• Title/Summary/Keyword: Conversion Energy

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The effect of crystallinity of hollow $TiO_2$ spheres on conversion efficiency of DSSC (Hollow $TiO_2$의 결정성이 염료감응형 태양전지의 광전 변환 효율에 미치는 영향)

  • Song, Minkyeong;Kim, Jeonghyun;Yu, Yeontae
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.50.2-50.2
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    • 2011
  • 염료감응형 태양전지는 기존의 실리콘 태양전지에 비해 저렴한 가격과 다양한 날씨 조건에서도 태양광과의 반응성이 안정하다는 여러 가지 장점을 갖고 있다. 하지만 광전 변환 효율이 기존의 실리콘 태양전지에 비해 현저히 떨어진다는 문제점과 장기적으로 안정하지 못하다는 단점을 가지고 있다. 이러한, 염료감응형 태양전지에서 크게 광전 변환 효율을 향상시킬 수 있는 재료는 염료, $TiO_2$와 같은 반도체 산화물전극 재료, 전해질이다. 이 중 $TiO_2$의 특성 및 크기는 염료감응형 태양전지의 효율에 영향을 미친다. 염료감응형 태양전지의 광전 변환 효율을 증가시키기 위해서 $TiO_2$는 넓은 비표면적, 높은 전자의 이동성 및 태양광과의 우수한 반응성을 가져야 한다. Microwave hydrothermal 방법에 의해 제조된 hollow $TiO_2$를 염료감응형 태양전지에 적용시킬 경우 기존의 $TiO_2$의 광흡수 반응이 200~400 nm 사이에서 발생하는 반면, hollow $TiO_2$의 광흡수 반응은 기존의 UV 영역인 200~400 nm 뿐만 아니라 가시광 영역인 400~460 nm 에서도 광흡수 반응이 가능하기 때문에 염료감응형 태양전지에서 광전 변환효율을 증가 시킬 수 있을 것으로 기대된다. 또한, microwave hydrothermal법에 의해 제조된 hollow $TiO_2$는 150-200 nm의 크기를 갖으며 20-30 nm 크기의 $TiO_2$ particle들로 이루어져 있다. hollow $TiO_2$ (150-200 nm)를 기존의 $TiO_2$ (10-20 nm) 층 위에 올려 염료감응형 태양전지의 electrode에 적용할 경우 기존의 $TiO_2$ 단층을 이용한 것보다 우수한 light-scattering 효과를 갖게 되어 광전 변환 효율 증가에 긍정적인 영향을 미칠 것이다. 본 연구에서는 hollow $TiO_2$의 광학적 특성 및 결정성이 염료감응형 태양전지에 미치는 영향을 조사하였다. hollow $TiO_2$의 광학적 특성 및 결정성의 변화를 위하여 microwave hydrothermal 법의 합성 온도 및 합성시간에 변화를 주었다. hollow $TiO_2$의 광학적 특성은 UV-visible spectrometer를 이용하여 조사하였으며, hollow $TiO_2$의 형상과 결정학적 특성은 TEM과 SEM 그리고 X선 회절 분석을 이용하여 관찰되었고, hollow $TiO_2$의 비표면적 측정은 BET 측정법을 이용하였다. 또한 염료감응형 태양전지 cell을 제작하여 $100mW/cm^2$(AM 1.5G) 기준에서 광전 변환 효율을 측정하였다.

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Effects of Equivalent Weight of Epoxy Resins and Content of Catalyst on the Curing Reaction in Cationic Catalyst/Epoxy Cure System (양이온 촉매/에폭시 경화계에서 에폭시 수지의 당량 및 촉매 함량이 경화반응에 미치는 영향)

  • Kim, Youn Cheol;Park, Soo-Jin;Lee, Jae-Rock
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.960-966
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    • 1997
  • The effects of epoxy resins and content of catalyst on the cure characteristics were studied by FT-IR, DSC and dynamic viscometer for the thermal properties and rheological properties of the catalytic (N-Benzylpyrazinium hexafluoroantimonate, BPH) epoxy thermosetting system. Compared with DSC results of DEGBF containing 0.5wt% BPH, the DSC thermograms of DGEBA containing 0.5wt% BPH indicated that the reaction was faster than that of DGEBF/BPH and the conversion rate of DGEBA/BPH was high in the initial stage of the reaction. As the concentration of BPH increases, the reaction and conversion rates show similar value in both the cases. The influence of hydroxyl group of epoxy resin on gel point defined from the crossover point of storage modulus (G') and loss modulus (G") could be explained by the formation of 3-dimensional network in the initial stage owing to the curing reaction between epoxides and hydroxyl groups of epoxy resin. This was consistent with the gel point obtained from DSC, FT-IR and moduli crossover. The activation energy (Et) obtained from the crossover point (G'/G"=1) are $31-39kJ.mol^{-1}$ for various BPH compositions in case of two epoxy systems.

