• Bulletin of the Korean Chemical Society
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• v.6 no.6
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• pp.362-366
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• 1985

The hydrogen atom transfer reaction between substituted methane, $CH_3X,$ and its radical, $CH_2X(X=H,F,CH_3,CN,OH\;and\;NH_2$ was studied by MINDO/3 method. The transition state(TS) structure and energy barriers were determined and variation of the transition state and of the reactivity due to the change of X were analyzed based on the potential energy surface characteristics. It was found that the greater the radical stabilization energy. the looser the TS becomes; the TS occurs at about 15% stretch of the C-H bond, which becomes longer as the radical stabilization energy of $CH_2X$ increasers. The intrinsic barrier, ${\Delta}E*_{x.x},$ of the reaction with X was found to increase in the order $H The degree of bond stretch of the C-H bond stretch of the C-H bond at the TS also had the same order indicating that the homolytic bond cleavage of the C-H bond is rate-determining. Orbital interactions at the TS between LUMO of the fragment $C{\ldots}H{\ldots}C$ and the symmetry adapted pair of nonbonding, $n{\pm}(=n_1{\pm}n_2),$ or pi orbitals of the two X atoms were shown to be the dominant contribution in determining tightness or looseness of the TS. The Marcus equation was shown to apply to the MINDO/3 barriers and energy changes of the reaction.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.30 no.2
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• pp.70-77
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• 2022

This study is a study to analyze the stress difference of pilots according to the category of aircraft. According to previous studies, pilot stress is affected by several factors such as flight time, fatigue regulation, and operating environment, and it is known that stress also affects cardiac variability. In this paper, we analyzed that there is a difference in stress according to the operating environment through airline pilots and pilots of educational institutions, and then tested the difference in stress between airplane pilots and helicopter pilots. This study differs in that it is a study that has almost no empirical research on pilot fatigue and stress considering the role of flight crew members and operational conditions for each mission. If we expand and verify the sample of the results for the stress difference in the future, it will be a great contribution to practical aviation safety research in connection with the fatigue risk management system in the future.

• Advances in aircraft and spacecraft science
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• v.8 no.4
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• pp.289-302
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• 2021

Ensuring flight safety for passengers as well as crew is the most important aspect of modern aviation, and in order to achieve this, it is necessary to be able to forecast the durability of individual components. The present contribution illustrates the results of a computational analysis to determine the possibility of analysing the prediction of bearing durability in on-board rotating equipment from the point of view of thermal fatigue.In this study, a method developed at the Air Force Institute of Technology was used for analysis, which allowed to determine the bearing durability from the flight altitude profile. Two aircraft have been chosen for analysis - a military M-28 and a civilian Embraer. As a result of the analysis were obtained: the bearing durability in on-board rotating devices, average operation time between failures, as well as failure rate. In conclusion, the practical applicability of this approach is demonstrated by the fact that even with a limited number of flight parameters, it is possible to estimate bearing durability and increase flight safety by regular inspections.

• Journal of Korea Society of Digital Industry and Information Management
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• v.18 no.3
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• pp.75-82
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• 2022

The purpose of the Consumer sentiment index survey is to determine the consumer's economic situation and consumption spending plan, and it is used as basic data for diagnosing economic phenomena and forecasting the future economic direction. The purpose of this paper is to analyze and predict the future Consumer sentiment index using the ARMA model based on the past consumer index. Consumer sentiment index is determined according to consumer trends, so it can reflect consumer realities. The consumer sentiment index is greatly influenced by economic indicators such as the base interest rate and consumer price index, as well as various external economic factors. If the consumer sentiment index, which fluctuates greatly due to consumer economic conditions, can be predicted, it will be useful information for households, businesses, and policy authorities. This study predicted the Consumer sentiment index for the next 3 years (36 months in total) by using time series analysis using the ARMA model. As a result of the analysis, it shows a characteristic of repeating an increase or a decrease every month according to the consumer trend. This study provides empirical results of prediction of Consumer sentiment index through statistical techniques, and has a contribution to raising the need for policy authorities to prepare flexible operating policies in line with economic trends.

• Proceedings of the Korea Information Processing Society Conference
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• 2009.04a
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• pp.35-38
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• 2009

The paper presents an effective method to detect fire in video surveillance and monitoring system. The main contribution of this work is that we successfully use the Hidden Markov Models in the process of detecting the fire with a few preprocessing steps. First, the moving pixels detected from image difference, the color values obtained from the fire flames, and their pixels clustering are applied to obtain the image regions labeled as fire candidates; secondly, utilizing massive training data, including fire videos and non-fire videos, creates the Hidden Markov Models of fire and non-fire, which are used to make the final decision that whether the frame of the real-time video has fire or not in both temporal and spatial analysis. Experimental results demonstrate that it is not only robust but also has a very low false alarm rate, furthermore, on the ground that the HMM training which takes up the most time of our whole procedure is off-line calculated, the real-time detection and alarm can be well implemented when compared with the other existing methods.

