• Title/Summary/Keyword: Copper electrode

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Ruthenium Thin Films Grown by Atomic Layer Deposition

  • Shin, Woong-Chul;Choi, Kyu-Jeong;Jung, Hyun-June;Yoon, Soon-Gil;Kim, Soo-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.12-12
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    • 2008
  • Ruthenium is one of the noble metals having good thermal and chemical stability, low resistivity, and relatively high work function(4.71eV). Because of these good physical, chemical, and electrical properties, Ru thin films have been extensively studied for various applications in semiconductor devices such as gate electrode for FET, capacitor electrodes for dynamic random access memories(DRAMs) with high-k dielectrics such as $Ta_2O_5$ and (Ba,Sr)$TiO_3$, and capacitor electrode for ferroelectric random access memories(FRAMs) with Pb(Zr,Ti)$O_3$. Additionally, Ru thin films have been studied for copper(Cu) seed layers for Cu electrochemical plating(ECP) in metallization process because of its good adhesion to and immiscibility with Cu. We investigated Ru thin films by thermal ALD with various deposition parameters such as deposition temperature, oxygen flow rate, and source pulse time. Ru thin films were grown by ALD(Lucida D100, NCD Co.) using RuDi as precursor and $O_2$ gas as a reactant at 200~$350^{\circ}C$.

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A Study on the Simulation of the Corona Charging Process of Polypropylene Electret Cell Using Finite Element Method (유한요소법을 이용한 폴리프로필렌 일렉트렛트 셀의 코로나 대전과정 시뮬레이션에 관한 연구)

  • Lee, Su-Kil;Park, Geon-Ho;Jung, Il-Hyung;Jang, Kyung-Uk;Lee, Joon-Ung
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.169-171
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    • 1993
  • In order to estimate space charging process in the corona charging apparatus which has been used to make polymer electret cell, the electrical properties of 30[${\mu}m$] thick polypropylene film were obtained from TSC measurement after corona charging between copper knife electrode and aluminum cylinder electrode with the voltage of -8, -7, -6, -5 (kV). And, the electrostatic contour and the electric field vector were calculated using Finite Element Method with the electrical properties obtained from TSC spectra analysis. The edge effect around the edge of knife electrode affects electrostatic contour on the surface of specimen and the electric field concentration inside the polymer. As a result the uneven charging state in the electret cell due to the mistake of design was calculated, and the optimal design of corona charging apparatus opprobriate to various specimen was come to be practicable.

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Electrode Characteristics of Non-contact Electrocardiographic Measurement

  • Mathias, Dakurah Naangmenkpeong;Kim, Sung-Il;Park, Jae-Soon;Joung, Yeun-Ho;Choi, Won Seok
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.1
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    • pp.42-45
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    • 2015
  • The ability to take electrocardiographic measurements while performing our daily activities has become the people-choice for modern age vital sign sensing. Currently, wet and dry ECG electrodes are known to pose threats like inflammations, allergic reactions, and metal poisoning due to their direct skin interaction. Therefore, the main goal in this work is to implement a very small ECG sensor system with a capacitive coupling, which is able to detect electrical signals of heart at a distance without the conductive gel. The aim of this paper is to design, implement, and characterize the contactless ECG electrodes. Under a careful consideration of factors that affect a capacitive electrode functional integrity, several different sizes of ECG electrodes were designed and tested with a pilot ECG device. A very small cotton-insulated copper tape electrode ($2.324cm^2$) was finally attained that could detect and measure bioelectric signal at about 500 um of distance from the subject's chest.

Electrical Properties of CuPc-OFET with Metal Electrode (금속 전극에 따른 CuPc-OFET 의 전기적 특성)

  • Lee, Ho-Shik;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2007.10a
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    • pp.751-753
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    • 2007
  • Organic field-effect transistors (OFETs) are of interest for use in widely area electronic applications. We fabricated a copper phthalocyanine (CuPc) based field-effect transistor with different metal electrode. The CuPc FET device was made a top-contact type and the substrate temperature was room temperature. The source and drain electrodes were used an Au and Al materials. The CuPc thickness was 40nm. and the channel length was $50{\mu}m$, channel width was 3mm. We observed a typical current-voltage (I-V) characteristics in CuPc FET with different electrode materials.

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Fabrication of Ti/Ir-Ru electrode by spin coating method for electrochemical removal of copper

  • Kim, Joohyun;Bae, Sungjun
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.646-653
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    • 2019
  • Recovery of valuable metals in the industrial wastewater and sludge has attracted an attention owing to limited metallic resources in the earth. In this study, we firstly fabricated Ti/Ir-Ru electrodes by spin coating technique for effective recovery of Cu in electrowinning process. Two different Ti/Ir-Ru electrodes were fabricated using 100 and 500 mM of precursors (i.e., Ir-Ru). SEM-EDX and AFM revealed that Ir and Ru were homogenously distributed on the surface of Ti plate by the spin coating, in particular the electrode prepared by 500 mM showed distinct boundary line between Ir-Ru layer and Ti substrate. XRD, XPS, and cyclic voltammetry also revealed that characteristics of IrO2, RuO2, and TiO2 and its electrocatalytic property increased as the concentration of coating precursor increased. Finally, we carried out Cu recovery experiments using two Ti/Ir-Ru as anodes in electrowinning process, showing that both anodes showed a complete removal of Cu (1 and 10 g/L) within 6 h reaction, but much higher kinetic rate constant was obtained by the anode prepared by 500 mM. The findings in this study can provide a fundamental knowledge for surface characteristics of Ti/Ir-Ru electrode prepared by spin coating method and its potential feasibility for effective electrowinning process.

