• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.551-555
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• 2005

This paper presents the temperature-pressure characteristics of SMH actuator using a peltier module. The simple SMH actuator, consisting of the plated hydrogen-absorbing alloy as a power source, Peltier elements as a heat source and a cylinder with metal bellows a functioning part has been developed. The SMH actuator is characterized by its small size, low weight, noiseless operation and a compliance similar to that of the human body. A new special metal hydride(SMH) actuator that uses the reversible reaction between the heat energy and mechanical energy of a hydrogen absorbing ally. It is well known that hydrogen-absorbing alloys can reversibly absorb and desorb a large amount of hydrogen, more than about 1000 times as their own volume. To improve the thermal conductivity of the hydrogen-absorbing alloy, an electro-less copper plating has been carried out. The effects of the electro-less copper plating and the dynamic characteristics of the SMH actuator have been studied. The hydrogen equilibrium pressure increases and hydrogen is desorbed by heating the hydrogen-absorbing alloys, whereas by cooling the alloys, the hydrogen equilibrium pressure decreases and hydrogen is absorbed. Therefor, the SMH actuator has the characteristic of being light and easy to use and so is suitable for use in medical and rehabilitation applications.

• 대한기계학회논문집
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• 제18권5호
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• pp.1235-1244
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• 1994

In this study, experimental results of the nucleate boling of wire-wrapped tubes are provided. Both water and R-113 were boiled. Solid stainless steel wires, stranded copper wires and stranded nylon wires were tested. Solid stainless wire is effective to enhance the boiling of water. The performance is approximately the same(or slightly better at certain conditions) as that of GEWA-T tubes. For the test range of wire diameter 0.6 $mm{\le}d{\le}2.6 mm$, the optimum gap width increases as the wire diameter increases. The maximum heat transfer coefficient was obtained for the 1.0 mm diameter wire, and it is 1.6 times larger than that of the GEWA-T at the heat flux of 20 $kW/m^{2}.$ Solid stainless wire is also effective to enhance the boling of R-113 at low heat fluxes. The performance of the wire-wrapped tube approaches that of GEWA-T. At high heat fluxes, however, the enhancement decreases. The reason may be attributed to the cavity shape and the high wettability of the refrigerants. Stranded copper or nylon wire is effective to enhance the boiling of R-113. The performance is approximately the same(or slightly better) as that of GEWA-T tubes. Maximum heat transfer was obtained for the stranded nylon wire, and it is approximately 1.4 times larger than that for the GEWA-T at the heat flux of 20 $kW/m^{2}.$ The reason may be atrributed to the favorable thermal environment in the restricted regions formed by twisted wires.

• Mycobiology
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• 제44권4호
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• pp.260-268
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• 2016

Regulation of alkaline-resistant laccase from Perenniporia tephropora KU-Alk4 was proved to be controlled by several factors. One important factor was the initial pH, which drove the fungus to produce different kinds of ligninolytic enzymes. P. tephropora KU-Alk4 could grow at pH 4.5, 7.0, and 8.0. The fungus produced laccase and MnP at pH 7.0, but only laccase at pH 8.0. The specific activity of laccase in the pH 8.0 culture was higher than that in the pH 7.0 culture. At pH 8.0, glucose was the best carbon source for laccase production but growth was better with lactose. Low concentrations of glucose at 0.1% to 1.0% enhanced laccase production, while concentrations over 1% gave contradictory results. Veratryl alcohol induced the production of laccase. A trace concentration of copper ions was required for laccase production. Biomass increased with an increasing rate of aeration of shaking flasks from 100 to 140 rpm; however, shaking at over 120 rpm decreased laccase quantity. Highest amount of laccase produced by KU-Alk4, 360 U/mL, was at pH 8.0 with 1% glucose and 0.2 mM copper sulfate, unshaken for the first 3 days, followed by addition of 0.85 mM veratryl alcohol and shaking at 120 rpm. The crude enzyme was significantly stable in alkaline pH 8.0~10.0 for 24 hr. After treating the pulp mill effluent with the KU-Alk4 system for 3 days, pH decreased from 9.6 to 6.8, with reduction of color and chemical oxygen demand at 83.2% and 81%, respectively. Laccase was detectable during the biotreatment process.

