• 제목/요약/키워드: Controlled crystallization

검색결과 102건 처리시간 0.023초

정공 주입층 특성에 따른 발광층에서의 재결합 영역 변화 (Change of Recombination Zone in Emission Layer by Characteristics of a Hole Injection Layer)

  • 한우미;임은주;이정윤;김명식;이기진
    • 한국전기전자재료학회논문지
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    • 제14권8호
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    • pp.675-678
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    • 2001
  • We fabricated the organic light emittign diodes (OLEDs) with ITO/Cu-Pc/triphenyl-diamine (TPD)/TPD+tris-(8-hydroxyquinoline) aluminum (Alq$_3$)/Al. The electrical properties of Cu-Pc thin film were studied as a hole injection layer. the energy gap of Cu-Pc thin films is decreased according to the substrate heat treatment temperature increased. It could be controlled the hole mobility by changing the heat treatment condition of Cu-Pc. The emission wavelengths could be controlled by changing hole mobility and recombination zone in emission layer.

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High Performance TFTs Fabricated Inside a Location-Controlled Grain by Czochralski (grain-filter) Process

  • Rana, Vikas;Ishihara, Ryoichi;Metselaar, J.W.;Beenakker, C.I.M.;Hiroshima, Yasushi;Abe, Daisuke;Higashi, Seiichiro;Inoue, Satoshi;Shimoda, Tatsuya
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.237-240
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    • 2003
  • This paper reports the characteristics of TFTs, formed inside a location-controlled grain: "single-crystalline" Si TFTs (c-Si TFTs). Position of the grains were controlled with a great precision by "${\mu}-Czochralski$ (grain-filter) process". Effects of process parameters, such as, deposition method of gate $SiO_2$, crystallization energy density and position of the channel with respect to the grain filters on TFT characteristics is investigated. It is concluded that the characteristics of TFTs drastically improved by avoiding the grain filter from the channel region. With TFTs having the current-flow direction parallel to radial direction from the grain-filter, electron mobility and subthreshold swing of 600 $cm^2/Vs$ and 0.21 V/dec. respectively are obtained.

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Characteristics of Barium Hexaferrite Nanoparticles Prepared by Temperature-Controlled Chemical Coprecipitation

  • Kwak, Jun-Young;Lee, Choong-Sub;Kim, Don;Kim, Yeong-Il
    • 대한화학회지
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    • 제56권5호
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    • pp.609-616
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    • 2012
  • Ba-ferrite ($BaFe_{12}O_{19}$) nanoparticles were synthesized by chemical coprecipitation method in an aqueous solution. The particle size and the crystallization temperature of the Ba-ferrite nanoparticles were controlled varying the precipitation temperature. The precipitate that was prepared at $0^{\circ}C$ showed the crystal structure of Ba-ferrite in X-ray diffraction when it was calcined at the temperature above $580^{\circ}C$, whereas what was prepared at $50^{\circ}C$ showed the crystallinity when it was calcined at the temperature higher than about $700^{\circ}C$. The particle sizes of the synthesized Ba-ferrite were in a range of about 20-30 nm when it was prepared by being precipitated at $0^{\circ}C$ and calcined at $650^{\circ}C$. When the precipitation temperature increased, the particle size also increased even at the same calcination temperature. The magnetic properties of the Ba-ferrite nanoparticles were also controlled by the synthetic condition of precipitation and calcination temperature. The coercive force could be appreciably lowered without a loss of saturation magnetization when the Ba-ferrite nanoparticles were prepared by precipitation and calcination both at low temperatures.

표면결정화유리에 관한 연구 (A Study on the Surface Crystallization of Glass)

