• 한국산학기술학회논문지
• /
• 제13권4호
• /
• pp.1915-1922
• /
• 2012

본 연구는 SBA-15, MCM-41, MCM-48, KIT-6와 같은 메조포러스실리카를 다양한 조건에서 합성하고 이를 이용하여 CMK(Carbon Mesoporous Korea)를 합성한다. 합성된 CMK를 이용하여 메조포러스 구조의 전이금속체를 제조하였다. 각각의 메조포러스실리카에 따라 합성된 CMK의 특성을 분석하고 이를 이용하여 합성된 메조포러스 전이금속체의 특성을 질소흡탈착 등온선, SEM, 저각 X-선 회절분석으로 분석하므로써 최적의 메조포러스 전이금속체의 합성조건을 도출하였다, 실험 결과 가장 우수한 특성을 나타내는 메조실리카는 SBA-15이며, BET 분석으로 SBA-15로부터 합성된 메조포러스 구리 분자체의 비표면적은 $225m^2/g$, 기공크기는 2.91nm로 나타났다.

• Carbon letters
• /
• 제13권2호
• /
• pp.109-114
• /
• 2012

A nuclear, biological, chemical (NBC) canister was indigenously developed using active carbon impregnated with ammoniacal salts of copper (II), chromium (VI) and silver (I), and high efficiency particulate aerosol filter media. The NBC canister was evaluated against carbon tetra chloride ($CCl_4$) vapours, which were used as a simulant for persistent chemical warfare agents under dynamic conditions for testing breakthrough times of canisters of gas masks in the National Approval Test of Respirators. The effects of $CCl_4$ concentration, test flow rate, temperature, and relative humidity (RH) on the breakthrough time of the NBC canister against $CCl_4$ vapour were also studied. The impregnated carbon that filled the NBC canister was characterized for surface area and pore volume by $N_2$ adsorption-desorption isotherm at liquid nitrogen temperature. The study clearly indicated that the NBC canister provides adequate protection against $CCl_4$ vapours. The breakthrough time decreased with the increase of the $CCl_4$ concentration and flow rate. The variation in temperature and RH did not significantly affect the breakthrough behaviour of the NBC canister at high vapour concentration of $CCl_4$, whereas the breakthrough time of the NBC canister was reduced by an increase of RH at low $CCl_4$ vapour concentration.

• 한국지반신소재학회논문집
• /
• 제14권1호
• /
• pp.23-32
• /
• 2015

본 연구에서는 지반 내 오염원제거와 저투수성 지반의 개량이 동시에 이루어 질 수 있는 연직배수시스템의 최적화 기술을 마련하기 위하여, 중금속 오염물질을 대상으로 미세유체 흐름실험을 수행하였으며, 그 결과를 바탕으로 pH조건에 따른 흐름특성을 분석하였다. 중금속 오염물에 대한 미세유체 흐름실험 결과, 소수성 성질이 반영되는 위치가 오염물의 흐름속도에 큰 영향을 미치는 것으로 분석되었으며, pH 조건이 흐름속도 변화에 영향인자로 작용하였다. 또한 복합 중금속 오염물인 경우에 pH가 염기성일수록 납의 흐름속도가 다소 증가하는 경향으로 나타났는데, 이는 납 오염물이 구리에 비하여 소수성 표면특성을 감소시킬 수 있음을 의미하는 결과라 할 수 있다.

• 한국수소및신에너지학회논문집
• /
• 제7권2호
• /
• pp.157-164
• /
• 1996

The AB5-type metal hydride electrodes using $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$(LM : Lanthaniumrich Mischmetal) alloy powders(${\leq}200$mesh) which were coated with 25wt% copper in an acidic bath were prepared with or without addition of 10wt% PTFE as a binder. Prior to electrochemical measurements, the electrodes were sintered at $40^{\circ}C$ for 1 and 2hrs in vacuum with Mm(mischmetal) and sponge type Ti getters. The properties such as maximum capacity, cycle life and mechanical strength of the negative electrode have been investigated. The surface analysis of the electrode was also obtained before and after charge-discharge cycling using scanning electron microscope(SEM). From the observations of electrochemical behavior, it was found that the sintered electrode shows a lower maximum discharge capacity compared with non-sintered electrode but it shows a better cycle life. For the both electrodes with or without addition of PTFE binder, the values of mechanical strength were obtained, and their values increased with increasing sintering time. However, there is little difference of discharge capacity for both electrodes.

