• Title/Summary/Keyword: Copper(I)

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Characteristics of Chromium, Copper, and Arsenic Leaching from CCA-Treated Wood (CCA 방부처리 목재로부터 크롬, 구리 및 비소의 용탈 특성)

  • Kim, He-Kap;Kim, Dong-Jin
    • Environmental Analysis Health and Toxicology
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    • v.22 no.4
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    • pp.339-348
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    • 2007
  • A laboratory experiment was conducted to study the characteristics of leaching of Cr, Cu, and As from chromated topper arsenate (CCA)-treated wood. The wood species tested was hemlock spruce ($10\;cm\;{\times}\;10\;cm\;{\times}\;10\;cm\;tube$). The leaching experiment was conducted over 60 days using I L of leachants whose pHs were adjusted to 2.0, 3.7, and 1.6, respectively with nitric acid, and also using lake water, according to the OECD guideline. Each leachate was analyzed for Cr and Cu using flame-AAS, and for As using vapor generation-AAS. Three metals were loathed at the highest levels at pH 2.0 but almost at similar levels at the other conditions. Cumulative quantifies over 60 days of a leaching period were in order of As>Cu>Cr. As was predicted to leach with an increase in flux over a 10 year period, while Cr and Cu fluxes were predicted to decrease with time. This result suggest that arsenic can pose a health risk to humans over a long period of time, when CCA-treated wood is used for building facilities (e.g., playgrounds, residential purposes, etc.) with which humans frequently contact.

Development of High-Performance Ultra-small Size RF Chip Inductors (고성능의 초소형 RF 칩 인덕터 개발)

  • 윤의중;천채일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.3
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    • pp.340-347
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    • 2004
  • Ultra-small size, high-performance, solenoid-type RF chip inductors utilizing low-loss A1$_2$O$_3$ core materials were investigated. The dimensions of the RF chip inductors fabricated were 1.0mm${\times}$0.5mm${\times}$0.5mm and copper coils were used. The materials (96% A1$_2$O$_3$) and shape (I-type) of the core, the diameters (40${\mu}{\textrm}{m}$) and position (middle) of the coil, and the lengths (0.35mm) of solenoid were determined by a high-frequency structure simulator (HFSS) to maximize the performance of the inductors. The high-frequency characteristics of the inductance (L) and quality-factor (Q) of the developed inductors were measured using a RF impedance/material analyzer (E4991A with E16197A test fixture). The developed inductors exhibit an inductance of 11 to 11.3nH and a qualify factor of 22.3 to 65.7 over the frequency ranges of 250 MHz to 1.7 GHz, and show results comparable to those measured for the inductors prepared by Coilcraft$^{TM}$. The simulated data described the high-frequency data of the L and Q of the fabricated inductors well.

Fundamental Electro-Mechanical Characteristics of Ballooning-Resistant Bi-2223 HTS Tapes (벌루닝 손상에 강한 Bi-2223 테이프의 기본적인 전기-기계적 특성)

  • Dizon, John Ryan C;Shin, Hyung-Seop;Ha, Dong-Woo;Cho, Jeon-Wook;Oh, Sang-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.26-27
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    • 2006
  • The fundamental mechanical characteristics under tensile and bending deformations of hermetically-sealed reinforced Bi-2223 tape and CTOP processed Bi-2223 tape were examined at 77K. Also, the Tensile strain dependence of the critical current, $I_c$, was obtained at 77K and self-field. The reinforced hermetic tape showed higher tensile strength and a better Tensile strain tolerance than the CTOP processed tape. For bending tests, a rho-shaped sample holder was used giving multiple bending strains. in increasing order. In the same case under bending deformation, the hermetic tape showed a higher bending strain tolerance than the CTOP processed tape. This higher strength of the hermetic tape can be attributed to the thick hardened copper reinforcement layer.

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Fabrication of Ultra Small Size Hole Array on Thin Metal Foil (초미세 금속 박판 홀 어레이 가공)

  • Rhim S. H.;Son Y. K.;Oh S. I.
    • Transactions of Materials Processing
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    • v.15 no.1 s.82
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    • pp.9-14
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    • 2006
  • In the present research, the simultaneous punching of ultra small size hole of $2\~10\;{\mu}m$ in diameter on flat rolled thin metal foils was conducted with elastic polymer punch. Workpiece used in the present investigation were the rolled pure copper of $3{\mu}m$ in thickness and CP titanium of 1.5fm in thickness. The metal foils were punched with the dies and arrays of circular and rectangular holes were made. The process set-up is similar to that of the flexible rubber pad farming or Guerin process. Arrays of holes were punched successfully in one step forming. The punched holes were examined in terms of their dimensions. The effects of the wafer die hole dimension and heat treatment of the workpiece on ultra small size hole formation of the thin foil were discussed. The process condition such as proper die shape, pressure, pressure rate and diameter-thickness ratio (d/t) were also discussed. The results in this paper show that the present method can be successfully applied to the fabrication of ultra small size hole away in a one step operation.

