• Title/Summary/Keyword: Corrosion Product

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A Study on Fouling Phenomena of in Petroleum Chemical Process (석유화학공정내에서 원유의 파울링 현상에 관한 연구)

  • Lee, Dong Rak;Ryu, Sang Ryoun;Park, Sang Jin;Cho, Wook Sang;Kim, Sang Wook
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.443-452
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    • 1996
  • Fouling is caused by sedimentation and corrosion of polymer, heavy paraffine, chemicals, heavy organics, asphaltene, etc. in the entire chemical process of heat exchanger, boiler, desalter, etc. Fouling phenomena remains a serious operating problem which results in increased energy consumption, increased pressure drops, reduction or complete loss of products yield, and increased maintenance costs. In order to calculate the separated amounts of foulants and to control the fouling process, the predictive model is developed which is based on Scott & Magat polymer solution theory, Peng-Robinson EOS, BWR EOS, and continuous and multicomponent thermodynamics.

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A Study on the high Temperature Properties of the Graded Thermal Barrier Coatings by APS and PAS (APS법으로 제조된 열장벽 피막과 PAS법으로 제조된 열장벽 성형체의 고온 물성에 관한 연구)

  • 강현욱;권현옥;한주철;송요승;홍상희;허성강;김선화
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.144-156
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    • 1999
  • Thermal Barrier Coating with Functional Gradient Materials (FGM-TBC) can play an important role to protect the parts from harmful environments in high temperatures such as oxidation, corrosion, and wear and to improve the efficiency of aircraft engine by lowering the surface temperature on turbine blade. FGM-TBC can increase the life spans of product and improve the operating properties. Therfore, in this study the evaluations of mechanical and thermal properties of FGM-TBC such as fatigue, oxidation and wear-resistance at high temperatures have been conducted. The samples of both the TBC with 2, 3, 5 layers (YSZ/NiCrAlY) to be produced by Air Plasma Spray method (APS) and the bulk TBC with 6 layers to be produced by Plasma Assisted Sintering method (PAS) were used. Furthermore, residual stress, bond strength, and thermal conductivity were evaluated. The average thickness of the APS was 500$\mu\textrm{m}$ to 600$\mu\textrm{m}$ and the average thickness of the PAS was 3mm. The hardness number of the top layer of APS was 750 Hv to 810Hv and that of PAS was 950 Hv to 1440Hv. The $ZrO_2$ coating layer of APS was composed of tetragonal structure after spraying as the result of XRD analysis. As shown in the results of the high temperature wear test, the 3 layer coating of APS had the best wear resistance at $800^{\circ}C$ and the 5 layer coating of APS had the best wear resistance at $600^{\circ}C$. But, these coatings had the tendency of the low-temperature softening at $300^{\circ}C$. The main mechanism of wear was the adhesive wear and the friction coefficient of coatings was increased as increasing the test temperatures. A s results of thermal conductivity test, the ${\Delta}T$ of the APS coating was increased as number of layer and the range of thermal conductivity of the PAS was $800^{\circ}C$ to $1000^{\circ}C$.

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An Improvement of Quality Standard and Construction Quality Control for Field Application of Epoxy-Coated Reinforcing Bars (에폭시 피복철근 현장적용을 위한 품질 기준 및 시공품질관리 개선에 관한 연구)

  • Jung, Chan-Gu;Jung, Hie-Young;Kim, Jee-Sang;Shim, Sung-Pho;Shim, Jin-Ah
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.190-198
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    • 2018
  • The Epoxy-coated Reinforcing bars have been proved to be able to extend a durability life because of its excellent corrosion resistance in bridges and structures under marine and severe environments. The usage of epoxy-coated reinforcement is continuously increasing in developed countries such as the US and Japan. However, domestic use is extremely limited due to lack of research and development, poor production facilities, low quality, increase of initial costs, and difficulty of field management. This study suggests the improvement of construction quality management such as manufacturing, transportation and construction for the field application through the test construction of the proven product in the related test results of the epoxy coated steel bars produced in the recently improved manufacturing facility.

