• 대한화학회지
• /
• 제17권2호
• /
• pp.130-135
• /
• 1973

여러 pH에서 3,4-methylenedioxyphenylmethyllenemalonitrile의 가수분해속도상수를 자외선분광광도법에 의하여 측정하여 넓은 궤도 범위에서 잘 맞는 반응속도식을 구하였다. 이 속도식에 의하면 가수분해 반응메카니즘 특히 종전에 잘 규명된 바 없는 산성 용매 속에서의 반응 과정을 잘 설명할 수 있다. 즉 pH 5 이하에서는 물의 첨가로서 가수분해가 시작되며 pH 6∼8 사이에서는 물분자와 수산화이온의 첨가가 경쟁적으로 일어나나 pH 9 이상에서는 수산화이온만이 첨가된다. 한편 친핵성 시약과 촉매 역할을 겸하고 있는 수산화이온 및 물의 역할로 잘 설명할 수가 있었다.

• 천문학회지
• /
• 제48권6호
• /
• pp.399-412
• /
• 2015

We study the radio properties at 1.4 GHz of Seyfert galaxies with strong forbidden highionization lines (FHILs), selected from the Sloan Digital Sky Survey - a large-sized sample containing nearly equal proportion of diverse range of Seyfert galaxies showing similar redshift distributions compiled by using the Very Large Array survey images. The radio detection rate is low, 49%, which is lower than the detection rate of several other known Seyfert galaxy samples. These galaxies show low star formation rates and the radio emission is dominated by the active nucleus with ≤10% contribution from thermal emission, and possibly, none show evidence for relativistic beaming. The radio detection rate, distributions of radio power, and correlations between radio power and line luminosities or X-ray luminosity for narrow-line Seyfert 1 (NLS1), Seyfert 1 and Seyfert 2 galaxies are consistent with the predictions of the unified scheme hypothesis. Using correlation between radio and [O III] λ 5007 Å luminosities, we show that ∼8% sample sources are radio-intermediate and the remaining are radio-quiet. There is possibly an ionization stratification associated with clouds on scales of 0.1-1.0 kpc, which have large optical depths at 1.4GHz, and it seems these clouds are responsible for free-free absorption of radio emission from the core; hence, leading to low radio detection rate for these FHIL-emitting Seyfert galaxies

• 대한안전경영과학회지
• /
• 제24권4호
• /
• pp.41-47
• /
• 2022

A reliable prediction model of national occupational accident fatality rate can be used to evaluate level of safety and health protection for workers in a country. Moreover, the socio-economic aspects of occupational accidents can be identified through interpretation of a well-organized prediction model. In this paper, we propose a machine learning based relative comparison methods to predict and interpret a national occupational accident fatality rate based on socio-economic indicators. First, we collected 29 years of the relevant data from 11 developed countries. Second, we applied 4 types of machine learning regression models and evaluate their performance. Third, we interpret the contribution of each input variable using Shapley Additive Explanations(SHAP). As a result, Gradient Boosting Regressor showed the best predictive performance. We found that different patterns exist across countries in accordance with different socio-economic variables and occupational accident fatality rate.

• The Korean Journal of Physiology
• /
• 제28권1호
• /
• pp.79-90
• /
• 1994

The objective of the present study is to assess the contribution of bulk flow to the regulatory mechanism of amniotic fluid volume and its ionic concentration in the membranes surrounding the amniotic fluid. For quantitative assessment, we prepared 4 kinds of artificial amniotic fIuids (isotonic isovolumetric, hypotonic isovolumetric, isotonic hypervolumetric and hypotonic hypervolumetric ones) by replacing 70% of amniotic fluid of pregnant rabbits with water or normal Tyrode solutions. Isoosmotic saline of 0.5 ml volume containing 0.05% Censored and 15 mM/l LiCl was administered initially into amniotic sacs of all subject animals. Samples of amniotic fluid were collected in after 30 and 90 minute intervals; the concentrations of Censored, $Na^+\;and\;Li^+$ were determined and compared. Followings are the results obtained. 1. from isovolumetric and increased Congcord group, we couldn't find significant change in $Li^+\;and\;Na^+$ concentration in isotonic amniotic fluid. However, $Na^+$ concentration increased significantly as well as a striking increase in Censored concentration in hypotonic amniotic fluid. 2. In isovoIumetric and decreased Censored group, the rate of $[Li^+]$ decrement and the rate of $[Na^+]$ increment were much higher in hypotonic amniotic fluid than in isotonic. 3. In hypervolumetric and increased Censored group, the rate of $Na^+$ efflux increased proportionately with the increment of Censored concentration up to 0.98, which was higher than the rate of $Li^+$ efflux in isotonic amniotic fluid. However, the increment of $Na^+$ concentration was rather related with the initial $Na^+$ concentration in hypotonic amniotic fluid, showing inverse relationship. $Li^+$ concentration increased only when there was a marked increase in Censored concentration and approached near a maximum value or 1. 4. For hypervolumetric and decreased Censored group, the observations were identical to isovolumetric and decreased Censored group. From these results the following conclusions could be made: 1) There is no net movement of water or monovalent cations across the membranes surrounding amniotic fIuid in isotonic isovolumetric condition. In contrast, there is a net efflux of amniotic fluid by osmotic bulk flow, resulting in elevation of $Na^+$ concentration in hypotonic isovolumetric condition. 2) In hypervolumetric conditions, there is a massive efflux of amniotic fluid or solvent drag through the surrounding membranes by fiItrative bulk flow, where the rate of $Na^+$ efflux has a linear relationship with that of water efflux. This is assumed to be carried out through enlarged and newly opened intercellular spaces resulting from increased intraamniotic pressure. 3) Once increasing intraamniotic pressure reaches a point allowing $Li^+$ to pass through during osmotic bulk flow in hypotonic amniotic fIuid, $Na^+$ influx seems to occur by diffusion simultaneously or immediately thereafter, too.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2010년도 추계학술대회 논문집
• /
• pp.421-426
• /
• 2010

