• Journal of Environmental Science International
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• v.11 no.2
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• pp.93-102
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• 2002

Using a simple continuous optical technique, coupled with measurements of zeta potential, the flocculation characteristics of kaoline suspensions of different content(15, 35 and 55 NTU) by several cationic polyelectrolytes, has been examined. The optimum mixing is obtained under a constant stirring of 200 rpm, differently from a general flocculation test. The charge density of a polyelectrolyte is important in determining the optimum dosage and in the removal of kaoline particles. The optimum dosage is less for the polyelectrolyte of higher charge density and is the same regardless of kaoline content. At the dosage, the removal of kaoline particles is higher for the polyelectrolyte of higher charge density and zeta potential of kaoline particles reaches to near zero. The rate of adsorption and flocculation rate have been found to be affected by charge density and molecular weight of a polyelelctrolyte and the content of kaoline particles.

• Journal of the Korean Society of Safety
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• v.14 no.1
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• pp.78-85
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• 1999

The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.91-103
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• 1995

The reaction rate, equilibrium, and flow injection analysis methods were fundamentally evaluated for the determination of aqueous ammonia. The selected indophenol blue method was based on the formation of indophenol blue in which ammonium ion reacted with hypochlorite and phenol in alkaline solution. In the optimized reaction condition, the reaction followed 1st order reaction kinetics and the final product was stable. The absorbance measurements before and after the equilibrium were utilized for the reaction rate and equilibrium methods. The reaction rate methods, based on the relative analytical signals for the possibility of eliminating interferents, were shown to have good linear calibration curves but the detection limit and the calibration sensitivity were poorer than those in the equilibrium method. The detection limits were 32-49 pub and 24 pub for the reaction rate and equilibrium methods, respectively In the flow injection analysis, the absorbance was measured before the equilibrium reached and thus resulted in 30% reduction of calibration sensitivity. However, the detection limit was 11 ppb, indicating that the peak-to-peak noise for the blank was remarkably improved. Compared to the manual methods, the optimized experimental condition in a closed reaction system reduced the blank absorbance and the inclusion of ammonia from the atmosphere was prevented. In addition, highly reproducible mixing of sample and reagents and analytical data extracted from continuous recording showed excellent reproducibility.

• Microbiology and Biotechnology Letters
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• v.7 no.4
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• pp.211-216
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• 1979

Air lift fermentor (ALF) is widely used for production of single-cell protein (SCP) from hydrocarbon and other carbon sources, because oxygen transfer efficiency is believed to be superior in the ALF to that in other conventional fermentors. However, the performance of ALF in terms of mixing is somewhat questionable. In this research, we studied about the performance of the ALF in SCP production using methanol fermentation process as a model system. The results show that ALF could be employed for SCP production or other fermentation processes when substrate is miscible and used at low concentration. With a high substrate concentration, it must be operated under high pressure or low dilution rate to meet the adequate oxygen transfer requirement.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.718-724
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• 2008

The ion selective microelectrode (ISME) has been used for measuring the ion profile of DO, $NH_4{^+}-N$, $NO_2{^-}-N$ and $NO_3{^-}-N$ in biofilm. In this study we evaluated the detection limit and validity of ISME and applied ISME for the continuous measurement of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration in the modified Ludzack-Ettinger (MLE) process. Average detection limits of $NH_4{^+}-N$ and $NO_3{^-}-N$ ISME were $10^{-4.44}M$ and $10^{-4.62}M$, respectively. Since the ISME with $5{\sim}10{\mu}m$ of tip diameter showed a faster response time than that of $1{\sim}5{\mu}m$, the ISME with a tip diameter of $5{\sim}10{\mu}m$ was fabricated and used to make real-time ion detections. Direct monitoring of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentrations in the aerobic (2) tank causes the instability of the electromotive force (EMF) for the initial 5~8 hours and also causes remarkable error values of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration. This phenomenon is caused by aeration and mixing in the reactor. Thus, the measuring chamber was newly designed for the aerobic (2) tank and then the EMF of the ISME were stabilized in less than 1 hour. Errors of $NH_4{^+}-N$ and $NO_3{^-}-N$ concentration were decreased after stabilization of the EMF. The ISME analysis were well corresponded to the results of auto analyzer and ion chromatography. Consequently, the concentration of $NH_4{^+}-N$ and $NO_3{^-}-N$ could be continuously measured for 178 hours by the ISME.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.306-317
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• 2014

This study has been executed to understand the additional and removal processes of nutrients in the Saemangeum Salt-water Lake, and discussed with other monthly-collected environmental parameters such as water temperature, salinity, dissolved oxygen, suspended solids, and Chl-a from 2008 to 2010. $NO_3$-N, TP, $PO_4$-P, and DISi showed the removal processes along with the salinity gradients at the surface water of the lake, whereas $NO_2$-N, $NH_4$-N, and Chl-a showed addition trend. In the bottom water all water quality parameters except $NO_3$-N appeared addition processes indicating evidence of continuous nutrients suppliance into the bottom layer. The mixing modelling approach revealed that the biogeochemical processes in the lake consume $NO_3$-N and consequently added $NH_4$-N and $PO_4$-P to the bottom water during the summer seasons. The $NH_4$-N and $PO_4$-P appeared strong increase at the bottom water of the river-side of the lake and strong concentration gradient difference of dissolved oxygen also appeared in the same time. DISi exhibited continuous seasonal supply from spring to summer. Internal addition of $NH_4$-N and $PO_4$-P in the river-side of the lake were much higher than the dike-side, while the increase of DISi showed similar level both the dike and river sides. The temporal distribution of benthic flux for DISi indicates that addition of nutrients in the bottom water was strongly affected by other sources, for example, submarine ground-water discharge (SGD) through bottom sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.2
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• pp.63-69
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• 2008