Improvement of Ammunition Box by Ergonomic Evaluation

  • Lee, Kyung-Sun;Kim, Sung-Hoon;Seo, Song-Won;Jung, Myung-Chul
    • Journal of the Ergonomics Society of Korea
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    • v.34 no.1
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    • pp.1-10
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    • 2015
  • Objective: The purpose of this paper is to evaluate old and newly designed ammunition boxes from an ergonomic point of view. Background: The ammunition boxes made of wood, which are currently used by the military, have some difficulties such as corrosion and damage of ammunition, environmental pollution, and stock management. Also, damages to the wooden ammunition boxes take place frequently, because soldiers carry them manually. Method: Sixteen participants volunteered to randomly perform lifting, carrying, and side-by-side moving tasks with 4 different old and new boxes, respectively for the ammunitions of 5.56mm, 60mm, 81mm, and 105mm in diameter. The old boxes are made of wood and are currently used in the military, while the new boxes are made of plastics. The joint moments of the elbow, shoulder, back, and knee were measured by using a motion analysis system and force platforms. In addition, an electromyographic system was used to measure the forces of hand and wrist muscles. Results: In most tasks, new boxes caused less joint moments at the elbow and shoulder than old boxes, because the new boxes were lighter and smaller than the old boxes. New boxes also derived less hand and wrist muscle forces due to the provision of fixed hard handles rather than string handles. Conclusion: The ergonomically designed new boxes could reduce the physical stresses of soldiers manually handling ammunitions and be helpful for storage and reuse. Application: This study shows an ergonomic application example for product development and evaluation.

The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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A study on minimum weight design of vertical corrugated bulkheads for chemical tankers

  • Shin, Sang-Hoon;Ko, Dae-Eun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.10 no.2
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    • pp.180-187
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    • 2018
  • Corrugated bulkhead has been adopted for cargo tank bulkheads of commercial vessels such as bulk carriers, product oil carriers and chemical tankers. It is considered that corrugated bulkhead is a preferred structural solution, compared to the flat stiffened bulkhead, due to several advantages such as lower mass, easier maintenance and smaller corrosion problems. Many researches to find the optimum shape of corrugated bulkhead have been mostly carried out for bulk carriers. Compared to corrugated bulkheads of bulk carriers, ones of chemical tankers are more complicated since they are composed of transverse and longitudinal bulkheads, and they are made of higher priced materials. The purpose of this study is the development of minimum weight design method for corrugated bulkhead of chemical tankers. Evolution strategy is applied as an optimization technique. It has been verified from many researches that evolution strategy searches global optimum point prominently by using multi-individual searching technique. Multi-individual searching methods need excessive time if they connect to 3-D finite element model for repetitive structural analyses. In order to resolve this issue, 2-D beam element connected to deck and lower stool is substituted for a corrugated structure in this study. To verify the reliability of the structural responses by idealized 2-D beam model, they have been compared with ones by 3-D finite element model. In this study, optimum design for corrugated bulkhead of 30 K chemical tanker has been carried out, and the results by developed optimum design program have been compared with design data of existing ship. It is found out that optimum design is about 9% lighter than one of existing ship.

Study on the effect of long-term high temperature irradiation on TRISO fuel

  • Shaimerdenov, Asset;Gizatulin, Shamil;Dyussambayev, Daulet;Askerbekov, Saulet;Ueta, Shohei;Aihara, Jun;Shibata, Taiju;Sakaba, Nariaki
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2792-2800
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    • 2022
  • In the core of the WWR-K reactor, a long-term irradiation of tristructural isotopic (TRISO)-coated fuel particles (CFPs) with a UO2 kernel was carried out under high-temperature gas-cooled reactor (HTGR)-like operating conditions. The temperature of this TRISO fuel during irradiation varied in the range of 950-1100 ℃. A fission per initial metal atom (FIMA) of uranium burnup of 9.9% was reached. The release of gaseous fission products was measured in-pile. The release-to-birth ratio (R/B) for the fission product isotopes was calculated. Aspects of fuel safety while achieving deep fuel burnup are important and relevant, including maintaining the integrity of the fuel coatings. The main mechanisms of fuel failure are kernel migration, silicon carbide corrosion by palladium, and gas pressure increase inside the CFP. The formation of gaseous fission products and carbon monoxide leads to an increase in the internal pressure in the CFP, which is a dominant failure mechanism of the coatings under this level of burnup. Irradiated fuel compacts were subjected to electric dissociation to isolate the CFPs from the fuel compacts. In addition, nondestructive methods, such as X-ray radiography and gamma spectrometry, were used. The predicted R/B ratio was evaluated using the fission gas release model developed in the high-temperature test reactor (HTTR) project. In the model, both the through-coatings of failed CFPs and as-fabricated uranium contamination were assumed to be sources of the fission gas. The obtained R/B ratio for gaseous fission products allows the finalization and validation of the model for the release of fission products from the CFPs and fuel compacts. The success of the integrity of TRISO fuel irradiated at approximately 9.9% FIMA was demonstrated. A low fuel failure fraction and R/B ratios indicated good performance and reliability of the studied TRISO fuel.