• Transactions on Electrical and Electronic Materials
• /
• 제8권1호
• /
• pp.5-10
• /
• 2007

Using a reference slurry, ammonium dodecyl sulfate (ADS), an anionic and environmentally friendly surfactant, was investigated as an alternative to BTA for its inhibition and lubrication characteristics. Results demonstrated that the inhibition efficiency of ADS was superior to that of BTA. Coefficient of friction (COF) was the lowest when the slurry contained ADS. This suggested that adsorbed ADS on the surface provided lubricating action thereby reducing the wear between the contacting surfaces. Temperature results were consistent with the COF and removal rate data. ADS showed the lowest temperature rise again confirming the softening effect of the adsorbed surfactant layer and less energy dissipation due to friction. Spectral analysis of shear force showed that increasing the pad-wafer sliding velocity at constant wafer pressure shifted the high frequency spectral peaks to lower frequencies while increasing the variance of the frictional force. Addition of ADS reduced the fluctuating component of the shear force and the extent of the pre-existing stick-slip phenomena caused by the kinematics of the process and collision event between pad asperities with the wafer. By contrast, in the case of BTA, there were no such observed benefits but instead undesirable effects were seen at some polishing conditions. This work underscored the importance of real-time force spectroscopy in elucidating the adsorption, lubrication and inhibition of additives in slurries in CMP.

• Composites Research
• /
• 제12권6호
• /
• pp.22-30
• /
• 1999

$Nb_3Sn$ 복합초전도 테이프는 금속간 화합물로서 다른 초전도 재료에 비하여 임계밀도가 높아 MRI등에 널리 이용되고 있다. 한편 $Nb_3Sn$층은 화합물이므로 bending이나 winding등의 코아 제작시 테이프 도체에 응력이 작용하면 화합물층에 취성으로 인한 크랙이 발생하여 부분적으로 파단이 일어나 임계전류 특성이 열화하며 무응력 상태에 비하여 크게 저하된다. 따라서 이와 같은 $Nb_3Sn$복합초전도 테이프의 실질적인 적용을 위해서는 선재의 제조과정 뿐만 아니라 가동 중에 기계적 응력에 대한$Nb_3Sn$복합 초전도 테이프의 미시적 거동 특성을 필히 이해하여야 할 필요가 있다. 본 연구에서는 음향방출기법(Acoustic Emission)을 이용하여 $Nb_3Sn$ 복합초전도 테이프에 대해서 일정변형속도(constant extension rate)제어로 인장하중이 작용할 경우 발생하는 AE 신호특성과 이에 대응하는 각 화합물층의 미시적 변형거동 특성과의 상관관계를 분석하였다.

• Bulletin of the Korean Chemical Society
• /
• 제25권5호
• /
• pp.639-646
• /
• 2004

Metal treated activated carbons are prepared using various metals. Adsorption behaviors, morphologies, as well as antibacterial effects of metal treated samples are compared before and after solvent washing. Adsorption isotherms are used to characterize the porous structure of metal treated activated carbons before and after the solvent washing with acetone or ethyl alcohol. From these data, it is noticed that the changes in physicochemical properties of metal treated activated carbons depend on the solvents employed. Similar results are observed from BET data obtained from nitrogen adsorption isotherms. From scanning electron microscopy (SEM) studies, the changes in shape and size of metal particles are observed after the samples are washed with solvents. These changes result in different blocking effects, which, in turn, affect the adsorption behavior of metal treated activated carbons. X-ray diffraction (XRD) patterns of the samples treated with different metals are different each other. High intense sharp peaks attributed to metals are observed from silver treated samples, while the peaks are not observed from copper treated samples. To compare thermodynamic behavior of metal treated activated carbons washed with different type of solvents, differential scanning calorimetric (DSC) analysis is carried out. The analysis shows similar endothermic curves for all of the samples. Finally, antibacterial effects of metal treated activated carbon against Escherichia coli are discussed. Comparing the effects among the metals employed, highest effects are obtained from Cd, while lowest effects are obtained from Cu. Antibacterial activity becomes higher with the increase of the amount of metals treated, Optimum concentrations of metals to treat activated carbons, obtained from a shake flask test, are known to be 0.4, 0.1, and 0.6 moles for Ag, Cd, and Cu, respectively.