As a basic study on the creation of artificial tidal flats using dredged sediments, the pilot-scale artificial tidal flats with 4 different mixing ratio of ocean dredged sediment were constructed in Nakdong river estuary. The phragmites australis was transplanted from the adjacent phragmites australis community after construction, and then the survival and growth rate of the planted phragmites australis were measured. Also the changes of soil chemical oxygen demand (COD), ignition loss (IL), and the heterotrophic microbial numbers were monitored. The survival rate of the planted phragmites australis decreased as the mixing ratio of dredged sediment increased but there was little difference of length and diameter of the shoots. 30% of COD and 9% of IL in the tidal flat with 100% dredged sediment decreased after 202 day, however, fluctuations of COD and IL concentrations were also observed possibly due to the open system. It was suggested that the construction of tidal flats using ocean dredged sediment and biological remediation of contaminated ocean dredged sediment can be possible considering the growth rate of transplanted phragmites australis, decrease of organic matter and increased heterotrophic microbial number in the pilot plant with 100% dredged sediment. However, the continuous monitoring on the vegetation and various environmental factors in the artificial tidal flat should be necessary to evaluate the success of creation of artificial flats using dredged sediments.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.623-630
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• 2007

Grouting materials are used for the unification of superstructural and substructural body like bridge seat (shoe) or machinery pedestal and e.t.c by filling their intercalary voids. Accordingly, grouting materials have been developed and used mainly with products of high strength because those materials are constructed specially in a part receiving large or impact load. In this situation, the structural body constructed by grouting materials with high stiffness-centered (caused by high strength) products is apt to cause brittle failure when receiving over a limit stress and to cause cracks according to cumulative fatigue by continuous and cyclic load. In addition, grouting materials are apt to cause cracks by using too much rapid hardening agents that give rise to high heat of hydration to maintain high strength at early age. In this study, to overcome these problems, cement type grouting materials including powder of waste tire and resin as elastic materials which aim to be more stable construction and to be improvement of mother-body's unification are developed and endowed with properties of high toughness and high durability add to existing properties of high flowability, non-shrinkage and high strength. Besides, this study contribute to of for green construction materials for being possible recycling industrial waste like waste tire and flyash. On the whole, seven type mixing conditions are tested and investigated to choose the best mixing condition.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.7 no.3
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• pp.157-170
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• 2002

To examine the structure and distribution of the Keum River plume produced by continuous river discharge we carried out three-dimensional numerical model experiments with or without Coriolis force and tide. When Coriolis force is included but tide is not the model plume forms the clockwise circulation north of southern channel in the developing stage. As the plume expansion progresses the center of circulation moves to the southwest, with fuming the discharging axis of low-salinity water to the southwest from the mouth of southern channel. These results are explained mainly in terms of barotropic geostrophy by surface slope maintained with accumulated low-salinity(buoyant) water in front of the estuary mouth due to of offshore strong salinity front. When the M$_2$ tide is included the model plume extends farther to the northwest, forming large tongue-like salinity distribution. The tidally averaged surface flows of the offshore plume are mainly in geostrophic balance. These changes in plume distribution are explained in terms of low-salinity water advection by tidal excursion and active tidal mixing; the former supplies low salinity water to the north off the estuary mouth and the later increases mean sea level along the plume and surface salinity in northern shallow coastal area. The main features of observed Keum River plume(Lee et al., 1999; Choi et al., 1999), which showed the northwestward deflection of the plume axis and northward deepening of the plume thickness from the estuary mouth region, are well reproduced by the model in which tide is included.

• Journal of the Korean Wood Science and Technology
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• v.27 no.2
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• pp.62-69
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• 1999

With increased utilization of chemical fertilizer, soil fertility is getting serious problem. As a result, using organic soil conditioner (woody wastes or sawdust compost) would be only solution to recover soil vitality. In this study, manufacturing and characteristics of organic soil conditioner from Shiitake bedlogs (woody wastes) were studied. Also, to investigate the effect of continuous application of this bedlog compost on growth of plants, growth tests for radish and tree seedlings were done. The results are as follows ; Analytical results of decayed and fresh wood materials showed almost same as its wood components. The mixing ratio of raw materials with the other filling materials is essential for the manufacturing as well as good quality of its compost during composting process. In this experiment, mixing 12kg of urea, 25kg of lime, 40kg of chicken shit, and small amount of fermentation aids corresponding to I ton of sawdust resulted in good composts. Their moisture contents were adjusted to about 55%. Temperature of pile, in composting process, rose after I week and kept about above $60^{\circ}C$ for certain period. They were turned two times, 30th and 59th day, respectively, after piling. This bedlog compost contained 81.7% of high organic matter, 1.4% of a little nitrogen, 6.75 of pH and 25 - 30 of C/N ratio. There were no harmful effect on germination and growth of plants, such as radish and softwood and hardwood seedlings. Concerned to the effect of bedlog compost on soil temperature, the compost did not affect plant growth by changing soil temperature abruptly, but compensated the soil temperature such as a little increasing on the early morning, a little decreasing on the mid-day or afternoon (pm 2:00), and increasing on the early evening (pm 6:00).