• 제목/요약/키워드: Copper(I)

검색결과 599건 처리시간 0.023초

Modified Activated Carbons from Olive Stones for the Removal of Heavy Metals

  • Youssef, A.M.;El-Nabarawy, Th.;El-Shafey, E.I.
    • Carbon letters
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    • 제7권1호
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    • pp.1-8
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    • 2006
  • The activated carbon "C" was obtained by carbonization followed by activation with steam at 40% of burn-off. Oxidized carbons C-N, C-P and C-H were obtained by oxidizing the activated carbon C with concentrated nitric acid, ammonium peroxysulfate and hydrogen peroxide, respectively. The textural properties of the carbons were determined from nitrogen adsorption at 77 K. The acidic surface functional groups were determined by pH titration, base neutralization capacity and electrophoretic mobility measurements. The cation exchange capacities of un-oxidized and oxidized carbons were determined by the removal of Cu(II) and Ni(II) from their aqueous solutions. The surface area and the total pore volume decreased but the pore radius increased by the treatment of activated carbon with oxidizing agents. These changes were more pronounced in case of oxidation with $HNO_3$. The surface pH of un-oxidized carbon was basic whereas those of the oxidized derivative were acidic. The removal of Cu(II) and Ni(II) was pH dependent and the maximum removal of the both ions was obtained at pH of 5-6. Cu(II) was more adsorbed, a phenomenon which was ascribed to its particular electronic configuration.

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평관형 및 나선 그루브형 열사이폰 내부 작동유체의 포화온도와 단열부의 표면온도에 관한 연구 (A Comparison between the Internal Saturation Temperature of Working Fluid and the Surface Temperature of Adiabatic Zone of Two-Phase Closed Thermosyphons with Various Helical Grooves)

  • 한규일;조동현;박종운;이상진
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1243-1249
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    • 2004
  • This study is focused on the comparison between the internal saturation temperature of the working fluid and the surface temperature of adiabatic zone of two-phase closed thermosyphons with various helical grooves. Distilled water, methanol and ethanol have been used as the working fluid. In the present work, a copper tube of the length of 1200mm and 14.28mm of inside diameter is used as the container of the thermosyphon. Each of the evaporator and the condenser section has a length of 550mm, while the remaining part of the thermosyphon tube is adiabatic section. A experimental study was carried out for analyzing the performances of having 50, 60, 70, 80, 90 helical grooves. A plain thermosyphon having the same inner and outer diameter as the grooved thermosyphons is also tested for the comparison. The results show that the numbers of grooves and the type of working fluids are very important factors for the operation of thermosyphons. A good agreement between the internal saturation temperature of working fluid and the surface temperature of adiabatic zone of two-phase closed thermosyphons with various helical grooves is obtained.

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Individual and Global Optimization of Switched Flux Permanent Magnet Motors

  • Zhu, Z.Q.;Liu, X.
    • Journal of international Conference on Electrical Machines and Systems
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    • 제1권1호
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    • pp.32-39
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    • 2012
  • With the aid of genetic algorithm (GA), global optimization with multiple geometry parameters is feasible in the design of switched flux permanent magnet (SFPM) machines. To investigate the advantages of global optimization over individual optimization, which has been used extensively for the design of SFPM machines, a comparison between the two approaches is carried out for the case of fixed copper loss and volume. In the case of individual parameter optimization, the sequence in which the individual parameters are optimized is very important. In the global optimization a better design can always be achieved although the corresponding torque density is found to be only slightly better than that of individually optimized with correct design sequence. By using the obtained global optimization results, the performance in machines having two types of stator and rotor pole combinations, i.e. 12/10 and 12/14, are compared, and it is shown that higher torque is exhibited in the 12/14 SFPM machine. Finally, this paper also demonstrates that global optimization, with the restriction of equal pole width, magnet thickness and slot opening, can maximize the torque density without significantly sacrificing other performance, such as cogging torque and overload capability.