• Nuclear Medicine and Molecular Imaging
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• 제41권4호
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• pp.326-334
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• 2007

에스트로젠 수용체 양성 유방암에서 과발현되는 에스트로젠 수용체는 $[^{18}F]FES$와 같은 $^{18}F$이 표지된 스테로이드계 에스트로젠 수용체 리간드를 사용하여 양전자방출단층촬영기로 영상을 얻을 수 있다. 반감기가 12.7시간인 $^{64}Cu$에 비해 1.8시간인 $^{18}F$은 반감기가 짧고, $^{64}Cu$로 표지 하는 경우보다 수율이 낮은 단점이 있다. 사이클렌은 구리, 인듐, 갈륨, 가돌리륨 등과 같은 금속과 안정한 착물을 형성한다. 이를 근거로 2개의 페놀 하이드록시 그룹을 가지고 있는 사이클렌을 기본구조로 한 구리 착물을 합성하였다. 재료 및 방법 : 1,7 위치에 보호기를 가지고 있는 1,7-bis(benzyloxy-carbonyl)-cyclen은 기존에 알려진 방법에 따라 합성 되어졌다. 여기에 4,10 위치에 2개의 4-benzyloxybenzyl groups을 도입한 후, Pd/C상에서의 수소화 반응으로 benzyloxycarbonyl과 benzyl groups이 모두 제거됨으로써 1,7-bis(4-hydroxybenzyl)-cyclen (1)을 성공적으로 합성할 수 있었다. 결과: 우리가 합성한 물질 1은 $^1H,\;^{13}C-NMR$ 그리고 질량분석기로 만들어졌는지 여부를 확인하였다. 이 물질들은 구리 이온과 반응하여 $[Cu(1)]^{2+}2(ClO_4)^-$와 $[Cu(1)Cl]^+Cl^-$를 형성하였고, 고분해능 FAB 질량분석기로 확인하였다. 결론: 우리는 질소원자에 trans 방향으로 2개의 페놀 그룹을 가지고 있는 cyclen 유도체를 합성하는데 성공하였고, 구리이온과 반응하여 각각 전체 전하가 +2그리고 +1인 구리 착물을 합성하였으며, 이들은 에스트로젠 수용체의 영상화를 위한 PET 추적자로 쓰일 수 있는 가능성이 있다.

• 공업화학
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• 제20권5호
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• pp.553-556
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• 2009

본 연구의 목표는 열분해 기술의 문제점을 보완하여 유가자원의 회수와 폐기물 처리의 효율을 높이는데 있다. 우선 경제성을 높이기 위해 기존 열분해온도(보통 $500{\sim}1000^{\circ}C$)보다 낮은 $450^{\circ}C$에서의 저온열분해 반응을 시도하였다. 촉매를 사용하여 반응온도와 반응시간을 단축할 수 있었고, 무 산소 상태를 유지시키는데 유리하도록 간접열을 사용하였다. 결과적으로 유가자원인 구리와 합성연료유의 회수율을 증가시킬 수 있었고, 발생하는 부산물과 배가스의 처리효과가 뛰어남을 알 수 있었다. 배가스는 2단의 중화조를 통과시켜 다이옥신은 거의 발생되지 않았으며, 나머지 대기환경기준의 측정항목 또한 기준치 이하를 보였다. 이번 연구에서는 앞에서 말한 저온 열분해장치(GTPK-001)를 제작하였고, 경제적으로나 친환경적으로 상용화 개발이 가능함을 알 수 있었다.

• 한국표면공학회지
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• 제49권1호
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• pp.54-61
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• 2016

Screen printing of commercially available Ag paste is the most widely used method for the front side metallization of Si solar cells. However, the metallization using Ag paste is expensive and needs high temperature annealing for reliable contact. Among many metallization schemes, Ni/Cu/Sn plating is one of the most promising methods due to low contact resistance and mass production, resulting in high efficiency and low production cost. Ni layer serves as a barrier which would prevent copper atoms from diffusion into the silicon substrate. However, Ni based schemes by electroless deposition usually have low thermal stability, and require high annealing process due to phosphorus content in the Ni based films. These problems can be resolved by adding W element in Ni-based film. In this study, Ni-W-P alloys were formed by electroless plating and properties of it such as sheet resistance, resistivity, specific contact resistivity, crystallinity, and morphology were investigated before and after annealing process by means of transmission line method (TLM), 4-point probe, X-ray diffraction (XRD), and Scanning Electron Microscopy (SEM).

