• Journal of Conservation Science
• /
• v.35 no.4
• /
• pp.373-383
• /
• 2019

We characterized the smelting process and smelting furnace through scanning electron microscopy-energy dispersive spectroscopy, wavelength dispersive X-ray fluorescence, X-ray diffraction, and raman micro-spectroscopy with 13 relics including slags and furnace walls excavated from square-shaped building sites and pits of the Three Kingdoms site at the Ungyo site section I. Our results revealed that the principal components were FeO and SiO₂; and CuO, PbO, and ZnO were contained in small quantities. Furthermore, fayalite, magnetite, augite, copper, and cuprite were found. High contents of FeO or SiO₂ components seem to have been added to form fayalite to remove gangue in the smelting process. The relatively low content of S detected in the copper prills suggests that roasting was performed well. Cristobalite and mullite, which are minerals that indicate high-temperature found in the furnace wall, show that the smelting temperature was higher than 1,250℃. The findings of this study show a high possibility that the Wanju Ungyo site is smelting remains of copper ores, which are nonferrous metals, rather than iron. Various smelting byproducts excavated in this area in the future will help us better understand the copper smelting process that may have been performed since ancient times.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.2 no.2
• /
• pp.68-75
• /
• 2006

The total production of the smelted copper reaches 450,000 tons per year, and the production of copper-related goods grows year by year owing to the extension of facilities and the development of production techniques. On the other hand, the volume of slag discharges by-produced at the time of copper smelting process is also on trend of increase. The by-produced copper smelting slag amounts to 700,000 tons a year, which is one and half times of the total smelted copper production. Accordingly nobody disagrees that comprehensive researches on how to deal with and how to reuse the accumulated smelting copper slag have to be encouraged. Even though the possible uses of the copper smelting slag have being made on various levels at present as materials for iron powder cement, sand-blasting and fire-proofing rock wool, but a considerable volume of the slag is abandoned as unnecessary by burying or piling up in careless in the open ground.

• Korean Journal of Heritage: History & Science
• /
• v.48 no.4
• /
• pp.126-137
• /
• 2015

The study on the archaeological bronze artifacts in Korea has prompted much research through the analysis to determine the production technology. However, research on the smelting technology is not enough. This is associated with the lack of copper smelting and refining remains and literatures were not found. Copper smelting technology was probably developed independently, but also can not ignore the effect of the another country. Thus, many studies compared to estimate the country's copper smelting technology. In this study, smelting technology was provided and compared through the literature and smelting sites study of the domestic and foreign.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.04a
• /
• pp.263-268
• /
• 2000

Recently, the recycling of the by-products was attempted to various fields. One of the major industry, the copper manufacturing industry produced a lot slags. in this study, the copper smelting slag was used to use practically application for the aggregate of concrete. To find the optimum mixing ratio of mortar with the copper smelting slag as substitution for sand, the mixing ratio was increased 1:2 to 1:5 step by step and every mixture was contained 5 steps sand substitutive ratio. The substitutive ratio of sand was increased 25% st대 by step from 0% to 100%. The result of this study was shown as follows. 1. In the every mixture, as the substitutive ratio was increased, the flow was decrease 3.64% from 18cm, and the unit content weigth was increased 5.5% in average. 2. The property of the strength was judged that it was more affected W/C and mixing ratio than the copper smelting slag.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2001.05a
• /
• pp.319-324
• /
• 2001

Recently new practical use way of industry product is required. In this study, to find flowing property of slump, unit weight, the air amount, compressive strength etc. Compressive strength 240, 270kgf/$cm^{2}$, slump 8$\pm$2.5(I), 152$\pm$.5(II)cm, mixing ratio of copper smelting slag decided by 0, 25, 50, 75, 100% gradually, The result of this study was follows ; 1. Unit weight increased 2.2%~4.4% according as mixing ratio of copper smelting slag increases. 2. Slump increased about 2~5% as the mixing ratio increased gradually 3. Compressive strength was increased about 4~28% in copper smelting slag mixing ratio 25~50% and 8~20% decreased more than mixing ratio 75%.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2003.11a
• /
• pp.590-597
• /
• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2003.10a
• /
• pp.22-34
• /
• 2003

Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

• Resources Recycling
• /
• v.21 no.1
• /
• pp.3-16
• /
• 2012

In order to review the technological modulus of the recycling of urban mine resources and non-ferrous smelting process in Korea, key point of recycling process, physical separation, non-ferrous smelting process, unit operation for the recycling technology, recycling process of LS-Nikko Copper and Korea Zinc were studied. Finally, metal recycling processes of the typical non-ferrous smelters in Japan such sa DOWA Holdings and JX Holdings were compared with those of LS-Nikko Copper and Korea Zinc.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.28 no.11
• /
• pp.26-32
• /
• 2014

In electrolysis smelting plants that using high DC current, the bus bar is most important facility for delivering the high current. The copper made bus bar is widely used for various advantages as good electrical and thermal conductivity, resonable malleability, ductility, and not rust easily. However, when high current in copper bus bar, temperature rises and maximum allowable current capacity is restricted by temperature of bus bar. In this paper, we investigated temperature variation of copper bus bar by putting cooling water channel imposed to bus bar construction. For the validity, various simulations were carried out.

• Journal of Conservation Science
• /
• v.36 no.3
• /
• pp.162-177
• /
• 2020

Research was conducted to characterize the copper production and smelting process with 11 copper smelting by-products (copper slag and copper crucible) excavated from the NA and LA areas at the Gwanbuk-ri archeological site in Buyeo. Scanning electron microscopy-energy dispersive spectroscopy, wavelength dispersive X-ray fluorescence, X-ray diffraction, and Raman microspectroscopy were employed in the analysis. The research results reveal that the copper slag from Gwanbuk-ri contained silicate oxide, magnetite, fayalite, and delafossite, which are typical characteristics of crucible slag and refined slag. The outward appearance and microstructure of the slag were grouped as follows: 1. glassy matrix + Cu prill, 2. glassy matrix + Cu prill + magnetite, 3. silicate mineral matrix + Cu prill, 4. crystalline (delafossite and magnetite) + amorphous (Cu prill), 5. magnetite + fayalite, and 6. slag from slag. The copper slags from Guanbuk-ri were found to contain residues of impurities such as SiO₂, Al₂O₃, CaO, SO₄, P₂O₅, Ag₂O, and Sb₂O₃ in their microstructure, and, in some cases, it was confirmed that copper, tin and lead are alloys. These results indicate that refining of intermediate copper(including impurities) and refining of alloys of copper(including impurities) - tin and refining of copper(including impurities) - tin - lead took place during the copper production process at Gwanbuk-ri, Buyeo.