• Title/Summary/Keyword: Conversion of $CO_2$ to CO

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Autothermal Reforming Reaction of Methane using Ni-Ru/$Al_2O_3$-MgO Metallic Monolith Catalysts (Ni-Ru/$Al_2O_3$-MgO 금속 모노리스 촉매체를 이용한 메탄의 자열 개질반응)

  • Lee, Chang-Ho;Lee, Tae-Jun;Shin, Jang-Sik;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.321-328
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    • 2011
  • The autothermal reforming reaction of methane was investigated to produce hyd rogen with Ni/$CeO_2-ZrO_2$, Ni/$Al_2O_3$-MgO and Ni-Ru/$Al_2O_3$-MgO catalysts. Honeycomb metalli c monolith was applied in order to obtain high catalytic activity and stability in autothermal r eforming. The catalysts were characterized by XRD, BET and SEM. The influence of various catalysts on hydrogen production was studied for the feed ratio($O_2/CH_4$, $H_2O/CH_4$). The $O_2/CH_4$ and $H_2O/CH_4$ ratio governed the methane conversion and temperature profile of reactor. Th e reactor temperature increased as the reaction shifted from endothermic to exothermic reactio n with increasing $O_2/CH_4$ ratio. Among the catalysts used in the experiment, the Ni-Ru/$Al_2O_3$-MgO catalyst showed the highest activity. The 60% of $CH_4$ conversion was obtained, and th e reactor temperature was maintained $600^{\circ}C$ at the condition of GHSV=$10000h^{-1}$ and feed ratio S/C/O=0.5/1/0.5.

Effect of Polyherbal Feed Supplement "Growell" during Induced Aflatoxicosis, Ochratoxicosis and Combined Mycotoxicoses in Broilers

  • Kalorey, D.R.;Kurkure, N.V.;Ramgaonkar, J.S.;Sakhare, P.S.;Warke, Shubhangi;Nigot, N.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.3
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    • pp.375-383
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    • 2005
  • An experiment was conducted to study the protective role of polyherbal feed supplement (Growell) during induced mycotoxicosis in broilers. A total of 240 Vencobb broilers were divided at day old stage into eight equal groups. Group A served as control and was given plain feed, group B, D, F and H were given Growell at 0.35 g/kg of feed. Group C, D, G and H were given dietary aflatoxin $B_1$ at 0.2 ppm and groups E, F, G and H were given ochratoxin A at 0.2 ppm in feed to study effect of Growell on individual aflatoxicosis, ochratoxicosis and combined mycotoxicosis of broilers. The chicks were given their respective feeds from 1st day to 6th week of age and were vaccinated at 7th and 28th day of age with Lasota strain of Newcastle disease virus. There was no statistically significant effect of mycotoxins individually or in combination on body weight of broilers. However, body weights were highest in group B and lowest in co-mycotoxicated group G. Feed conversion ratio was best in group B followed by A, D, F, E, H and G. Significant improvement in haemoglobin values was observed in broilers due to feeding of Growell in ochratoxin and co-mycotoxicated groups. There was no significant effect of mycotoxin treatment on PCV, TEC and TLC of broilers. Due to single and combined mycotoxicosis, there was reduction in serum total protein, albumin, cholesterol and triglyceride and rise in alkaline phosphatase, creatinine and uric acid levels. Supplementation of diets with Growell reduced the alterations induced due to mycotoxins. There was a significant rise in per cent organ weight of liver and reduction of that of spleen, bursa of Fabricius and thymus of broilers fed mycotoxins. Protection from alteration in per cent organ weight of these organ by supplementation of Growell was recorded. The observed impaired immune response and histopathological changes in liver, kidney, spleen, bursa of Fabricius and thymus of broilers given mycotoxins were protected by supplementation of Growell.

Enhancement of the Characteristics of Cement Matrix by the Accelerated Carbonation Reaction of Portlandite with Supercritical Carbon Dioxide

