pull-off adhesion test, blistering test and cathodic disbondment test were carried out to evaluate the effects of residual welding fume. Consequently, it was clearly indicated that the residual welding fume didn't affect the corrosion protection of epoxy coated on steel when surface was treated by light sweep blasting to heavy sweep blasting which was applied in this study.

Research of Steel Corrosion and Corrosion Protection System for Reinforcing Steels in Concrete Exposed to Chloride Environments. (염해환경하 철근콘크리트의 철근 부식 및 방식기법 연구)

  • 문홍식;이상국;송호진;정영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.653-658
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    • 2001
  • Recent long-span bridges, such as Kwang-Ahn Grand bridge, Seo-Hae Grand Bridge, Young-Jong Grand Bridge, etc, have been designed and constructed near the shore. Thus, it needs to analyze the durability of marine concrete structures which are exposed to severe chloride environments. It is well known that corrosion of reinforcement steel in concrete is one of the major factors for the durability of concrete structures. The objective of this experimental study is to investigate the performance of impressed current system and corrosion inhibitors for the corrosion protection of reinforced concrete structures. Concrete test specimens were made with various test parameters, such as cover depth, steel diameter, compressive strength, direction and frequency of notch. For the efficient evaluation of these corrosion protection systems, these tests have been carried out in the shore.

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Study on The Corrosion Inhibition Characteristics of Carbon Steel by Sodium Phosphate And Sodium Nitrite (삼인산 나트륨과 아질산 나트륨에 의한 탄소강 부식방지 특성 연구)

  • Moon, Jeon-Soo;Lee, Jae-Kun
    • Corrosion Science and Technology
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    • v.9 no.3
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    • pp.137-141
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    • 2010
  • Sodium nitrite is widely used as one of the popular corrosion inhibitors for the protection of ferrous metal in closed cooling water system, such as a diesel engine and a chiller. The optimum treatment conditions are studied through laboratory tests using linear polarization resistance (LPR) technique. Corrosion rate of the carbon steel electrode could be maintained less than $2.5{\times}10^{-3}$ mmpy in the test condition of 500 ppm as ${NO_2}^-$, 200 ppm as $Cl^-$, $70^{\circ}C$ and pH 6.8. The pH control is confirmed not to be an important factor in the protection of carbon steel by sodium nitrite inhibitor. The addition of tolyltriazole was needed for the protection of the copper alloy in the sodium nitrite treatment system.

The Remote Wireless Corrosion Monitoring System for Water Pipeline (상수도 배관용 무선 원격 부식모니터링 시스템)

  • Ha, Tae-Hyeon;Bae, Jeong-Hyo;Lee, Hyeon-Gu;Ha, Yun-Cheol;Kim, Dae-Gyeong
    • Proceedings of the KIEE Conference
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    • 2003.11c
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    • pp.637-640
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    • 2003
  • The owner of water pipeline has a burden of responsibility for the protection of corrosion and the prevention against leakage of water. So, they have been installed a CP(Cathodic Protection) System in oder to protect corrosion. And they also have been measured and analyzed the data about P/S(Pipe to Soil) potential of water pipeline. The P/S potential is basic data of evaluation for water pipeline corrosion. In this paper, results of development about remote wireless corrosion monitoring system for water pipe line are presented briefly.

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