• Bulletin of the Korean Chemical Society
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• 제23권5호
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• pp.721-726
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• 2002

Two new C2-symmetric chiral $\alpha-$ and w-Diimines incorporating bulky ferrocenylethylamine and their copper(I)complexes have been synthesized and characterized by analytical and various spectroscopic techniques. The catalytic activities of these complexes have been tested in the asymmetric cyclopropanation of a series of olefins with some diazoacetates to achieve varying degree of dia- and enantio-selectivities depending on the nature of the ligand, the substrates, and the reagents. Some mechanistic implication has been made with regard to the interactions among all these chemical species.

• Journal of the Korean Society for Heat Treatment
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• 제33권4호
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• pp.185-192
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• 2020

In this study, materials characterization of pure copper and copper based carbon nano-tube composite prepared by powder metallurgy method were investigated. Prior to evaluate materials characterization, spark plasma sintering processing variables such as sintering temperature, pressure, thickness and diameter of compacts was optimized to ensure the microstructure and materials property of pure Cu and Cu-CNT composite. In addition, corrosion behavior of Cu-based CNT composite produced by powder sintering method was investigated. It was confirmed from this study that the corroded surfaces of the composite shows less dissolution compared with pure copper in 3.5 wt% NaCl solution. The measured corrosion current density (I_corr) indicates improved corrosion property of Cu based composite containing small additions of CNTs in chloride containing media. Micro-galvanic activity between Cu and CNT was not observed in given sintering condition.

• Proceedings of the Korea Society of Environmental Toocicology Conference
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• 한국환경독성학회 2003년도 춘계학술대회
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• pp.156-157
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• 2003

The goal of this study is to develop a biomarker used in monitoring abnormal behaviors of Japanese medaka (Oryzias latipes) as a model organism caused by hazardous chemicals. Japanese medaka was treated under appropriate sublethal concentrations of copper and the fish were subjected to copper treatment after starvation for 48 hr. The untreated individuals showed common behavioral characteristics (i.e., smooth and linear movements with small curvatures) in the movement behaviors.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
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• pp.34-37
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• 2004

Recently advancing mobile communication tools and I.T industry, semiconductor device is requested more integrated, faster operation time and more scaled-down. Because of these reasons semiconductor device is requested multilayer interconnection. For the multilayer interconnection chemical mechanical polishing (CMP) becomes one of the most useful process in semiconductor manufacturing process. In this experiment, we focus on understand the characterize and improve the CMP technology by control of slurry flow rate. Consequently, we obtain that optimal flow rate of slurry is 170ml/min, since optimal conditions are less chemical flow and performance high with good selectivity to Ta. If we apply this results to copper CMP process. it is thought that we will be able to obtain better yield.

• Proceedings of the KIEE Conference
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1716-1718
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• 1996

It is well known that the metallophthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as $NO_2$ and also chemically and thermally stable. Therefore, lots of MPcs are studied for the potential chemical sensor for $NO_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS spectrascopy and ellipsometry. Transfer condition, film characterization, and preliminary results of current-voltage(I-V) characteristics of these films exposed to $NO_2$ gas as a function of film thickness will be discussed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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• pp.6.2-8
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• 1996

The NO$_2$ GAS-detection characteristic of CuTBT (Copper-tetra-tert-butylphtha1ocyanine) LB films were investigated through a study of current-voltage (I-V) characteristics with a variation of number N of interdigital electrodes (N=1∼25). A concentration of 200ppm NO$_2$ gas was used. It was found that a conductance G increases monotonically as the number of interdigital electrode increases, and a sensitivity $\Delta$G ($\Delta$G=G$\_$gas//G$\_$air/) is at least higher than 50 and stable. As far as a sensitivity is concerned, the sensitivity when N=26 is greater than that when N=1 by 70 or so. It indicates that the number of interdigital electrodes affects the currents, sensitivity and stability.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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• pp.162-165
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• 1996

It is well shown that the metallophthalocyanine (MPcs) are sensitive to tonic gaseous molecules such as NO$_2$ and also chemically and thermally stable. Therefore, lots of MPcs are studied for the potential chemical sensor for NO$_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyaninc ware prepared by Langmuir-Blodgett method and characterized by using UV-VIS spectrascopy and cllipsometry. Transfer condition, film characterization, and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$ gas as a function of film thickness will be discusscd.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.121-124
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• 1996

It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO$_2$and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for NO$_2$gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir -Blodgett method and characterized by using UV-VIS spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$gas as a function of film thickness, temperature and temperature were discussed.

• Proceedings of the KIEE Conference
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1247-1249
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• 1997

Langmuir-Blodgett(LB) method is one of the ways of fabricating organic ultra thin films. It is well known that It has the advantage to control the alignment and orientation of the molecules in the films. Metallo-phthalocyanines (MPcs) are sensitive to electron affinitive toxic gaseous molecules, such as $NO_2$, NO, $SO_2$. In this study, thin films of octa-dodecyloxy copper-phthalocyanine were prepared by LB method and characterized by using UV/Vis absorption spectroscopy and ellipsometry. Optimal transfer condition of LB films was investigated and preliminary results of current-voltage (I-V) characteristics of these films exposed to $NO_2$ gas as a function of film thickness.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.79-82
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• 1994

We have manufacture Copper-tetra-tert-butylphalocyanine (CuTBP)Langmuir-Blodgett(LB) films, which is known be sensitive to NO$_2$ gab. A response of these films to the NO$_2$ gab was studied. A surface pleasure of 25mN/m was obtained as a proper one for a film deposition. A deposited film status was identified with Uv/visible absorption spectra, ellipsometry measurements, and current-voltage(I-Y) characteristics. The NO$_2$ gas response experiments under 200ppm conducentration show that there are increment of electrical conductivity by 12 times, 5 seconds of response time, and 5 seconds of response time, and 90 seconds of recovery time.