An Experimental Study on Hydration Heat Control in The Mass Concrete Using Oscillating Capillary Tube Heat Pipe (진동세관형 히트파이프(OCHP)를 이용한 매스콘크리트의 수화열 제어에 관한 실험적 연구)

  • Beak, Dong-Il;Kim, Myung-Sik;Lee, Moon-Sik;Kim, Kang-Min;Yum, Chi-Sun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.409-412
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    • 2006
  • In process of reinforced concrete(RC) box structure, the heat of hydration may cause serious thermal cracking problems. In order to eliminate hydration heat of mass concrete, this paper reports results of hydration heat control in mass concrete using the OCHP(Oscillating Capillary tube Heat Pipe). Recently OCHP is drawn special attention from these points of low cost as well as short construction schedule for the manufacturing of heat exchanger, flexibility, simplification and high performance. There were three RC box molds$(1.2{\times}1.2{\times}1.2m)$ which shows a difference as compared with each other. One was not equipped with OCHP. While others were equipped with OCHP and these were cooled with air natural convection and spraying water respectively. The OCHP was composed of copper pipe with 12 turns(O.D : 4mm, I.D : 2.8mm). The working fluid was R-22 and its charging ratio was 30(Vol. %). In order to analyze the distribution of temperature and index figure of thermal crack in sequential placement of mass concrete, we used HYCON of computer program. As a result of the experiment, the peak temperature decreased about $15.6\sim23.4^{\circ}C$ than the general specimen and the probability of thermal crack generated in mass concrete decreased up to 0%.

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A Study for Optimum Design and Fabrication of Microscale Solenoid RF Chip Inductors (극소형 솔레노이드 RF 칩 인덕터의 설계 및 제작에 대한 연구)

  • 윤의중;정영창
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.11
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    • pp.501-507
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    • 2003
  • In this study, microscale, high-performance, solenoid-type RF chip inductors were investigated. The size of the RF chip inductors fabricated in this work was 1.0${\times}$0.5${\times}$0.5㎣. 96% $Al_2$ $O_3$and I-type were used as the material and shape of the core, respectively. The copper (Cu) wire with 6 turns was employed as the coils. The diameter (40${\mu}{\textrm}{m}$) and position (middle) of the coil and the length (0.35mm) of solenoid were determined by a high-frequency structure simulator (HFSS) to maximize the performance of the inductors. High frequency characteristics of the inductance (L) and quality-factor (Q) of developed inductors were measured using an RF Impedance/Material Analyzer (HP4291B with HP16193A test fixture). The inductors developed have inductances of 10.8nH and quality factors of 25.2 to 50 over the frequency ranges of 250MHz to l GHz, and show results comparable to those measured for the inductors prepared by CoilCraf $t^{Tm}$ . The simulated data predicted the high-frequency data of the L and Q of the inductors developed well.l.

A Study on the Development of Stress Optic Law Considering Residual Stress in Photo elastic Experiment(I) (잔류응력을 고려한 광탄성실험의 광응력법칙 개발에 관한 연구 (1))

  • 서재국;황재석;최선호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.5
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    • pp.1190-1201
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    • 1995
  • Photoelastic experiment has been restricted by three significant problems such as the problems of modeling for a complicated body, of development of experimental model material, and of residual stress in photoelastic specimen. The residual stress in photoelastic model materials is caused by molding, cutting and time effects, etc.. Especially, large residual stress exists on the interface of photoelastic model material for bi-material. Small residual stress occurred in the photoelastic model materials is usually neglected in the photoelastic experiments. But the residual stress provides some errors in the results of photoelastic experiments. In this paper, the stress optic law which can be effectively applied to the phtoelastic model materials with residual stress is developed. By using this stress optic law, we can obtain good results from isochromatic fringe patterns of photoelastic experiment specimen in which residual stress are involved. The stress optic law can be applied to obtain good results of photoelastic experiment from composite materials or bimaterials.

pH Effect on Lead Transport into astrocytes by Divalent Metal Transporter 1 (DMT1/Nramp2)

