• Bulletin of the Korean Chemical Society
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• v.27 no.7
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• pp.1048-1052
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• 2006

Ab initio calculations of the structure, atomic charges and natural bond orbital (NBO) have been performed at HF/6-311G** and B3LYP/6-311G** levels for the title compound of dibenzothiazyl-disulfide. The calculated results show that the two nitrogen atoms have the biggest negative charges and they are the potential sites to react with the metallic ions, which make the title compound become a di-dentate ligand. Vibrational frequencies of the title compound have been obtained and compared with the experimental value and the comparison indicates that B3LYP/6-311G** level is better than HF/6-311G** level to predict the vibrational frequencies for the system studied here. For the title compound, electronic absorption spectra calculated by time?ependent density functional theory (TD-DFT) are more accurate than Hartree-Focksingle-excitation CI (CI-Singles) method. NBO analyses show that the electronic transitions are mainly derived from the contribution of bands $\pi\rightarrow\pi^{*}$. Thermodynamic calculated results show that the formation of the title compound from 2-mercaptobenzothiazole is a spontaneous process at room temperature with the change of free Gibbs being negative value.

• Korean Journal of Human Ecology
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• v.16 no.2
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• pp.381-393
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• 2007

This study was intended to analyze and investigate a diversity of aesthetic values expressed in the military look of the Milan collections by using content analysis method to find what design characteristic and image emerged concretely in the later 20th century. A total of 334 military look works shown in fashion magazines such as Vogue and Collezioni Donna over the period between 1996 and 2000 were collected as research data, which were classified into 5 categories such as item, silhouette, color, color coordination, fashion image. The results were summarized as follows: first, it was found that coat was the most preferred item in expressing the military look image. Second, it was found that the straight line was the most preferred silhouette, which indicates that it was the most suitable silhouette in expressing the bisexual image of the military look. Third, in the colors of the military look, achromatic colors such as black and white were found to be of the highest frequency, which shows that achromatic colors continued to be proposed as fashionable colors around 1996 and this influence was reflected in the military look. Finally, in terms of the item of color coordination, monochromatic coordination accounted for more than half of the military look, through which it could be explained that designers utilized it greatly to make an effective expression of the masculine image.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.6
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• pp.864-871
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• 2015

Recently, one of the main research on the power distribution system is the microgrid. The microgrid is a combination of power sources and loads, which is controllable and has separable connection. The main objective of microgrid is the deployment of the renewable clean energy and the enhancement of load-side reliability. The modern power sources and loads have DC I/O interfaces, which is the major advantage of DC microgrid compared to the conventional AC grid. The components in the microgrid have diverse features, so there is need of proper coordination control. For achieving economic feature, the active power of renewable energy resources is regarded as major control parameter and the whole operation modes of DC microgrid are defined, and the proper operations of each component are described. From the inherent characteristics of DC, there are two control variables: voltage and active power. Through analysis of operation modes, it is possible to determine exact control objectives and optimized voltage & power control strategy in each mode. Because of consideration of whole operation modes, regardless of the number and capacity of components, this coordination control method can be used without modification. This paper defines operation mode of DC microgrid with several DC sources and suggests economic and efficient coordinated control methods. Simulation with PSCAD proves effectiveness.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.42 no.4
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• pp.116-125
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• 2019

The Dynamic Vehicle Routing Problem (DVRP) involves a combinatorial optimization problem where new customer demands become known over time, and old routes must be reconfigured to generate new routes while executing the current solution. We consider the high level of dynamism problem. An application of highly dynamic DVRP is the ambulance service where a patient contacts the service center, followed by an evaluation of case severity, and a visit by a practitioner/ ambulance is scheduled accordingly. This paper considers a variant of the DVRP and proposes a decentralized algorithm in which collaborators (Depot and Vehicle), both have only partial information about the entire system. The DVRP is modeled as a periodic re optimization of VRP using the proposed decentralized algorithm where collaborators exchange local information to achieve the best global objective for the current state of the system. We assume the existence of a dispatcher e.g., headquarter of the company who can communicate to vehicles in order to gather information and assigns the new visits to them. The effectiveness of the proposed decentralized coordination algorithm is further evaluated using benchmark data given in literature. The results show that the proposed method performed better than the compared algorithms which utilize the centralized coordination in 12 out of 21 benchmark problems.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3727-3732
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• 2013

The interaction between metalloporphyrins and diazine tautomers was investigated using quantum chemistry method. The results showed that the metal atom in the metalloporphyrin was not coplanar with porphin ring, and zinc porphyrin has the most extent of its non-coplanar nature. The most stable complex in nine complexes was iron porphyrin. NBO analysis indicated that the interaction between the lone pair of electrons on the nitrogen atom and the unoccupied lone pair orbital of metal contributes significantly to the stability of the complexes. Through the conceptual DFT parameter and Fukui dual descriptor, the thermodynamic stability and reactivity of complexes were analyzed. The density difference function (DDF) analyzes were performed to explore the rearrangement of electronic density after the coordination interaction. NICS calculation indicated that metalloporphyrin aromaticity was reduced after the coordination interaction, and aromaticity of diazine tautomer was increased along direction vector of the coordination interaction force.

