• Title/Summary/Keyword: Copper growth

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The Blanket Deposition and the Sputter Seeding Effects on Substrates of the Chemically Vapor Deposited Cu Films (Sputter Seeding을 이용한 CVD Cu 박막의 비선택적 증착 및 기판의 영향)

  • Park, Jong-Man;Kim, Seok;Choi, Doo-Jin;Ko, Dae-Hong
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.827-835
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    • 1998
  • Blanket Copper films were chemically vapor deposited on six kinds for substrates for scrutinizing the change of characteristics induced by the difference of substrates and seeding layers. Both TiN/Si and {{{{ { SiO}_{2 } }}/Si wafers were used as-recevied and with the Cu-seeding layers of 40${\AA}$ and 160${\AA}$ which were produced by sputtering The CVD processes were exectued at the deposition temperatures between 130$^{\circ}C$ and 260$^{\circ}C$ us-ing (hfc)Cu(VTMS) as a precursor. The deposition rate of 40$^{\circ}C$ Cu-seeded substrates was higher than that of other substrates and especially in seeded {{{{ { SiO}_{2 } }}/Si substrate because of the incubation period reducing in-duced by seeding layer at the same deposition time and temperature. The resistivity of 160${\AA}$ Cu seeded substrate was lower then that of 40 ${\AA}$ because the nucleation and growth behavior in Cu-island is different from the behavior in {{{{ { SiO}_{2 } }} substrate due to the dielectricity of {{{{ { SiO}_{2 } }}.

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The Study for Adsorption of Indoor Pollutants by Ocher and Diatomite Filter (황토와 다공성 규조토 필터에 의한 실내 오염 물질의 흡착 연구)

  • Kim, Ho-Keun;Irodakhon, Akhmadalieva;Nam, Ki-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.4_2
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    • pp.583-591
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    • 2020
  • Environmental problems have showen over the past decades due to the rapid development of the world economy and the continued growth of the population. Ocher has been widely used for water treatment research, but few studies have been conducted on adsorption of air pollutants using ocher and porous diatomite earth for indoor air purification. In this study, ocher and diatomite earth were sintered with filters to remove indoor air pollutants. The four types of TMA, H2S, NH3 and CH3COOH were used to study the adsorption efficiency of ocher and porous diatomite filters. With the proper use of ocher, diatomite and copper catalysts, indoor air pollutants could be adsorbed. Alkaline substances (TMA and NH3) and acidic substances (H2S and CH3COOH) were able to adsorb at 120 and 90 minutes, respectively.

Crystallization and Electrical properties of $CuO-P_2O_5-V_2O_5$ Glass for solid state Electrolyte (고체 전해질용 $CuO-P_2O_5-V_2O_5$ 유리의 결정화와 전기 전도도)

  • Son, Myung-Mo;Lee, Heon-Soo;Chun, Yon-Soo;Gu, Hal-Bon;Lee, Sang-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.934-937
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    • 2003
  • Glasses in the system $CuO-P_2O_5-V_2O_5$ were prepared by a press-quenching method on the copper plate. The glass-ceramics from these glasses were obtained by post-heat treatment, and the crystallization behavior and DC conductivities were determined. The conductivities of the glasses were range from $10^{-6}s.Cm^{-1}$ at room temperature, but the conductivities of the glass-ceramics were $10^{-3}s.Cm^{-1}$ increased by $10^3$ order. The crystalline product in the glass-ceramics was $CuV_2O_6$. Heat-treatment conditions influenced the crystal growth of $CuV_2O_6$ and conductivity. The linear relationship between in (${\sigma}T$) and $T^{-1}$ suggested that the electrical conduction in the present glass-ceramics would be due to a small polaron hopping(SPH) mechanism.