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Effects of feeding different varieties of faba bean (Vicia faba L.) straws with concentrate supplement on feed intake, digestibility, body weight gain and carcass characteristics of Arsi-Bale sheep

  • Wegi, Teklu;Tolera, Adugna;Wamatu, Jane;Animut, Getachew;Rischkowsky, Barbara
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.8
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    • pp.1221-1229
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    • 2018
  • Objective: A study was conducted to evaluate the varietal differences among faba bean straws and also to assess the potentials of faba bean straws supplemented with concentrate fed at the rate 70% straws and 30% concentrate mixture on feed intake, digestibility, body weight gain and carcass characteristics of the animals. Methods: Forty yearling Arsi-Bale sheep with initial body weight of $19.85{\pm}0.29kg$ (mean${\pm}$standard deviation) were grouped in a randomized complete block design into eight blocks of five animals each based on their initial body weight. Straws included in the study were from Mosisa (T1M), Walki (T2W), Degaga (T3D), Shallo (T4S), and local (T5L) varieties of faba bean and concentrate (2:1 ratio of wheat bran to "noug" seed cake). The experiment consisted of seven days of digestibility and 90 days of feeding trials followed by evaluation of carcass parameters at the end. Results: Local variety had lower (p<0.05) in grain and straw yield compared to improved varieties but higher in crude protein, metabolizable energy contents and in vitro organic matter digestibility. The apparent digestibility of dry matter and crude protein of sheep fed Walki and Mosisa straws were higher than (p<0.05) straws from Shallo varieties. Sheep fed Walki straw had greater (p<0.05) dry matter intake, average daily gain and feed conversion efficiency than sheep fed local and Shallo straws. Slaughter body weight and empty body weight were higher (p<0.05) for sheep fed Mosisa and Walki straws as compared to sheep fed Shallo straws. Apart from this, the other carcass components were not affected (p>0.05) by variety of the faba bean straws. Conclusion: There is significant varietal differences between faba bean straws both in quality and quantity. Similarly, significant variation was observed in feed intake, digestibility, body weight gain and feed conversion efficiency among sheep fed different straws of faba bean varieties with concentrate supplement. Based on these results, Walki and Mosisa varieties could be recommended as pulse crop rotation with cereals in the study area.

Rigorous Modeling and Simulation of Multi-tubular Reactor for Water Gas Shift Reaction (Water Gas Shift Reaction을 위한 Multi-tubular Reactor 모델링 및 모사)

  • Park, Junyong;Choi, Youngjae;Kim, Kihyun;Oh, Min
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.931-937
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    • 2008
  • Rigorous multiscale modelling and simulation of the MTR for WGSR was carried out to accurately predict the behavior of process variables and the reactor performance. The MTR consists of 4 fixed bed tube reactors packed with heterogeneous catalysts, as well as surrounding shell part for the cooling purpose. Considering that fluid flow field and reaction kinetics give a great influence on the reactor performance, employing multiscale methodology encompassing Computational Fluid Dynamics (CFD) and process modeling was natural and, in a sense, inevitable conclusion. Inlet and outlet temperature of the reactant fluid at the tube side was $345^{\circ}C$ and $390^{\circ}C$, respectively and the CO conversion at the exit of the tube side with these conditions approached to about 0.89. At the shell side, the inlet and outlet temperature of the cooling fluid, which flows counter-currently to tube flow, was $190^{\circ}C$ and $240^{\circ}C$. From this heat exchange, the energy saving was achieved for the flow at shell side and temperature of the tube side was properly controlled to obtain high CO conversion. The simulation results from this research were accurately comparable to the experimental data from various papers.