• Journal of electromagnetic engineering and science
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• v.7 no.2
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• pp.83-90
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• 2007

In this paper, the formulation of the protection ratio based upon a composite fade margin and availability is newly presented for the detailed planning of frequency coordination in the microwave relay system network, and computed results for co-channel and adjacent channel protection ratios are illustrated over an actual system with 6.2 GHz. It is shown that the protection ratio to assure a quality of service can be expressed in terms of the composite fade margin, noise-to-interference ratio, net filter discrimination, and system parameters. In addition, the net filter discrimination, depending upon the transmitter spectrum mask and the overall receiver filter characteristic, has been examined to investigate the effect of the adjacent channel protection ratio caused by the adjacent channel interference. Regarding simulated results for 6.2 GHz, 60 km, 64-QAM, and N/I=6 dB at the bit error rate of $10^{-6}$, composite fade margin and co-channel protection ratio yield 25.14 and 50.3 dB, respectively. Also, the net filter discrimination of 26.5 dB and the adjacent channel protection ratio of 23.8 dB are obtained at the first adjacent channel of 30 MHz. The proposed method provides some merits in view of a comprehensive and practical application with more detailed and various system parameters needed to access the criteria for making the proper frequency coordination.

• Bulletin of the Korean Chemical Society
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• v.30 no.5
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• pp.1061-1066
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• 2009

Two fluoro-substituted 2-pyrazoline derivatives, 1-phenyl-3-(4-methoxyphenyl)-5-(4-fluorophenyl)-2-pyrazoline (1) and 1-phenyl-3-(4-methoxyphenyl)-5-(2-fluoro-phenyl)-2-pyrazoline (2) have been synthesized and characterized by elemental analysis, IR, UV-Vis and fluorescence spectra. The crystal structure of 1 has been determined by X-ray single crystal diffraction. For the two compounds, density functional theory (DFT) calculations of the structures and natural population atomic charge analysis (NPA) have been performed at B3LYP/6-311G** level of theory. By using TD-DFT method, electron spectra of 1 and 2 have been predicted, which are very approximate with the experimental ones. Comparative studies on 1 and 2 indicate that the location change of fluorine atom in 5-position phenyl ring of 2-pyrazoline does not make significant change of geometries and electronic transition bands, but it leads to evident change of atomic charge distributions and peak intensities of UV and fluorescence spectra.

• Journal of Communications and Networks
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• v.18 no.4
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• pp.639-648
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• 2016

Next-generation (4G) systems are designed to support universal frequency reuse (UFR) to achieve best use of valuable spectra. However, it leads to undesirable interference level near cell borders. To control this, 4G systems adopt techniques, such as network multiple-input multiple-output (MIMO) and inter-cell interference coordination (ICIC), to improve cell-edge throughput. Network MIMO aims at mitigating inter-cell interference towards cell-edge users (CEUs) through multi-cell cooperation, where each collaborative base station serves both cell-center users (CCUs) and CEUs, including other cells' CEUs, under a power constraint. The present ICIC strategies cannot be directly applied to network MIMO because they were designed in absence of multi-cell coordination. In the presence of network MIMO, this paper investigates antenna orientations in ICIC and the method of power management. Results show that a proper antenna orientation can improve the cell-edge capacity and meantime lower the interference to CCUs. Capacity inconsistency between CCUs and CEUs is detrimental to mobile communications. Simulation results show that the proposed power management for ICIC in network MIMO systems can achieve a uniform data rate regardless users' position.

• Proceedings of the KIEE Conference
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• 2008.11a
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• pp.34-36
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• 2008

In this paper, we study on the necessity for limiting impedance of Superconducting Fault Current Limiter(SFCL) considering protective coordination. Several countermeasures have been proposed to protect the power system effectively from the larger fault current. Among them, the SFCL has been expected as one of the most effective solutions. However, the application of SFCL into power system can cause some problems, such as non-operation of instantaneous elements, of protective coordination because of limiting fault current. So we suggest that impedance of SFCL is must limited for operation of instantaneous elements. 'This method is essential to introduce application of SFCL into power distribution system.

• Proceedings of the KIEE Conference
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• 2005.11b
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• pp.313-315
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• 2005

Recently There has been growing interest in new renewable energy systems with high-energy efficiency due to the increasing energy consumption and environmental pollution problems. But an insertion of new distributed generation to existng power distribution systems can cause several problems such as voltage variations, harmonics, protective coordination, increasing fault current etc, because of reverse power. This paper was applied to fault location defecting a method as each Relay sensing fault current value and carried out short-circuit analysis by MATLAB and PSCAD/EMTDC programs and identity the faulted section o f22.9[kV] distribution system interconnected a large number of distributed generation. The existing protection system of 22.9[kV] power distribution system analyzed and the study on protective coordination recloser and Sectionalzer accomplished