  • Cheong, Jae-Hoon;Desmond I. Bannon;Josep P. Bressler
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2001.11a
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    • pp.91-91
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    • 2001
  • Nramp2, also known as DMT1 and DCT1, is a 12-transmembrane domain protein responsible for dietary iron uptake as well as metal ions such as lead, manganese, zinc, copper, nickel, cadmium, and cobalt. High expression of DMT1 increase lead uptake, and DMT1-dependent lead transport was H -dependent and inhibited by iron ions. The molecular mechanism of lead transport in CNS is as yet unknown. although interactions between iron and lead at the level of absorption have been known for some time. The process of lead uptake into astrocytes was not known yet. Nramp2 may mediate transport of heavy metal into astrocytes. We investigated whether Nramp2 mediate transport of lead into astrocytes. And we do whether Nramp2 was expressed highly by deprivation of iron in Astrocytes, and lead uptake into astrocytes was influenced by expression of Nramp2. Immortalized human fetal astrocyte(SV-FHA) cells were cultured in medium containing Dulbecco's modified Eagle's medium and treated with Deferoxamine. Northern blot analysis was done for determining mRNA level of DMT1 and lead uptake assay was done in incubation condition of pH 5.5 and 7.4.

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Study on Factors Leading to Seasonality of Reproduction in Dairy Buffaloes. I. Nutritional Factors

  • Qureshi, M.S.;Samad, H.A.;Habib, G.;Usmani, R.H.;Siddiqui, M.M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.7
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    • pp.1019-1024
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    • 1999
  • Fifth one Nili-Ravi dairy buffaloes were studied in North-west Frontier Province of Pakistan. Rectal examination of reproductive organs was carried out on days 14 and 21 and then fortnightly. Milk samples were collected and analyzed for progesterone levels (MPL). Feed samples were collected fortnightly and analyzed. The buffaloes calving during the normal breeding season (NBS, August to January) (p<0.01) postpartum estrus interval of 55.95 days versus 91.15 days in those calving during the low breeding season (LBS, February to July). MPL in the LBS remained lower than the NBS (p<0.01). Shortest postpartum ovulation interval was noted during autumn(August to October), followed by winter (November to January), summer (May to July) and spring (February to April). The incidence of silent ovulations was during LBS than NBS (70.6% versus 29.4%). In autumn there was minimum intake of crude protein (CPI) and maximum intake of metabolizable energy (MEI, p<0.01). Calcium intake was higher in NBS than LBS calving buffaloes (p<0.01). Phosphorus, copper and magnesium intake was lower (p<0.05) and zinc intake was higher (p<0.01) in autumn, It was (p<0.05) and zinc intake was higher (p<0.01) in autumn, It was concluded that onset of breeding season was associated with increasing MEI and decreasing CPI and minerals intake.

Copper MOCVD using catalytic surfactant : Novel concept

  • Hwang, Eui-Seong;Lee, Jihwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.30-30
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    • 1999
  • 알루미늄에 비해 전기저항이 낮고 electromigration 및 stress-migration에 대한 저항서이 높은 구리는 차세대 반도체 소자의 배선금속 재료로 여겨지고 있다. 최근 Chemical Mechanical Polishing (CMP) 기술의 도래로 구리배선 공정의 채택이 더욱 앞당겨질 전망이다. 한편, 구리 MOCVD를 위해 다양한 전구체화합물이 합성되었고, 근래에는 Cu(I)(hfc)L (L은 Lewis base 형태의 ligand) 형태의 전구체를 이용한 많은 증착 연구를 통하여 순수하고 전기저항이 낮은 구리 박막의 증착이 보고되었다. 구리 MOCVD의 가장 큰 문제점은 증착속도가 150-$^{\circ}C$20$0^{\circ}C$에서 500$\AA$/min 이하로 낮고 또한 증착된 필름 표면이 매우 거칠다는 데 있다. 이러한 단점으로 인해 전기화학적 증착후 CMP를 적용하는 것이 더욱 경제적이라는 견해가 우세해 지고 있다. 본 강연에서는 박막의 증착 속도와 표면 거칠기를 동시에 향사시키기 위해 catalytic surfactant를 이용한 새로운 MOCVD 개념을 도입하고, 구리 MOCVD에서 단원자층으로 흡착된 요오드 원자가 그 역할을 수행할 수 있음을 보이겠다. 또 요오드원자가 표면반응을 어떻게 수정하여 활성화에너지를 낮추는가를 반응메카니즘으로 밝히고 표면 평탄화의 미시적 해석을 제공하고자 한다. Catalytic Surfactant의 개념은 다른 박막 재료의 MOCVD에도 적용될 수 있으며, 나아가 적절한 기판 표면처리를 통하여 epitaxy도 가능할 것으로 본다.

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