• 한국동물학회지
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• 제7권1호
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• pp.1-5
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• 1964

Triglycin 수용액에 미치는 gamma 선의 영향을 low voltage electrophoresis, paper chromatography 및 carbonyl 화합물정량의 세 방법으로 연구하여 다음 결과를 얻었다. 1. 조사된 triglycine 분해산물중 한 성분이 동 ion 과 산화합물을 이루었으며 triglycine에 비하여 높은 음전성을 나타내었다. 2. 조사된 triglycine 분해산물중 다섯 성분이 paper chromatography 에 의해 분리되었으며 이중 둘이 동정되었다. 3. 조사된 triglycine 으로부터 생성되는 carbonly 화합물의 양은 $5{\times}10^{20}\;ev/ml$ 까지는 증가하였으며 이로부터 $1.9{\times}10^{21}\;ev/ml$ 까지의 고선량에서는 오히려 감소를 나타내어 complex system내에 있어서 이차반응에 관여함을 알 수 있었다. 4. 조사된 triglycine에서 glycine을 분리함으로써 peptide bond 의 가수분해의 가능성을 보여주었다.

• Transactions on Electrical and Electronic Materials
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• 제14권5호
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• pp.246-249
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• 2013

Graphene was obtained on Cu foil by thermal decomposition method. A gas mixture of $H_2$ and $CH_4$ and an ambient annealing temperature of $1,000^{\circ}C$ were used during the deposition for 30 Min., and for the transfer onto $SiO_2/Si$ and Si substrates. The physical properties of graphene were investigated with regard to the effect ofnitrogen atom doping and the various substrates used. The G/2D ratio decreased when the graphene became monolayer graphene. The graphene grown on $SiO_2/Si$ substrate showed a low intensity of the G/2D ratio, because the polarity of the $SiO_2$ layer improved the quality of graphene. The intensity of the G/2D ratio of graphene doped with nitrogen atoms increased with the doping time. The quality of graphene depended on the concentration of the nitrogen doping and chemical properties of substrates. High-quality monolayer graphene was obtained with a low G/2D ratio. The increase in the intensity of the G/2D ratios corresponded to a blue shift in the 2D peaks.

• 한국표면공학회지
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• 제38권3호
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• pp.118-125
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• 2005

Low temperature plasma treatment with different gases and rf powers were performed to improve the adhesion strength between polytetrafluoroethylene(PTFE) and electroless deposited copper. According to the research, $H_2$ plasma having hydrogen radical was more effective in surface polarity modification than $O_2$ plasma due to the defluorination reaction. However, surface roughness of PTFE was more increased with $O_2$ than $H_2$ plasma. PTFE treated with $120W-O_2$ plasma and $250w-H_2$ plasma, consecutively showed rougher surface than single step $250w-H_2$ plasma treated one and more hydrophilic than single step $120W-O_2$ plasma treated one. And it showed 5B tape test grade, which is better adhesion property than 1B or 3B obtained by single step plasma treatment. In addition, adhesion strength between PTFE and Cu deposit is also deeply affected by residual water on its interface.

• 한국항행학회논문지
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• 제12권2호
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• pp.122-131
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• 2008

본 논문에서는 마이크로스트립 헤어핀 형태의 링 공진기를 이용하여 저위상 잡음을 개선한 소형화된 S 대역에 사용가능한 발진기를 설계 및 제작하였다. 기판은 고조파 특성이 우수한 유전율 ${\varepsilon}_r$=3.5 기판두께 h=20mil 금속두께 t=17um 손실 탄젠트 $tan{\delta}$=0.0025 인 TACONIC사의 RF-35를 사용하였다. 측정된 결과 발진 주파수는 2.45 GHz에서 출력전력은 20.9 dBm으로서 기존의 발진기에 비하여 상당히 높은 출력을 얻었고, 위상 잡음 특성은 100 kHz offset에서 -100.5 dBc/Hz 로서 기존의 발진기 성능과 비교하면 우수한 특성이 있음을 확인할 수 있었고, 고조파 억압 특성은 32 dBc 이상으로서 우수한 특성을 갖는 발진기임을 보여주었다. 본 논문에서 제안된 발진기의 형태를 이용하여 RFIC, MIC, MMIC 형태로 제작한다면 발진기를 소형화할 수 있을 것이며, 이 제작된 발진기는 S-밴드의 주파수원으로 이용 가능할 수 있을 것으로 사료된다.