Experimental Study on Bio-signal Characteristics of Stuckyi during Heating (스투키의 가열에 의한 생체 신호 변화 특성에 대한 실험 연구)

  • Nam, Dahyun;Kim, Jeongbae
    • Journal of Institute of Convergence Technology
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    • v.6 no.1
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    • pp.7-11
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    • 2016
  • An experiment was performed to show the bio-signal characteristics of the Stuckyi when was heated. To measure the bio-signal of the plant, this study used the electrode with copper(+) and constantan(-). The electrode was directly inserted into the Stuckyi stems. And used T-type thermocouple to measure the inside temperature of the Stuckyi. During the experiments, room temperature also measured with T-type thermocouple. Heating was made with hair dryer periodically that 3 times turned on for heating 5 min and off for non-heating 25 min. Under the situation, the responses of the Stuckyi including voltage potential and inside temperature were measured using data logger(HP-34970A) according to the distances(15cm, 30cm, 45cm) between hair dryer and the plant. Through the experiments, We knew that the inside temperature has similar level and behavior with the room temperature at normal state. And during heating period, the inside temperature and the potential were also simultaneously increased sharply. From the experiments, we revealed that the measuring system of bio-signal of the plant being proposed in this study can be useful to show the Characteristics of the plants.

Effect of KHCO3 Concentration Using CuO Nanowire for Electrochemical CO2 Reduction Reaction

  • Kanase, Rohini Subhash;Kang, Soon Hyung
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.11-17
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    • 2020
  • Copper has been proved to be the best catalyst for electrochemical CO2 reduction reaction, however, for optimal efficiency and selectivity, its performance requires improvements. Electrochemical CO2 reduction reaction (RR) using CuO nanowire electrode was performed with different concentrations of KHCO3 electrolyte (0.1 M, 0.5 M, and 1 M). Cu(OH)2 was formed on Cu foil, followed by thermal-treatment at 200℃ under the air atmosphere for 2 hrs to transform it to the crystalline phase of CuO. We evaluated the effects of different KHCO3 electrolyte concentrations on electrochemical CO2 reduction reaction (RR) using the CuO nanowire electrode. At a constant current (5mA), low concentrated bicarbonate exhibited a more negative potential -0.77 V vs. Reversible Hydrogen Electrode (RHE) (briefly abbreviated as VRHE), while the negative potential reduced to -0.33 VRHE in the high concentration of bicarbonate solution. Production of H2 and CH4 increased with an increased concentration of electrolyte (KHCO3). CH4 production efficiency was high at low negative potential whereas HCOOH was not influenced by bicarbonate concentration. Our study provides insights into efficient, economically viable, and sustainable methods of mitigating the harmful environmental effects of CO2 emission.

Differential Titrimetric Determination of Bismuth$^1$

  • Choi, Q.-Won;Lim, H. S.
    • Bulletin of the Korean Chemical Society
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    • v.4 no.5
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    • pp.217-219
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    • 1983
  • A precise EDTA titrimetric method involving a weight titration of major portion with solid reagent followed by titration of the remainder with a very dilute standard solution has been developed for the determination of bismuth. When the end point is determined by means of amperometry with a rotating mercury electrode, the error in bismuth analysis is less than 0.01 % even when $Pb^{2+}$, $Zn^{2+}$, or $Cd^{2+}$ is present. However, copper interferes appreciably and masking with thiourea gives too low results.

Molecular Level Detection of Heavy Metal Ions Using Atomic Force Microscope (원자간인력현미경을 이용한 분자수준의 중금속 이온 검출)

  • Kim, Younghun;Kang, Sung Koo;Choi, Inhee;Lee, Jeongjin;Yi, Jongheop
    • Clean Technology
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    • v.11 no.2
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    • pp.69-74
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    • 2005
  • A metal ion detector with a submicron size electrode was fabricated by field-induced AFM oxidation. The square frame of the mesa pattern was functionalized by APTES for the metal ion detection, and the remaining portion was used as an electrode by the self-assembly of MPTMS for Au metal deposition. The conductance changed with the quantity of adsorbed copper ions, due to electron tunneling between the mobile and surface electrodes. The smaller electrode has a lower limit of detection due to the enhancement in electron tunneling through metal ions that are adsorbed between the conductive-tip (mobile) and the surface (fixed) electrode. This two-electrode system immobilized with different functional groups was successfully used in the selective adsorption and detection of target materials.

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Decomposition of CFC-12($CCl_2F_2$) by Discharge Plasma (방전 플라스마에 의한 CFC-12($CCl_2F_2$)의 분해)

  • 강현춘;우인성;황명환;안형환;이한섭;조정국;강안수
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.93-100
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    • 1999
  • Decomposition efficiency, power consumption, and applied voltage of CFC(Chlorofluorocatbon) were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of CFC-12 with various electric frequencies(5~50kHz). flow rates (100~1,000mL/min), initial concentrations(100~1,000ppm), electrode materials(W, Cu, Al). electrode thickness(1, 2, 3mm) and reference gases($N_2$, $O_2$, air) were measured and the products were analyzed with FT-IR. Experimental results showed that at the frequency of 10kHz, the highest decomposition efficiency of 92.7% for CFC-12 were observed at the power consumptions of 29.6W. respectively, and that decomposition efficiency decreased with increasing frequency above 20kHz and decomposition efficiency per unit power were 3.13%/W for CFC-12. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3m. As the electrode material, decomposition efficiency was in order that tungsten(W), copper(Cu), aluminum (Al). Decomposition of CFC-12 in the reference gas of $N_2$ showed the highest efficiency among three reference gases, and then the effect of reference gas on the decomposition efficiency decreased in order of air and $O_2$. The optimum power for the maximum decomposition efficiency was 25.3W for CFC.

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