  • 박용완;강은태
    • 한국세라믹학회지
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    • 제14권4호
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    • pp.230-235
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    • 1977
  • In this paper the conditions of surface crystallization of glass were studied. The basic glass which is apt to crystallize, with $SiO_2$ 72.50, $Al_2O_3$ 5, 00, $Na_2O$ 8.00 $K_2O$ 3.50, CaO 5.00, MgO 3.00, $B_2O_3$ 3.00 Wt% is chosen. The strain point and softening point of this glass is 4$25^{\circ}C$ and 778$^{\circ}C$ each, and between the two temperatures we could get grystal on its surface by immersion in salt baths during some controlled hours. The kind of crystal on the surface of glass was confirmed by X-ray diffraction analysis and the change of the thickness of crystalline layers depending on temperature and time, was surveyed by using optical microscope. The results are as follows; 1. The chloride group is more suitable than sulfate group for the treating salt. 2. In the condition with 50 LiCl.50NaCl at 62$0^{\circ}C$ for 2 hrs and with 50 LiCL.20-30 NaCl.30-20 $CaCl_2$ at 72$0^{\circ}C$ for 15-20 min. we could get the best crystalline layers. 3. The crystal was silica-O and petalite with a little tridymite and nepheline. 4. The thickness of crystalline layers increased with increasement of temperature and time.

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재조합 GG1234-DsRed 융합 단백질의 생산 및 In vitro 탄산칼슘 결정화에 미치는 영향에 대한 연구 (Production of Recombinant GG1234-DsRed Fusion Protein and Its Effect on in vitro CaCO3 Crystallization)

  • 손채연;김진호;김지하;최유성
    • KSBB Journal
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    • 제30권6호
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    • pp.296-301
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    • 2015
  • Eggshell-based biocomposites have become attractive due to their exquisite nanostructure and biological properties, which are mainly composed of highly organized calcium carbonate crystals controlled by organic macromolecules such as proteins and polysaccharides. Here, we designed the recombinant fusion protein of a putative eggshell matrix protein named as GG1234 and a fluorescent reporter protein of DsRed. The protein was successfully over-expressed in E. coli and purified by Ni-NTA affinity chromatography. In vitro calcium carbonate crystallization was conducted in the presence of the fusion protein, and morphological change was investigated. The protein inhibited the calcite growth in vitro, and spherical calcium carbonate micro-particles with the diameter of about $20-30{\mu}m$ were obtained. We expect that this study would be helpful for better understanding of eggshell-based biomineralization.

칼코게나이드 박막의 전기적 펄스에 의한 상변화 연구 (The phase transition with electric field in chalcogenide thin films)

  • 양성준;신경;이재민;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 디스플레이 광소자분야
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    • pp.115-118
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    • 2004
  • The phase transition between amorphous and crystalline states in chalcogenide semiconductor films can controlled by electric pulses or pulsed laser beam; hence some chalcogenide semoconductor films can be applied to electrically write/erase nonvolatile memory devices, where the low conductive amorphous state and the high conductive crystalline stale are assigned to binary states. AST(AsSbTe) used to phase change material by applying electical pulses. Thickness of AST chalcogenide thin film have about 100nm. Electrodes are made of ITO and Al. $T_c$(Crystallization temperature) of AST system is lower than that of the GST(GeSbTe) system, so that the current pulse width of crystallization process can be decreased.

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Crystallization and Electrical Properties of SBN60 Thin Films Prepared by Ion Beam Sputter Deposition

  • Jang, Jae-Hoon;Jeong, Seong-Won;Lee, Hee-Young
    • Transactions on Electrical and Electronic Materials
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    • 제6권1호
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    • pp.10-13
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    • 2005
  • $Sr_{0.6}Ba_{0.4}Nb_{2}O_{6}$, hereafter SBN60, thin films of 300 nm thickness were deposited using ion beam sputtering technique, in which sintered ceramic target of the same composition was utilized and the $Ar:O_{2}$ gas ratio was controlled during deposition onto $Pt(100)/TiO_{2}/SiO_{2}/Si$ substrate. Crystallization and orientation behavior as well as electrical properties of the films were examined after annealing treatment at $650{\sim}800{\cric}C$. It was found that the film orientation was dependent upon $Ar:O_{2}$ratio, in which strong (00l) orientation was developed when the gas ratio was about 1:4 at $4.3{\times}10^{-4}$ torr. Typical remanent polarization (2Pr), the coercive field (Ec) and the dielectric constant of Pt/SBN60/Pt thin film capacitor were approximately $10{\mu}C/cm^{2}$, 60 kV/cm, and 615, respectively.