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Primary metabolic responses in the leaves and roots of bell pepper plants subjected to microelements-deficient conditions

  • Sung, Jwakyung;Lee, Yejin;Lee, Seulbi
    • Korean Journal of Agricultural Science
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    • v.48 no.1
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    • pp.179-189
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    • 2021
  • Plants need essential mineral elements to favorably develop and to complete their life cycle. Despite the irreplaceable roles of microelements, they are often ignored due to the relative importance of macroelements with their influence on crop growth and development. We focused on the changes in primary metabolites in the leaves and roots of bell pepper plants under 6 microelements-deficient conditions: Copper (Cu), Zinc (Zn), Iron (Fe), Manganese (Mn), Boron (B) and Molybdenum (Mo). Bell pepper plants were grown in hydroponic containers, and individual elements were adjusted to 1/10-strength of Hoagland nutrient solution. A remarkable perturbation in the abundance of the primary metabolites was observed for the Fe and B and the Mn and B deficiencies in the leaves and roots, respectively. The metabolites with up-accumulation in the Fe-deficient leaves were glucose, fructose, xylose, glutamine, asparagine and serine. In contrast, the Mn deficiency also resulted in a higher accumulation of glucose, fructose, xylose, galactose, serine, glycine, β-alanine, alanine and valine in the roots. The B deficiency noticeably accumulated alanine, valine and phenylalanine in the roots while it showed a substantial decrease in glucose, fructose and xylose. These results show that the primary metabolism could be seriously disturbed due to a microelement deficiency, and the alteration may be either the specific or adaptive responses of bell pepper plants.

The Effect of SnO2 Addition on Sintering Behaviors in a Titanium Oxide-Copper Oxide System

  • Lee, Ju-Won;Oh, Kyung-Sik;Chung, Tai-Joo;Paek, Yeong-Kyeun
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.357-362
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    • 2022
  • The low-temperature sinterability of TiO2-CuO systems was investigated using a solid solution of SnO2. Sample powders were prepared through conventional ball milling of mixed raw powders. With the SnO2 content, the compositions of the samples were Ti1-xSnxO2-CuO(2 wt.%) in the range of x ≤ 0.08. Compared with the samples without SnO2 addition, the densification was enhanced when the samples were sintered at 900℃. The dominant mass transport mechanism seemed to be grain-boundary diffusion during heat treatment at 900℃, where active grain-boundary diffusion was responsible for the improved densification. The rapid grain growth featured by activated sintering was also obstructed with the addition of SnO2. This suggested that both CuO as an activator and SnO2 dopant synergistically reduced the sintering temperature of TiO2.

Effect of Brown Oxide Formation on the Fracture Toughness of Leadframe/EMC Interface (Brown Oxide 형성이 리드프레임/EMC 계면의 파괴인성치에 미치는 영향)

  • Lee, H.Y.;Yu, J.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.531-537
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    • 1999
  • A copper based leadframe was oxidized in brown-oxide forming solution, then the growth characteristics of brown oxide and the effect of brown-oxide formation on the adhesion strength of leadframe to epoxy molding compound (EMC) were studied by using sandwiched double cantilever beam (SDCB) specimens. The brown oxide is composed of fine acicular CuO, and its thickness increased up to ~150 nm within 2 minutes and saturated. Bare leadframe showed alomost no adhesion to EMC, while once the brown-oxide layer formed on the Surface of leadframe, the adhesion strength increased up to ~80 J/$\m^2$ within 2 minutes. Correlation between oxide thickness, $\delta$ and the adhesion strength in terms of interfacial fracture toughness, $G_{c}$ was linear. Considering the above results, we might conclude that the main adhesion mechanism of brown-oxide treated leadframe to EMC is mechanical interlocking, in which fine acicular CuO plays a major role.e.