Analysis of Potential Greenhouse Gas Mitigation in Pohang Steel Industrial Complex (포항철강산업단지의 온실가스 잠재 감축량 분석)

  • Lee, Gwang Goo
    • Clean Technology
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    • v.20 no.4
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    • pp.439-448
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    • 2014
  • The potential mitigation of greenhouse gas (GHG) is studied in the Pohang steel industrial complex (PHSIC). The total GHG emission in 2010 is estimated to be in the range from 4,174,000 to 4,574,000 $tCO_2-eq$ in PHSIC. To meet the target proposed by the government, it is needed to reduce 552,000 $tCO_2-eq$ at minium by 2020. To estimate the potential amount of GHG reduction, the technologies used in the voluntary carbon reduction projects are applied to 51 companies which are subject to GHG target management. From the viewpoint of technological availability and payback period, the fuel conversion and waste heat recovery have an advantage in the short term with a possibility to reduce 160,000 $tCO_2-eq$. In the mid term, the thermal technologies in steel and iron industry have the potential to cut 229,000 $tCO_2-eq$, while the electrical technologies have the potential of 125,000 $tCO_2-eq$ reduction. The gap between the target GHG mitigation and potential reduction using the short and mid term technologies is about 38,000 $tCO_2-eq$, which should be compensated by the fundamental process innovation and the implementation of the most cutting-edge technologies including renewable energy.

Comparison of growth performances with three different Korean native chickens for a twelve-week post hatch period

  • Kim, Yu Bin;Cho, Hyun Min;Hong, Jun Seon;Koh, Nae Hyoung;Jeon, Jong Oh;Wickramasuriya, Samiru Sudharaka;Nawarathne, Shan Randima;Yi, Young-Joo;Heo, Jung Min
    • Korean Journal of Agricultural Science
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    • v.47 no.3
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    • pp.605-614
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    • 2020
  • This study was conducted to compare the growth performances of three groups of commercial Korean native chickens (KNCs) including two strains of crossbreeds and H3 (Hanhyeop 3) from hatch to twelve weeks of age. (1A, 2A, and H3). A total of 468 one-day-old chicks were allocated in a completely randomized design with 15 replicates per treatment for the crossbreeds and 9 replicates per treatment for H3 (12 birds per cage). Commercial broiler diets (i.e., Week 0 - 5 crude protein [CP] 22.0%, metabolizable energy [ME] 3,025 kcal·kg-1; week 5 - 8 CP 20.0%, ME 3,100 kcal·kg-1; week 8 - 12 CP 19.0%, ME 3,150 kcal·kg-1) were provided according to the Korean Feeding Standard for Poultry on an ad-libitum basis with fresh clean water during the twelve-week period. Body weight gain and shank length (SL) were measured weekly until week 6 and bi-weekly during week 6 to 12. Compared to H3, the two crossbreed groups had a higher body weight (BW) on weeks 3 to 8; however, the bodyweight of H3 on week 10 was significantly higher than the other groups (p < 0.05). Moreover, the average daily feed intake (ADFI) of H3 was higher than that of the two crossbreed groups from hatching to 84 days except for week 3, and H3 showed a lower average daily gain (ADG) on weeks 3 and 10 (p < 0.05). Furthermore, H3 had a higher feed conversion ratio compared to another crossbreed chicken on weeks 1 to 8 and the last week after hatching. Among all the groups, there was no significant difference for shank length during the experimental period.

Associations of the Porcine Melanocortin-4 Receptor (MC4R) Gene with Growth Traits in Duroc Pigs (듀록 품종의 Melanocortin-4 Receptor(MC4R) 유전자와 성장형질과의 연관성 분석)

  • Cho, K.H.;Kim, M.J.;Choi, B.H.;Jeon, G.J.;Ryu, J.W.;Jung, H.J.;Kim, I.C.;Lee, H.K.;Jeon, G.J.
    • Journal of Animal Science and Technology
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    • v.49 no.4
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    • pp.437-442
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    • 2007
  • The melanocortin-4 receptor(MC4R) is virtually expressed in all brain regions and plays an important role in energy homeostasis in mammals. MC4R has been intensively studied as a trait gene controlling economically important traits, such as growth and feed conversion, etc. Six hundreds and sixty Duroc pigs were genotyped for the MC4R locus and analyzed their relationships with breeding values for average daily gain(ADG), backfat thickness(BF), days to 90kg(D90) and feed conversion(FC). The estimated genotype frequencies for the all Duroc pigs were: 30.8%, 45.2%, 24.1% for AA, AB and BB genotypes, respectively. The mutant A allele was significantly associated with ADG, D90 and BF whereas no significant relationship was found with FC. The change of gene frequencies by generation was shown in both selected and culled groups. These results indicate that the MC4R polymorphism could be integrated in the present selection program to realize a marker-assisted selection for the growth traits of the Duroc population.