太白山地區 망간鑛床에 있어서 酸化망간鑛物의 生成機構 (Mechanisms of Formation of Manganese Oxide Minerals in the Manganese Deposits of the Taebaeg Mt. Region, Korea)

  • 김수진;조현구;최헌수
    • 한국광물학회지
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    • 제5권1호
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    • pp.1-5
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    • 1992
  • 太白山地區의 主要 망간鑛床에서 産出하는 酸化망간 鑛物들은 一次的으로 생성된 炭酸망간 또는 珪酸망간의 表成風化作用에 依하여 生成되었다. 이들 酸化망간 鑛石의 生成에 관여된 地質作用에는 溶解作用, 酸化作用, 運搬作用, 沈澱作用, 晶出作用 및 再結晶作用 等이 있다. 그러나 箇箇의 酸化망간 鑛物 生成은 交代作用, 溶液으로부터의 晶出作用 및 固體狀態에서의 晶出, 및 再結晶作用 等에 依하여 이루어졌다. 이들 鑛物生成作用에 依하여 多樣한 名種 鑛石의 組職이 形成되었으며, 母鑛石의 鑛物組成과 風化環境에 따라 特徵的인 鑛物 및 鑛物共生關係가 形成되었다. 그러나 一般的으로 風化殘留鑛床 중의 酸化망간 鑛物들은 $Mn^{2+}{\to}Mn^{3+}{\to}Mn^{4+}$의 方向으로 生成되었다.

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High Temperature Durability Amorphous ITO:Yb Films Deposited by Magnetron Co-Sputtering

  • Jung, Tae Dong;Song, Pung Keun
    • 한국표면공학회지
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    • 제45권6호
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    • pp.242-247
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    • 2012
  • Yb-doped ITO (ITO:Yb) films were deposited on unheated non-alkali glass substrates by magnetron cosputtering using two cathodes (DC, RF) equipped with the ITO and $Yb_2O_3$ target, respectively. The composition of the ITO:Yb films was controlled by adjusting the RF powers from 0 W to 480 W in 120 W steps with the DC power fixed at 70 W. The ITO:Yb films had a higher crystallization temperature ($200^{\circ}C$) than that of the ITO films ($170^{\circ}C$), which was attributed to both larger ionic radius of $Yb^{3+}$ and higher bond enthalpy of $Yb_2O_3$, compared to ITO. This amorphous ITO:Yb film post-annealed at $170^{\circ}C$ showed a resistivity of $5.52{\times}10^{-4}{\Omega}cm$, indicating that a introduction of Yb increased resistivity of the ITO film. However, these amorphous ITO:Yb films showed a high etching rate, fine pattering property, and a very smooth surface morphology above the crystallization temperature of the amorphous ITO films (about $170^{\circ}C$). The transmittance of all films was >80% in the visible region.

$Fe_2O_3-CaO-SiO_2$계 결정화 유리의 제조 및 특성(II) (Characterization and Preparation of Glass-Ceramics in the System $Fe_2O_3-CaO-SiO_2$)

  • 이용근;최세영
    • 한국세라믹학회지
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    • 제33권1호
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    • pp.119-125
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    • 1996
  • Magnetic properties through controlled nucleation and crystallization wer studied for ferrimagnetic 40Fe2O3-20CaO-40SiO2 glass useful as thermoseeds for hyperthermia of tumor therapy. The maximum nucleation and crystal growth temperature are $700^{\circ}C$ and 100$0^{\circ}C$ respectively. The glass showed the maximum saturation magnetization of 168.4 emu/cm3 when nucleated $700^{\circ}C$ for 60 min and crystal grown at 100$0^{\circ}C$ for 4hrs. The maximum coercive force was 390 Oe when uncleated $700^{\circ}C$ for 60 min and crystal grown at 975$^{\circ}C$ for 2 hrs. The variation of the saturation magnetization could be well quantitatively interpreted in terms of the volume fraction of the magnetite whereas that of the coercive forces could be explained only qual.itatively in terms of the particle size of the magnetite. Hysteresis losses showed the maximum value of 0.18W/cm3 when heat treated at 100$0^{\circ}C$ for 4 hrs pre-necleated at $700^{\circ}C$ for 60 min and temperature increase of 7K under AC magnetic field of 10 kOe and 10kHz.

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