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Discretized solenoid design of a 1.5 T and a 3.0 T REBCO whole-body MRI magnets with cost comparison according to magnetic flux

  • Wonju Jung;Geonyoung Kim;Kibum Choi;Hyunsoo Park;Seungyong Hahn
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.4
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    • pp.75-80
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    • 2023
  • Rare earth barium copper oxide (REBCO) materials have shown the possibility of high-temperature superconductor (HTS) magnetic resonance imaging (MRI) magnets due to their elevated transition temperature. While numerous MRI magnet designs have emerged, there is a growing emphasis on estimating the cost before manufacturing. In this paper, we propose two designs of REBCO whole-body MRI magnets: (1) 1.5 T and (2) 3.0 T, the standard center field choices for hospital use, and compare their costs based on conductor usage. The basis topology of the design method is based on discretized solenoids to enhance field homogeneity. Magnetic stress calculation is done to further prove the mechanical feasibility of their construction. Multi-width winding technique and outer notch structure are used to improve critical current characteristic. We apply consistent constraints for current margins, sizes, and field homogeneities to ensure an equal cost comparison. A graph is plotted to show the cost increase with magnetic flux growth. Additionally, we compare our designs to two additional MRI magnet designs from other publications with respect to the cost and magnetic flux, and present the linear relationship between them.

Agricultural Utilization of Paper Mill Sludge Manure Compost - II. Effects on the Growth of Carrot(Daucus carota L.) (제지(製紙) 스럿지 퇴비(堆肥)의 농업적(農業的) 이용연구 - II. 당근에 대(對)한 시용효과)

  • Chang, Ki-Woon;Kim, Sang-Deog;Choi, Woo-Young;Lee, Kyu-Seung
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.2
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    • pp.155-159
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    • 1992
  • This study was carried out to know the effects of two kinds of peper mill sludge manure compost(SMC-1 and SMC-2) on the growth and chemical comments of carrot(Daucus carota L.) : SMC-1 contained 18% of swine manure and 8 % of sawdust on a fresh weight basis and SMC-2 contained swine manure without sawdust a third of the total weight of the manure and S-0(control) was treated with chemical fertilizer only, S-1 and S-2 was with SMC-1 and SMC-2 respectively, in addition to the chemical fertilizer. Carrot treated with S-1 and S-2 showed the increasing tendency of fresh weight per root and fresh yield of carrot per unit area than control(S-0), and the contents of nitrogen(N), phosporus(P), potassium(K) and calcium(Ca) in carrot grown on SMC treatments were higher than those on control(S-0), The S-2 treatment tended to increase values of the fresh weight of live leaves, root diameter, fresh weight per root and fresh yield of carrot per unit area than S-1 treatment. The contents in carrot were higher in the order of K>Ca, N. P>Mg, and the contents of aluminium, zinc, copper and chromium were below the level of toxicity for plant growth, and the contents of cadmium and lead were negligible. From the results obtained, it can be said that SMC application showed favorable effects on the growth of carrot when compared to control(S-0), and with the SMC treatments SMC-2 aplication was favorable.

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Growth, Flowering, and Nutrient Composition of Salvia Grown in Peat moss Media Containing Pellets Processed with Poultry Feather Fibers at Different Mixing Ratios