터보 냉동기용 핀 튜브에 관한 연구(II) - 비등 열전달에 관하여 - (A Study on Finned Tube Used in Turbo Refrigerator(II) - on boiling heat transfer -)

  • 한규일;김시영;조동현
    • 수산해양교육연구
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    • 제5권2호
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    • pp.119-127
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    • 1993
  • This work studies for heat transfer and pressure drop performance of integral inner and outer fin tubes, designed to enhance the heat transfer performance of smooth tubes for in recipro and turbo refrigerator or high performance compact heat exchangers. Eight different inner spiral fin copper tubes with integral fin at outside surfaces were employed to improve boiling heat transfer coeffcient. For comparison, tests were made using a plain tube having the inside diameter and an outside diameter equal to that at the root of the fins for the finned tubes. Pool boiling heat transfer is investigated experimentally and theoretically on single tube arrangement. The refrigerant evaporates at a saturation state of 1 bar on the outside tube surface heated by hot water. The refrigerant R11 ($CFCl_3$) was used at a pressure of $P_s=1bar$ as a convenient test fluid with a boiling temperature of $T_s=23.6^{\circ}C$. The observed heat transfer enhancement of boiling for finned tubes significantly exceeded that to be expected on grounds of increased area. The maximum Vapor - side enhancement(i.e., vapor - side heat transfer coefficient of finned tube/vapor - side coefficient for plain tube) was found to be around 4 at 1299fpm - 30grooves tube.

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Molecular Characterization and Expression of CuZn-superoxide Dismutase (PSOD1) from Populus alba${\times}$Populus glandulosa

  • Lee Jun-Won;In Jun-Gyo;Lee Bum-Soo;Choi Yong-Eui;Kim Jin-Ju;Yang Deok-Chun
    • Plant Resources
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    • 제8권1호
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    • pp.52-59
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    • 2005
  • A cDNA, PSOD1, encoding cytosolic copper/zinc superoxide dismutase (CuZn-SOD) was cloned and characterized from a full length cDNA library prepared from Populus alba${\times}$Populus glandulosa cultured in vitro. A PSOD1, is 725 nucleotides long and has an open reading frame of 459 bp with 152 amino acid residues (pI 5.43). The deduced amino acid sequence of PSOD1 perfect matched to the previously reported CuZn-SOD (CAC33845.1). Consensus amino acid residues (His-45, -47, -62, -70, -79, -119) were involved in Cu-, Cu/Zn-, and Zn- binding ligands. The deduced amino acid sequence of PSOD1 exhibited the high level of similarity from 100 to $85\%$ among previously registered SOD genes. The expression of PSOD1 in poplar increased at the 1 mM $H_{2}O_2$ and drought stress during 30 min and 60 min, but the ozone treated poplar increased at 30 min in the early time and then decreased at 60 min.

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Optimization of Culture Conditions for Production of Pneumococcal Capsular Polysaccharide Type IV

  • Kim, S.N.;Min, K.K.;Choi, I.H.;Kim, S.W.;Pyo, S.N.;Rhee, D.K.
    • Archives of Pharmacal Research
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    • 제19권3호
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    • pp.173-177
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    • 1996
  • The Pneumococcus, Streptococcus pneumoniae, has an ample polysaccharide (PS) capsule that is highly antigenic and is the main virulence factor of the organism. The capsular PS is the source of PS vaccine. This investigation was undertaken to optimize the culture conditions for the production of capsular PS by type 4 pneumococcus. Among several culture media, brain heart infusion (BHI) and Casitone based medium were found to support luxuriant growth of pneumococcus type 4 at the same level. Therefore in this study, the Casitone based medium was used to study optimization of the culture condition because of BHI broth's high cost and complex nature. The phase of growth which accomodated maximum PS production was exponential phase. Concentrations of glucose greater than 0.8% did not enhance growth or PS production. Substitution of nitrogen sources with other resources or supplementation of various concentrations of metal ion (with the exception of calcium, copper, and magnesium ions) had adverse effects on growth and PS production. On the other hand, low level aeration and supplementation of 3 mg/l concentration of asparagine, phenylalanine, or threonine were beneficial for increased PS production. The synergistic effect of all the favorable conditions observed in pneumococcal growth assays provided a two-fold cumulative increase in capsular PS production.