• 대한화학회지
• /
• 제57권4호
• /
• pp.483-488
• /
• 2013

$CuCl_2$로부터 용액합성법에 의해 CuO를 제조하였다. $CuCl_2$를 용액에 첨가하기 전에 용액내에 anatase형 $TiO_2$ 입자를 분산시켜 CuO가 형성되는 과정에서 $TiO_2$/CuO 결합입자를 합성하였다. 얻어진 $TiO_2$/CuO에 적당량의 글루코스를 가하여 반응시켜 CuO의 일부를 $Cu_2O$로 환원시켰다. 얻어진 시료 $TiO_2/Cu_xO$ (1$TiO_2/Cu_xO$ 복합체는 anatase와는 다르게 가시광선 전 영역에서 흡광이 발생했으며 당연한 결과로 태양광선에서 $TiO_2/Cu_xO$ 복합체의 광촉매 활성은 anatase $TiO_2$에 비하여 매우 뛰어난 것으로 나타났다. 또한 $TiO_2/Cu_xO$ 복합체의 항균성이 대단히 뛰어난 것으로 나타났다.

• 센서학회지
• /
• 제6권2호
• /
• pp.155-162
• /
• 1997

zinc acetate를 포함하는 용액으로부터 r-plane 사파이어 기판 위에 ZnO 막(膜)을 증착하였다. 초음파(超音波) 발생기(發生器)로 용액을 진동시켜 증기입자를 만든 후 이것을 고온 반응로(反應盧) 내에서 열분해(熱分解) 시켜 막(膜)을 증착하였다. 제조된 막(膜)의 결정성, 표면형태 및 조성을 XRD, SEM 및 AES로 각각 분석하였다. 기판온도가 막(膜)의 특성에 미치는 영향에 대해 조사하였다. 기판온도 $300^{\circ}C$에서 (110) 방향으로 강하게 성장된 막(膜)을 얻을 수 있었다. 구리의 첨가(添加)와 습식산화(濕式酸化)에 의해 막(膜)의 저항율을 $3{\times}10^{6}{\Omega}{\cdot}cm$이상으로 높일 수 있었다.

• 소성∙가공
• /
• 제20권7호
• /
• pp.473-478
• /
• 2011

In this study, the performance of a thermo siphon type radiator made of copper for LED lighting system was evaluated by using an inverse heat transfer method. Heating experiments and finite element heat transfer analysis were conducted for three different cases. The data obtained from experiments were compared with the analysis results. Based on the data obtained from experiments, the inverse heat transfer method was used in order to evaluate the heat transfer coefficient. First, the heat transfer analysis was conducted for non-vacuum state, without the refrigerant. The evaluated heat transfer coefficient on the radiator surface was 40W/$m^2^{\circ}C$. Second, the heat transfer analysis was conducted for non-vacuum state, with the refrigerant, resulting in the heat transfer coefficient of 95W/$m^2^{\circ}C$. Third, the heat transfer analysis was conducted for vacuum state, with refrigerant. For the third case, the evaluated heat transfer coefficients were 140W/$m^2^{\circ}C$. Third, the heat transfer analysis was conducted for vacuum state, with refrigerant. For the third case, the evaluated heat transfer coefficients were 140W/$m^2^{\circ}C$ for the radiator body, 5W/$m^2^{\circ}C$. Third, the heat transfer analysis was conducted for vacuum state, with refrigerant for the rising position of radiator pipe, 35W/$m^2^{\circ}C$. Third, the heat transfer analysis was conducted for vacuum state, with refrigerant. For the highest position of radiator pipe, and 120W/$m^2^{\circ}C$ for the downturn position of radiator pipe. As a result of inverse heat transfer analysis, it was confirmed that the thermal performance of the current radiator was best in the case of the vacuum state using the refrigerant.