• Title/Summary/Keyword: Copper Titanate

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EPR and Electrical Studies in Layered Na1.9Li0.1Ti3O7 and its Copper Doped Derivatives (층상구조의 Na1.9Li0.1Ti3O7과 그 구리 혼입 유도체의 EPR 및 전기적 연구)

  • Pal, D.;Chand, Prem;Tandon, R.P.;Shripal
    • Journal of the Korean Chemical Society
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    • v.49 no.6
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    • pp.560-566
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    • 2005
  • Sintered ceramic samples of pure and some copper doped layered sodium lithium tri-titanate ($Na_{1.9}Li_{0.1}Ti_{3-X}Cu_XO_{7-X}$) materials with different dopant molar percentages (0.0$Cu^{2+}$ at $Ti^{4+}$ sites in the lattice is proposed in this paper. Furthermore, three distinct regions have been identified in log(${\sigma}_{d.c.}T$) versus 1000/T plots. The lowest temperature region is attributed to electronic hopping conduction(polaron) for all copper doped derivatives and ionic conduction for lithium substituted $Na_2Ti_3O_7$.The mechanism of conduction in the intermediate region is associated interlayer ionic conduction and in the highest temperature region is associated modified interlayer ionic conduction.