• Nuclear Engineering and Technology
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• v.26 no.1
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• pp.78-89
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• 1994

The radionuclide release rates from the engineered barrier composed of concrete structure and clay-based backfill in a low and intermediate level waste repository were assessed. Four types of release pathway were considered, and the contribution of each pathway to the total release were analyzed. To quantify the effect of uncertainties of input parameter values on the assessment of radionuclide release rates, the Latin Hypercube sampling method was used, and the resulting release rate distribution were determined through a goodness-of-fit test. Finally, the ranges of maxi-mum release rates ore estimated statistically with a confidence level of 95%.

• Nuclear Engineering and Technology
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• v.55 no.1
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• pp.378-390
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• 2023

The SPES (Selective Production of Exotic Species) facility, currently under development at Legnaro National Laboratories of INFN, aims at the production of intense RIB (Radioactive Ion Beams) employing the Isotope Separation On-Line (ISOL) technique for interdisciplinary research. The radioactive isotopes of interest are produced by the interaction of a multi-foil uranium carbide target with a 40 MeV 200 μA proton beam generated by a cyclotron proton driver. The Target Ion Source (TIS) is the core of the SPES project, here the radioactive nuclei, mainly neutron-rich isotopes, are stopped, extracted, ionized, separated, accelerated and delivered to specific experimental areas. Due to efficiency reasons, the TIS unit needs to be replaced periodically during operation. In this highly radioactive environment, the employment of autonomous systems allows the manipulation, transport, and storage of the TIS unit without the need for human intervention. A dedicated remote handling infrastructure is therefore under development to fulfill the functional and safety requirement of the project. This contribution describes the layout of the SPES target area, where all the remote handling systems operate to grant the smooth operation of the facility avoiding personnel exposure to a high dose rate or contamination issues.

• International Journal of Computer Science & Network Security
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• v.23 no.4
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• pp.156-165
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• 2023

IEEE 802.15.4e-TSCH is recognized as a wireless industrial sensor network standard used in IoT systems. To ensure both power savings and reliable communications, the TSCH standard uses techniques including channel hopping and bandwidth reserve. In TSCH mode, scheduling is crucial because it allows sensor nodes to select when data should be delivered or received. Because a wide range of applications may necessitate energy economy and transmission dependability, we present a distributed approach that uses a cluster tree topology to forecast scheduling requirements for the following slotframe, concentrating on the Poisson model. The proposed Optimized Minimal Scheduling Function (OMSF) is interested in the details of the scheduling time intervals, something that was not supported by the Minimal Scheduling Function (MSF) proposed by the 6TSCH group. Our contribution helps to deduce the number of cells needed in the following slotframe by reducing the number of negotiation operations between the pairs of nodes in each cluster to settle on a schedule. As a result, the cluster tree network's error rate, traffic load, latency, and queue size have all decreased.

• Journal of Distribution Science
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• v.20 no.6
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• pp.67-74
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• 2022

Purpose: In the current era of rapid development of the information and communication technologies (ICT) sector, the formation of an effective regulatory approach is important. There are some methodological shortcomings and difficulties in the approach system of international organizations that assesses the level of application of ICT in various areas in terms of quantity and quality. The basic element of economic growth differs according to the economic conditions prevailing in the period and the country. While the agricultural sector plays an active role in economic growth or development in an underdeveloped country, in a developed country, capital-intensive and even technology-intensive production is the main element of economic growth. From this point of view, the contribution of information and communication technologies (ICT) to Azerbaijan's socio-economy for the period between 2010-2020 will be examined. Research design and methodology: The unit root test and Granger causality test were applied by taking the CDPPC per Capita, Employment, and Unemployment Rate from the social-o-economic data as the dependent variable, fixed and mobile phone usage and internet usage as the independent variables. The principal results: According to the results obtained; It has been determined that the use of ICT positively affects the socio-economic economic situation.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.1
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• pp.31.2-31.2
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• 2021

To estimate the contribution of quasars on keeping the IGM ionized, building a quasar luminosity function (LF) is necessary. Quasar LFs derived from multiple quasar surveys, however, are incompatible, especially for the faint regime, emphasizing the need for deep images. In this study, we construct quasar LF reaching M₁₄₅₀~-21.5 AB magnitude at z ~ 5, which is 1.5 mag deeper than previously reported LFs, using deep images from the Hyper Suprime-Cam Subaru Strategic Program (HSC-SSP). We trained an artificial neural network (ANN) by inserting the colors as inputs to classify the quasars at z ~ 5 from the late-type stars and low-redshift galaxies. The accuracy of ANN is > 99 %. We also adopted the Bayesian information criterion to elaborate on the quasar-like objects. As a result, we recovered 5/5 confirmed quasars and remarkably minimized the contamination rate of high-redshift galaxies by up to six times compared to the selection using color selection alone. The constructed quasar parametric LF shows a flatter faint-end slope α=-127^+0.16_-0.15 similar to the recent LFs. The number of faint quasars (M₁₄₅₀ < -23.5) is too few to be the main contributor to IGM ionizing photons.