  • Kim, In-Tae;Kim, Hwan-Young;Park, Geun-Il;Yoo, Jae-Hyung;Kim, Joon-Hyung;Seo, Yong-Chil
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.586-591
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    • 2001
  • This research investigated the feasibility of the accelerated carbonation of cement waste forms with carbon dioxide in a supercritical state. Hydraulic cement has been used as a main solidification matrix for the immobilization of radioactive and/or hazardous wastes. As a result of the hydration reaction for major compounds of portland cement, portlandite (Ca(OH)$_2$) is present in the hydrated cement waste form. The chemical durability of a cement form is expected to increase by converting portlandite to the less soluble calcite (CaCO$_3$). For a faster reaction of portlandite with carbon dioxide, SCCD (supercritical carbon dioxide) rather than gaseous $CO_2$, in ambient pressure is used. The cement forms fabricated with an addition of slated lime or Na-bentonite were cured under ambient conditions for 28days and then treated with SCCD in an autoclave maintained at 34$^{\circ}C$ and 80atm. After SCCD treatment, the physicochemical properties of cement matrices were analyzed to evaluate the effectiveness of accelerated carbonation reaction. Conversion of parts of portlandite to calcite by the carbonation reaction with SCCD was verified by XRD (X-ray diffraction) analysis and the composition of portlandite and calcite was estimated using thermogravimetric (TG) data. After SCCD treatment, tile cement density slightly increased by about 1.5% regardless of the SCCD treatment time. The leaching behavior of cement, tested in accordance with an ISO leach test method at 7$0^{\circ}C$ for over 300 days, showed a proportional relationship to the square root of the leaching time, so the major leaching mechanism of cement matrix was diffusion controlled. The cumulative fraction leached (CFL) of calcium decreased by more than 50% after SCCD treatment. It might be concluded that the enhancement of the characteristics of a cement matrix by an accelerated carbonation reaction with SCCD is possible to some extent.

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Design of SPOKE Type BLDC Motor for Traction Application Considering Irreversible Demagnetization of Permanent Magnet

  • Hur Jin;Kang Gyu-Hong
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.2
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    • pp.129-136
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    • 2005
  • This paper presents a design strategy of SPOKE type BLDC motors considering an irreversible demagnetization of a permanent magnet (PM). So the irreversible demagnetization characteristic of the motor is analyzed by rotor structure. The instantaneous currents in either starting or lock rotor condition, which are calculated from the current dynamic analysis, are applied to the analysis of the irreversible demagnetization field by FEM. In irreversible demagnetization analysis by FEM, the variation of residual flux density in PM is analyzed using the non-linearity of magnetic core on B-H plan. The analysis results are compared to several rotor structures and used for optimize the rotor structure.

Regulation and Function of the Peg3 Imprinted Domain

  • He, Hongzhi;Kim, Joomyeong
    • Genomics & Informatics
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    • v.12 no.3
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    • pp.105-113
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    • 2014
  • A subset of mammalian genes differ functionally between two alleles due to genomic imprinting, and seven such genes (Peg3, Usp29, APeg3, Zfp264, Zim1, Zim2, Zim3) are localized within the 500-kb genomic interval of the human and mouse genomes, constituting the Peg3 imprinted domain. This Peg3 domain shares several features with the other imprinted domains, including an evolutionarily conserved domain structure, along with transcriptional co-regulation through shared cis regulatory elements, as well as functional roles in controlling fetal growth rates and maternal-caring behaviors. The Peg3 domain also displays some unique features, including YY1-mediated regulation of transcription and imprinting; conversion and adaptation of several protein-coding members as ncRNA genes during evolution; and its close connection to human cancers through the potential tumor suppressor functions of Peg3 and Usp29. In this review, we summarize and discuss these features of the Peg3 domain.

ADVANCED SFR DESIGN CONCEPTS AND R&D ACTIVITIES

  • Hahn, Do-Hee;Chang, Jin-Wook;Kim, Young-In;Kim, Yeong-Il;Lee, Chan-Bock;Kim, Seong-O;Lee, Jae-Han;Ha, Kwi-Seok;Kim, Byung-Ho;Lee, Yong-Bum
    • Nuclear Engineering and Technology
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    • v.41 no.4
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    • pp.427-446
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    • 2009
  • In order to meet the increasing demand for electricity, Korea has to rely on nuclear energy due to its poor natural resources. In order for nuclear energy to be expanded in its utilization, issues with uranium supply and waste management issues have to be addressed. Fast reactor system is one of the most promising options for electricity generation with its efficient utilization of uranium resources and reduction of radioactive waste, thus contributing to sustainable development. The Korea Atomic Energy Research Institute (KAERI) has been performing R&Ds on Sodium-cooled Fast Reactors (SFRs) under the national nuclear R&D program. Based on the experiences gained from the development of KALIMER conceptual designs of a pool-type U-TRU-10%Zr metal fuel loaded reactor, KAERI is currently developing Advanced SFR design concepts that can better meet the Generation IV technology goals. This also includes developing, Advanced SFR technologies necessary for its commercialization and basic key technologies, aiming at the conceptual design of an Advanced SFR by 2011. KAERI is making R&D efforts to develop advanced design concepts including a passive decay heat removal system and a supercritical $CO_2$ Brayton cycle energy conversion system, as well as developing design methodologies, computational tools, and sodium technology. The long-term Advanced SFR development plan will be carried out toward the construction of an Advanced SFR demonstration plant by 2028.

