• 한국전자파학회논문지
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• 제23권10호
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• pp.1173-1179
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• 2012

본 논문에서는 협력 무선 통신 시스템의 순방향 링크에서 각 이동국의 제한된 피드백 정보를 이용하여, 인접한 기지국들에서 동시에 전송되는 빔성형된 순방향 링크들 간의 간섭을 효과적으로 억제하는 충돌 회피 빔성형 기술을 제안한다. 제안하는 충돌 회피 빔성형 기술에서, 각 이동국은 서비스 기지국이 신호 전송을 위해 사용할 신호 가중치 벡터와 간섭 기지국이 해당 이동국에게 최대 간섭을 주는 주 간섭 가중치 벡터들에 대한 정보를 피드백한다. 또한, 클러스터 스케줄러는 각 기지국에서 사용하는 가중치들에 의해 성형되는 빔들 간의 충돌을 억제하도록, 동시에 데이터를 전송할 이동국들과 해당 이동국들이 사용할 빔성형 가중치들을 동시에 결정한다. 시뮬레이션을 통해 제안하는 충돌 회피 빔성형 기술이 기존의 기지국별로 빔성형을 수행하는 비 협력 빔성형 기술보다 높은 시스템 전송 용량을 제공할 수 있음을 보인다. 또한, 협력 공간 분할 다중 접속 기술과의 전송용량을 비교하여, 제안하는 충돌 회피 빔성형 기술과의 장단점을 비교 분석한다.

• Korean Membrane Journal
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• 제8권1호
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• pp.43-49
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• 2006

Complex membranes consisting of silver salt ($AgBF_4,\;AgCF_3SO_3,\;AgSbF_6,\;AgNO_3$) and poly(vinyl alcohol) (PVA) or crosslinked PVA (CPVA) were prepared and tested for the separation of propylene/propane mixtures. For the tested membranes, the complex membranes containing $AgBF_4$ exhibited the highest separation properties, i.e., approximately 20 GPU ($1 GPU=10^{-6}cm^3 (STP)/(cm^2 sec cmHg)$) and 100 of selectivity at 0.2 of silver mole fraction. The CPVA membranes containing silver salt always showed higher selectivity than PVA membranes, presenting silver ions coordinated to -CHO are more effective than those to -OH groups. The threshold silver concentration of CPVA membranes was lower than that of PVA membranes, which might be due to stronger interaction of silver ions with -CHO than that with -OH. The composition at which the selectivity is the highest did not significantly depend on the crosslinking, but did on the kind of silver salt.

• 대한전자공학회논문지TC
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• 제45권10호
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• pp.1-9
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• 2008

본 논문에서는 반직교 기반 사용자 선정과 제로 포싱(zero-forcing) 빔 형성에 기반한 간단하면서도 효율적인 세 셀 단위 셀 협력 전송 방법을 제안한다. 육각 셀룰라 시스템 모델에서 각 셀마다 두 그룹의 사용자를 갖는 와이너 (Wyner) 채널 모델에 대해서, 제안한 제로-포싱 협력 전송 방식의 합 전송율의 상계치는 송신 안테나 수와 사용자수의 이중 로거리듬(logarithm)에 비례함을 보인다. 모의 실험 결과는 제안된 협력 전송 방식의 효율성을 확증하며, 사용자 수에 따른 합 전송율은 상계치와 거의 같음을 확인할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제16권6호
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• pp.524-528
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• 1995

The reaction of [IrCl(cod)]2 with ppol ligand, Ph2PCH2CH2CH2P(Ph)CH2CH2CH=CH2, in ethanol gives an iridium complex, whose structure is converted from an ionic form, [Ir(cod)(ppol)]Cl·2C2H5OH (1),in polar solvents (ethanol, methanol and acetonitrile), to a molecular form, [IrCl(cod)(ppol)], in non-polar solvents (benzene and toluene). The cationic complexes, [Ir(cod)(ppol)]AsF6·1/2C2H5OH and [Ir(cod)(ppol)]PF6·1/2CH3CN, were prepared to compare with the ionic form by 31P NMR spectroscopy. When carbon monoxide is introduced to 1, cod is replaced by CO to give the 5-coordinated complex, [IrCl(CO)(ppol)]. Hydrogenation of 1-octene was not successful in the presence of 1. In order to verify the reason for 1 not behaving as a good catalyst for hydrogenation, electrophilic reactions with HCl, I2 and HBF4·etherate were performed, which yielded the oxidative addition product, [IrHCl2(ppol)], the substitution product, [IrI(cod)(ppol)], and another cationic product, [Ir(cod)(ppol)]BF4, respectively. Thus, the iridium complex is not sufficiently basic to activate hydrogen atoms or the olefin of the ppol ligand.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.48-54
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• 2012

The $[Fe_4S_4]^{2+}$ clusters with 2-, 3-, and 4-pyridinemethanethiolate (S2-Pic, S3-Pic, and S4-Pic, respectively) terminal ligands have been synthesized from the ligand substitution reaction of the $(^nBu_4N)_2[Fe_4S_4Cl_4]$ (I) cluster. The new $(^nBu_4N)_2[Fe_4S_4(SR)_4]$ (R = 2-Pic; II, 3-Pic; III, 4-Pic; IV) clusters were characterized by FTIR and UV-Vis spectroscopy. Cluster II was crystallized in the monoclinic space group C2/c with a = 24.530 (5) $\AA$, b = 24.636(4) $\AA$, c = 21.762(4) $\AA$, ${\beta}=103.253(3)^{\circ}$, and Z = 8. The X-ray structure of II showed two unique 2:2 site-differentiated $[Fe_4S_4]^{2+}$ clusters due to the bidentate-mode coordination by 2-pyridinemethanethiolate ligands. Cluster III was crystallized in the same monoclinic space group C2/c with a = 26.0740(18) $\AA$, b = 23.3195(16) $\AA$, c = 22.3720(15) $\AA$, ${\beta}=100.467(2)^{\circ}$, and Z = 8. The 3-pyridinemethanethiolate ligand of III was coordinated to the $[Fe_4S_4]^{2+}$ core as a terminal mode. Cluster IV with 4-pyridinemethanethiolate ligands was found to have a similar structure to the cluster III. Fully reversible $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ redox waves were observed from all three clusters by cyclic voltammetry measurement. The electrochemical potentials for the $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ transition decreased in the order of II, III and IV, and the reduction potential changes by the ligands were explained based on the structural differences among the complexes. The complex III was reacted with sulfonium salt of $[PhMeSCH_2-p-C_6H_4CN](BF_4)$ in MeCN to test possible radical-involving reaction as a functional model of the [$Fe_4S_4$]-SAM (S-adenosylmethionine) cofactor. However, the isolated reaction products of 3-pyridinemethanethiolate-p-cyanobenzylsulfide and thioanisole suggested that the reaction followed an ionic mechanism and the products formed from the terminal ligand attack to the sulfonium.