Development of GDL-carbon Composite Bipolar Plate Assemblies for PEMFC (PEM 연료전지용 가스확산층-탄소 복합재료 분리판 조합체 개발)

  • Lim, Jun Woo
    • Composites Research
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    • v.34 no.6
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    • pp.406-411
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    • 2021
  • PEM (proton exchange membrane) fuel cells generate only water as a by-product, and thus are in the spotlight as an eco-friendly energy source. Among the various components composing the stack of the fuel cell, research on the bipolar plate that determines the efficiency of the fuel cell is being actively conducted. The composite bipolar plate has high strength, rigidity and corrosion resistance, but has the disadvantage of having a relatively low electrical conductivity. In this study, to overcome these shortcomings, a gas diffusion layer (GDL)-composite bipolar plate assembly was developed and its performance was experimentally verified. The graphite foil coating method developed in the previous study was applied to reduce the contact resistance between the bipolar plate and the GDL. In addition, in order to improve electron path in the stack and minimize the contact resistance between the GDL and the bipolar plate, a GDL-bipolar plate assembly was fabricated using a thin metal foil. As a result of the experiment, it was confirmed that the developed GDL-bipolar plate assembly had 98% lower electrical resistance compared to the conventional composite bipolar plate.

A numerical study on feasibility of the circled fiber reinforced polymer (FRP) panel for a tunnel lining structure (터널 라이닝 구조체로서 곡면 섬유강화 복합재료의 적용성 검토를 위한 수치해석적 연구)

  • Lee, Gyu-Phil;Shin, Hyu-Soung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.12 no.6
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    • pp.451-461
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    • 2010
  • Utilization of the fiber reinforced polymer (FRP) material has been enlarged as a substitution material to the general construction materials having certain long-term problems such as corrosion, etc. However, it could be difficult to apply the FRP material, which has a linear shape generally, to an arch-shaped tunnel structure. Therefore, an attempt has been made in this study to develop a device to form a designed cross section of FRP material by pulling out with a curvature. A sample of the circled FRP product was successfully produced and then the sample has been tested to identify its physical characteristics. Then, intensive feasibility studies on the circled FRP panel to be used for a tunnel lining structure have been carried out by numerical analyses. As a result, it appears that the new circled FRP-concrete composite panel has a high capability to be used for a tunnel lining material without any structural problem.

The Principles of Fractal Geometry and Its Applications for Pulp & Paper Industry (펄프·제지 산업에서의 프랙탈 기하 원리 및 그 응용)

  • Ko, Young Chan;Park, Jong-Moon;Shin, Soo-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.177-186
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    • 2015
  • Until Mandelbrot introduced the concept of fractal geometry and fractal dimension in early 1970s, it has been generally considered that the geometry of nature should be too complex and irregular to describe analytically or mathematically. Here fractal dimension indicates a non-integer number such as 0.5, 1.5, or 2.5 instead of only integers used in the traditional Euclidean geometry, i.e., 0 for point, 1 for line, 2 for area, and 3 for volume. Since his pioneering work on fractal geometry, the geometry of nature has been found fractal. Mandelbrot introduced the concept of fractal geometry. For example, fractal geometry has been found in mountains, coastlines, clouds, lightning, earthquakes, turbulence, trees and plants. Even human organs are found to be fractal. This suggests that the fractal geometry should be the law for Nature rather than the exception. Fractal geometry has a hierarchical structure consisting of the elements having the same shape, but the different sizes from the largest to the smallest. Thus, fractal geometry can be characterized by the similarity and hierarchical structure. A process requires driving energy to proceed. Otherwise, the process would stop. A hierarchical structure is considered ideal to generate such driving force. This explains why natural process or phenomena such as lightning, thunderstorm, earth quakes, and turbulence has fractal geometry. It would not be surprising to find that even the human organs such as the brain, the lung, and the circulatory system have fractal geometry. Until now, a normal frequency distribution (or Gaussian frequency distribution) has been commonly used to describe frequencies of an object. However, a log-normal frequency distribution has been most frequently found in natural phenomena and chemical processes such as corrosion and coagulation. It can be mathematically shown that if an object has a log-normal frequency distribution, it has fractal geometry. In other words, these two go hand in hand. Lastly, applying fractal principles is discussed, focusing on pulp and paper industry. The principles should be applicable to characterizing surface roughness, particle size distributions, and formation. They should be also applicable to wet-end chemistry for ideal mixing, felt and fabric design for papermaking process, dewatering, drying, creping, and post-converting such as laminating, embossing, and printing.