Comparison of Methane Production of Holstein Steers Fed Forage and Concentrates Separately or As a TMR (TMR과 조사료 농후사료 분리급여 방식의 홀스타인 거세우 메탄배출량 비교)

  • Lee, Yoonseok;Bharanidharana, Rajaraman;Park, Jae-Hyun;Jang, Sun Sik;Yeo, Joon Mo;Kim, Wan Young;Kim, Kyoung Hoon
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.36 no.2
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    • pp.104-108
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    • 2016
  • The objective of this study was to determine how feeding forage and concentrate separately (SF) or as a total mixed ration (TMR) affects enteric methane production of cattle. Six Holstein steers ($203{\pm}22.5kg$) were used in a $2{\times}3$ changeover design experiment. Experimental diets (TMR and SF) consisted of compound feed, timothy hay and soybean curd residue in a ratio of 40:48:12, respectively, and diets were fed at 10% of metabolic body weight, on an as-fed basis. There were no differences in dry matter intake and enteric methane production (g/d) between SF and TMR but the methane conversion rate (methane energy/GE intake) of TMR was significantly higher (p=0.05) than that of SF. The mean methane emission factor (kg/head/year) and conversion rate of the two treatments were 21.4 and 0.05, respectively. There was a strong relationship between metabolic body weight and enteric methane production (p<0.001). At the present time, further studies may be necessary in order to establish the effects of TMR and SF on enteric methane production.

A Study to Improve the DC Output Waveforms of AFE Three-Phase PWM Rectifiers (AFE 방식 3상 PWM 정류기의 직류 출력파형 개선에 관한 연구)

  • Jeon, Hyeon-Min;Yoon, Kyoung-Kuk;Kim, Jong-Su
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.6
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    • pp.739-745
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    • 2017
  • Many studies have been conducted to reduce environmental pollution by ships and reduce fuel consumption. As part of this effort, research on power conversion systems through DC distribution systems that link renewable energy with conventional power grids has been pursued as well. The diode rectifiers currently used include many lower harmonics in the input current of the load and distort supply voltage to lower the power quality of the whole system. This distortion of voltage waveforms causes the malfunctions of generators, load devices and inverter pole switching elements, resulting in a large number of switching losses. In this paper, a controller is presented to improve DC output waveforms, the input Power Factor and the THD of an AFE type PWM rectifier used for PLL. DC output voltage waveforms have been improved, and the input Power Factor can now be matched to the unit power factor. In addition, the THD of the input power supply has been proven by simulation to comply with the requirements of IEEE Std514-2014.

LMDI Decomposition Analysis on Characteristics of Greenhouse Gas Emission from the Line of Railroad in Korea (LMDI 분해 분석을 이용한 국내 철도 노선별 온실가스 배출 특성 분석)

  • Lee, Jae-Hyung;Lim, Jee-Jae;Kim, Yong-Ki;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.15 no.3
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    • pp.286-293
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    • 2012
  • Korean government is enforcing 'Greenhouse gas target management' in order to achieve Greenhouse gas reduction target. To attain Greenhouse gas reduction target, companies in Korea must establish their GHG inventory system and analysis their GHG emissions characteristics for deduction of mitigation measures. LMDI(Log Mean Divisia Index) decomposition analysis is widely used to understand characteristics of GHG emission and energy consumption. In this paper, the characteristics of GHG emission from the line of railroad in Korea is respectively analyzed in terms of conversion effect, intensity effect, production effect and distance effect. Data of railroad GHG emission from 2000 to 2007 are used. As a result, total effect of railroad's GHG emission is $96,813tCO_2eq$. Production effect ($39,865tCO_2eq$) and distance effect ($327,923tCO_2eq$) affect increase of railroad GHG emissions while Conversion effect ($-158,161tCO_2eq$) and intensity effect ($-112,814tCO_2eq$) influence decrease of the emissions.