A stepwised catalytic combustion of ammonia with $H_2$ and CO on supported Pt, Pd and Rh catalysts (Pt, Pd와 Rh가 담지된 촉매상에서 암모니아와 수소/일산화탄소의 단계별 촉매연소에 관한 연구)

  • Hwang, J.Y.;Ryu, I.S.;Lee, K.C.;Lee, S.J.;Noh, D.S.;Rhee, K.S.;Kang, S.K.
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.20-26
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    • 2006
  • This study investigated on the conversion of nitrogen component in ammonia gas to control fuel-NOx. Control conditions were found to suppress the production of NOx in the catalytic combustion of the gasified fuels. Also, the results would provide the basis of the theoretical study on fuel-NOx generation mechanism.

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Effect of La Promoter in the Production of Synthesis Gas over Supported Ni Catalysts (니켈담지촉매에서 합성가스 제조시 La 조촉매의 영향)

  • Hwang, Jae-Young;Kim, Young-Kook;Lim, Yun-Soo;Park, Hong-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.1
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    • pp.89-96
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    • 2004
  • The effect of La promoter on the carbon deposition and catalytic activity in the synthesis gas production with supported Ni catalysts was investigated. Active component was Ni and support was $CeO_2$ and the promoter used was La. The reaction was carried out in a fixed bed reactor at 1 atm and $650{\sim}800^{\circ}C$. The catalysts were prepared by two methods, the impregnation method and urea method. The catalysts prepared by the urea method showed 10 times higher surface area than those of prepared by the impregnation method. By the introduction of La promoter in the catalyst system, carbon deposition was remarkably reduced from 16% to 2%. It appears that the promoter facilitates the formation of a stable fluoride-type phase, which reduces the carbon deposition. The best catalytic activity and CO and $H_2$ selectivities were obtained with 2.5wt% $Ni/Ce(La)O_x$ catalyst at $750^{\circ}C$, giving 90% methane conversion, 93 and.80% of CO and $H_2$ selectivities, respectively.

Preparation of Monodispersed Crosslinked Polymer Beads (단분산상으로 가교된 고분자 비드의 합성)

  • 심상은;변재만;전종원;차윤종;최순자
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.287-298
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    • 2000
  • In preparing micron-sized monodisperse polystyrene beads by dispersion polymerization, the conversion, and the particle size and its distribution were affected by the reaction temperature, concentration of the monomer, solvent and initiator, molecular weight and concentration of the steric stabilizer, amount of oxygen existing in the reactor, and an appropriate combination of these starting materials. Ethanol as a dispersing agent, styrene as a monomer, PVP as a steric stabilizer, AIBN as an initiator, DVB as a cross-linking agent and toluene as a co-solvent were the basic materials for the synthesis. The reaction rate and the conversion were increased with the reaction temperature and the amount of DVB from 1 to 4%, and the conversion was saturated after 10 hours of the reaction time. The optimum reaction recipe for the preparation of the monodisperse PS beads was 25% styrene monomer, 0.5% DVB, 25% toluene, 10-15% PVP, and 2 and 4% AIBN, thereby, 3.9~4 ${\mu}{\textrm}{m}$ and 3.4~9.3 ${\mu}{\textrm}{m}$ of polystyrene beads, respectively, were successfully synthesized.

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Design Study of Fuel Supply System for 5MW-class Bio Gasturbine by Using Food Waste Water (5MW급 바이오 가스터빈용 전처리시스템 설계연구)

  • Hur, Kwang-Beom;Park, Jung-Keuk;Yun, Eun-Young;Lee, Jung-Bin
    • New & Renewable Energy
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    • v.7 no.2
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    • pp.10-17
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    • 2011
  • Korea is the 11th largest energy consumption country and 96% of its total energy consumption depends on imports from overseas. Therefore it is a very important task to secure renewable energy sources which can reduce both the carbon-dioxide emission and dependency on overseas energy imports. Among the various renewable energy sources, organic wastes are important sources. In Korea, 113 million toe of methane is generated from organic wastes annually, but only 3.7% is effectively used for energy conversion. Thus, it is very important to make better use of organic wastes, especially for power generation. The goals of this project are to develope the fuel supplying system of Bio Gasturbine (GT) for 5MW-class co-generation system. The fuel supplying system mainly consists of $H_2S$ removal system, Bio Gas compression system, Siloxane removal system and moisture separating systems. The fuel requirement of 5MW-class GT is at around 60% of $CH_4$, $H_2S$ (<30 ppm), Siloxane(<10 mg/$nm^3$) and supply pressure (> 25 bar) from biogas compressor. Main mechnical charateristics of Bio Gasturbine system have the specific performance; 1) high speed turbine speed (12,840 rpm) 2) very clean emmission NOx (<50 ppm) 3) high efficiency of energy conversion rate. This paper focuses on the development of design technology for food waste biogas pretreatment system for 5MW-class biogas turbine. The study also has the plan to replace the fuel of gas turbine and other distributed power systems. As the increase of bioenergy, this system help to contribute to spread more New & Renewable Energy and the establishment of Renewable Portfolio Standards (RPS) for Korea.