With hydraulic noise test facility, a variety of tests were performed to investigate the pulsation pressure generation mechanism and its transmission characteristics and to derive the noise control methodology. Many experiments were carried out by changing average pressure, flow rate, pump speed, hose length and MCV spool condition. From the test results, the correlations between pulsation pressure and other design parameters, such as static pressure, flow rate and MCV spool opening area and length of hose, were found out. And also each contribution factors were evaluated from the regression analysis. By changing hose length, the pulsation pressure resonance phenomenon was investigated. In order to find out the pulsation pressure reduction measures pulsation pressure analysis, such as pulsation pressure of hydraulic pump itself and pulsation pressure of hydraulic system, by using AMESim were studied. In addition hydraulic silencer was developed based on the Helmholtz resonator. And its performance was evaluated by installing the silencer at the excavator.

• ETRI Journal
• /
• 제31권5호
• /
• pp.489-499
• /
• 2009

This paper focuses on assessment and design of transmission systems for distribution of digital signals over standard Category-7A copper cables at speeds beyond 10 Gbps. The main contribution of this paper is on the technical feasibility and system design for data rates of 40 Gbps and 100 Gbps over copper. Based on capacity analysis and rate optimization algorithms, system parameters are obtained and the design implementation trade-offs are discussed. Our simulation results confirm that with the aid of a decision-feedback equalizer and powerful coding techniques, namely, TCM or LDPC code, 40 Gbps transmission is feasible over 50 m of CAT-7A copper cable. These results also indicate that 100 Gbps transmission can be achieved over 15 m cables.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 1996년도 춘계학술발표회논문집(2)
• /
• pp.227-232
• /
• 1996

The one-third calibrating relation by steady solution can cause large error when applied to an unsteady flow with large amplitude waves. Extended calibrating method, which can treat the normal convective contribution, is developed. The normal mass convective term is included into the 2-D mass transport equation by means of rms value and random function. The unknown shear rate is numerically determined by solving the 2-D mass transport equation inversely. This recovery method which predicts the unknown shear rate is constructed. It is found that it works very well without distortion. The inclusion of the normal convective term has a negligible effect on the mass transfer coefficient.

• 품질경영학회지
• /
• 제27권3호
• /
• pp.51-66
• /
• 1999

This paper empirically investigates the impact of winning a quality award by investigating the rate of return of a firm's stock in the stock market, and by analyzing the contribution and effectiveness to a firm's competitiveness. It also compares the effect of firms winning MB(Malcolm Baldrige) award with that of firms winning Korean quality awards on the stock market. A comparative method is used to analyze the change of award-winning firms'rate of return and then they are classified by time-series, cross-sectional, firm's size, award agency, and the year of receiving the award. The number of firms employed in this study is 74, however, multiple award-winning firms are included in the analysis, which increased the sample size to 118. Results indicate that Korean quality awards improve an award-winning firms'market value but not as much as the MB award did.

• 품질경영학회지
• /
• 제27권3호
• /
• pp.40-50
• /
• 1999

This paper empirically investigates the impact of winning a quality award by investigating the rate of return of a firm's stock in the stock market, and by analyzing the contribution and effectiveness to a firm's competitiveness. It also compares the effect of firms winning MB(Malcolm Baldrige) award with that of firms winning Korean quality awards on the stock market. A comparative method is used to analyze the change of award-winning firms'rate of return and then they are classified by time-series, cross-sectional, firm's size, award agency, and the year of receiving the award. The number of firms employed in this study is 74, however, multiple award-winning firms are included in the analysis, which increased the sample size to 118. Results indicate that Korean quality awards improve an award-winning firms'market value but not as much as the MB award did.

• 수산해양기술연구
• /
• 제45권4호
• /
• pp.276-286
• /
• 2009

The main purpose of this research is to analyze economic feasibility of biodegradable sonw crab gill net model project. The results of benefit/cost analysis show that use of the biodegradable gear is economically feasible. Assuming that the rate of gill net lost is 5 percent, net present value was estimated 311,898,282-590,533,375won, benefit-cost ratio 1.816-1.923 and internal rate of return 7.96-10.59%. The development and diffusion of biodegradable fishing gear appear to make a significant contribution to fisheries resource conservation and marine ecosystem protection. In addition, biodegradable gear production firms may have a good opportunity of exporting it to other coastal states, depending on the progress of WTO subsidy negotiation.