  • Yoo, Yong Kwon;Kim, In Kyung;Roh, Mark S.;Roh, Yong Seung;Huda, Masud
    • Horticultural Science & Technology
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    • v.35 no.3
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    • pp.289-299
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    • 2017
  • The objective of this study was to determine the effect of replacing perlite (PL) with pellets processed with poultry feather fiber as an inert material to prepare growing medium. The growth and flowering of Salvia splendens 'Vista Red' grown in individual growing medium $Biosangto^{(R)}$, peat moss (PM), PL, and two pellets (P45-1 and P45-2) were evaluated. Peat moss was mixed with PL, P45-1, or P45-2 at various ratios (1:0 to 1:3 or 3:1 by volume) to investigate the feasibility of replacing PL with pellets. Nutrient composition of the growing medium and leaf tissues was analyzed. The number of florets, inflorescence length, plant height, and fresh weight of plants grown in media containing P45-1 or P45-2 were reduced compared to those grown in individual growing medium PM or PL. As the mixing ratio of P45-1 or P45-2 to PM was higher, the growth of salvia, such as inflorescence length, plant height, number of leaves, and fresh weight was inhibited. Our results indicate that mixing three parts PM with one part of P45-1 (PM/P45-1/3:1) or P45-2 (PM/P45-2/3:1) accelerated flowering and increased the number of florets and leaves compared to other mixing ratios of PM and pellets media. The concentrations of phosphorus (P), calcium (Ca), boron (B), iron (Fe), and copper (Cu) in individual growing medium PL, P45-1, and P45-2 were significantly lower than those in PM. The concentration of N was the highest in leaves of plants grown in P45-1 or P45-2 amended media, and the concentrations of P, Ca, and zinc (Zn) in leaves were lower in individual growing medium P45-1 or P45-2 than in PM and PL. The pH of PM/P45-1/3:1 or PM/P45-2/3:1 media was maintained at optimal level (5.8-5.9) and the concentrations of macro- and micro-elements in the media and leaves were considered to be optimal levels. Therefore, mixing three parts PM with one part P45-1(PM:P45-1/3:1) or P45-2 (PM:P45-2/3:1) is recommended for improved growth and flowering in salvia. This suggests that P45-1 or P45-2 can replace PL as an inert material to prepare growing medium.

Effects of zinc bearing palygorskite supplementation on the growth performance, hepatic mineral content, and antioxidant status of broilers at early age

  • Yang, Weili;Chen, Yueping;Cheng, Yefei;Wen, Chao;Zhou, Yanmin
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.7
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    • pp.1006-1012
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    • 2017
  • Objective: This study was conducted to investigate effects of zinc (Zn) bearing palygorskite (ZnPal) supplementation on growth performance, hepatic mineral content, and antioxidant status of broilers at early age. Methods: A total of 240 1-day-old Arbor Acres broiler chicks were allocated into 5 treatments with 6 replicates of 8 chicks each. Birds in 5 treatments were fed a basal diet supplemented with 0 (Control group; Analyzed Zn content: 81 mg/kg), 20, 40, 60, and 80 mg/kg Zn as ZnPal for 21 days, respectively. Blood, liver and intestinal mucosa were collected at 21 days of age. Results: Treatments did not affect growth performance of broilers during the 21-day study (p>0.05). The contents of hepatic Zn and magnesium (Mg) were linearly increased (p<0.001) by ZnPal supplementation. ZnPal inclusion linearly (p = 0.007) reduced malondialdehyde (MDA) concentration in serum. The activity of total superoxide dismutase (T-SOD) in liver increased linearly (p = 0.001) with concentration of ZnPal in diet. ZnPal inclusion linearly (p = 0.036) and quadratically (p = 0.005) increased T-SOD activity, and linearly (p = 0.012) increased copper/zinc superoxide dismutase (Cu/Zn SOD) activity in jejunal mucosa. The maximum responses of hepatic and jejunal antioxidant enzymes activities (T-SOD and Cu/Zn SOD) were found when supplementing the basal diet with 60 mg/kg Zn as ZnPal. Furthermore, ZnPal supplementation quadratically (p = 0.001) increased Cu/Zn SOD activity in ileal mucosa, and its maximum activity was observed in the diet supplemented with 20 mg/kg Zn as ZnPal. Conclusion: ZnPal supplementation did not alter growth performance of broilers. Dietary ZnPal inclusion could increase concentrations of hepatic trace minerals (Zn and Mg) and inhibit lipid peroxidation by reducing serum MDA accumulation, with the optimal dosage of Zn from ZnPal being 80 mg/kg diet (analyzed Zn content in the diet: 165 mg/kg), and 60 mg/kg Zn as ZnPal (analyzed Zn content in the diet: 148 mg/kg) was the optimum dosage for broilers to achieve maximum antioxidant enzyme activities.