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E종 절연 유도 전동기의 설계 (Design of Class E Insulation Induction Motor)

  • 이승원
    • 전기의세계
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    • 제16권2호
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    • pp.1-8
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    • 1967
  • From the discovery of Alago's disk, a number of trials and efforts have been concentrated on a small-sized and light-weighted induction motor. They have devoted themseleves, however, mainly to a improvement of cooling effect, a proper weight-distribution of copper and iron and desirable number of slots. In consequence, such an effort restricted only to the field of design, has resulted in unsatisfactory developments in the insulating materials consisting of the main parts of an induction motor. The quality of fibre and paper which are used as class-A insulation materials with their "compound" and "varnish" has been increased to some extent. Similarly Class-B insulation materials like asbest mica has been almost a combination of inorganic and binding materials. But nowadays synthesic chemistry is making a remarkable progress. So it comes possible for us to have silicon resin and other good ones of similar charateristics. And even a thin silicon resin insures us to get excellent heat-pro f and insulation, so a better space factor and cost-down in motor design have come possible in most advanced nations of the world, but not in our country. Furthermore, a consideration of productivity and economy in manufacturing process has been neglected by a majority of engineers. This is more unpleasant und more undesirable. I think this rational method of induction motor design using new synthesic resin will devote in making your productivity and economy better. And the nation-wide standard value of electric motor size is sited here. size is sited here.

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Implementation of Multipurpose PCI Express Adapter Cards with On-Board Optical Module

  • Koo, Kyungmo;Yu, Junglok;Kim, Sangwan;Choi, Min;Cha, Kwangho
    • Journal of Information Processing Systems
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    • 제14권1호
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    • pp.270-279
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    • 2018
  • PCI Express (PCIe) bus, which was only used as an internal I/O bus of a computer system, has expanded its function to outside of a system, with progress of PCIe switching processor. In particular, advanced features of PCIe switching processor enable PCIe bus to serve as an interconnection network as well as connecting external devices. As PCIe switching processors more advanced, it is required to consider the different adapter card architecture. This study developed multipurpose adapter cards by applying an on-board optical module, a latest optical communications element, in order to improve transfer distance and utilization. The performance evaluation confirmed that the new adapter cards with long cable can provide the same bandwidth as that of the existing adapter cards with short copper cable.

습식공정으로 형성된 구리산화물 나노와이어의 전계방출특성 향상 (Enhancement of Field Emission Characteristics of CuO Nanowires Formed by Wet Chemical Process)

  • 성우용;김왈준;이승민;이호영;박경호;이순일;김용협
    • 한국표면공학회지
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    • 제37권6호
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    • pp.313-318
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    • 2004
  • Vertically-aligned and uniformly-distributed CuO nanowires were formed on copper-coated Si substrates by wet chemical process, immersing them in a hot alkaline solution. The effects of hydrogen plasma treatment on the field emission characteristics of CuO nanowires were investigated. It was found that hydrogen plasma treatment enhanced the field emission properties of CuO nanowires by showing a decrease in turn-on voltage, and an increase in emission current density, and stability of current-voltage curves. However, the excessive hydrogen plasma treatment made the I-V curves unstable. It was confirmed by XPS (X-ray Photoelectron Spectroscopy) analysis that hydrogen plasma treatment deoxidized CuO nanowires, thereby the work function of the nanowires decreased from 4.35 eV (CuO) to 4.1 eV (Cu). It is thought that the decrease in the work function enhanced the field emission characteristics. It is well-known that the lower the work function, the better the field emission characteristics. The results suggest that the hydrogen plasma treatment is very effective in achieving enhanced field emission properties of the CuO nanowires, and there may exist an optimal hydrogen plasma treatment condition.

미세 홀 어레이 펀칭 가공 (Punching of Micro-Hole Array)

  • 손영기;오수익;임성한
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 금형가공,미세가공,플라스틱가공 공동 심포지엄
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    • pp.193-197
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    • 2005
  • This paper presents a method by which multiple holes of ultra small size can be punched simultaneously. Silicon wafers were used to fabricate punching die. Workpiece used in the present investigation were the rolled pure copper of $3{\mu}m$ in thickness and CP titanium of $1.5{\mu}m$ in thickness. The metal foils were punched with the dies and arrays of circular and rectangular holes were made. The diameter of holes ranges from $2-10{\mu}m$. The process set-up is similar to that of the flexible rubber pad forming or Guerin process. Arrays of holes were punched successfully in one step forming. The punched holes were examined in terms of their dimensions, surface qualities, and potential defect. The effects of the die hole dimension on ultra small size hole formation of the thin foil were discussed. The optimum process condition such as proper die shape and diameter-thickness ratio (d/t) were also discussed. The results in this paper show that the present method can be successfully applied to the fabrication of ultra small size hole array in a one step operation.

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