• Title/Summary/Keyword: Continuous Flow Reactor

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PREPARATION OF NICKEL POWDERS BY REDUCTION OF NICKEL HYDROXIDE USING THE TAYLOR FLUID FLOW

  • I.-J. PARK;D.-W. KIM;G.-H. KIM;H.-J. CHAE;H.-C. JUNG
    • Archives of Metallurgy and Materials
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    • v.63 no.3
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    • pp.1443-1447
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    • 2018
  • In this study, Ni(OH)2 was synthesized by the continuous reaction by the Taylor fluid flow and compared with those prepared from the conventional batch type reaction. The nickel powders were synthesized by reduction of Ni(OH)2 in an aqueous solution with hydrazine hydrate acting as the reductant. And then the characteristics of the nickel powder according to the synthesis method were compared. The average particle size of the synthesized Ni(OH)2 using Taylor reactor was generally decreased about 1.5~2.5 times more than the batch reaction. The nickel powders prepared by the batch reaction highly agglomerated with non-uniform particles. In the Taylor reaction, the agglomeration of particles was broken and uniform nickel powder was produced.

Phenol Treatment Plasma Reactor of Dielectric Barrier Discharge (유전체 장벽 방전 플라즈마 반응기를 이용한 페놀 처리)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.21 no.4
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    • pp.479-488
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    • 2012
  • A Dielectric barrier discharge (DBD) plasma is shown in the present investigation to be effective of phenol degradation in the aqueous solutions in batch reactor with continuous air bubbling. Removal of phenol and effects of various parameters on the removal efficiency in the aqueous solution with high-voltage streamer discharge plasma are studied. The effect of 1st voltage (80 ~ 220 V), air flow rate (3 ~ 7 L/min), pH (3 ~ 11), electric conductivity of solution (4.16 ${\mu}S$/cm, deionized water) ~ 16.57 mS/cm (addition of NaCl 10 g/L) and initial phenol concentration (2.5 ~ 20.0 mg/L) were investigated. The observed results showed that phenol degradation was higher in the basic solution than that of the acidic. The optimum values on the 1st voltage and air flow rate for phenol degradation were 140 V and 6 L/min, respectively. It was considered that absorbance variation of $UV_{254}$ of phenol solution can be use as an indirect indicator of change of the non-biodegradable organic compounds within the treated phenol solution. Electric conductivity was not influenced the phenol degradation. To obtain the removal efficiency of phenol and COD of phenol over 97 % (initial phenol concentration, 10.0 mg/L), 80 min and 120 min were need, respectively. Phenol and COD degradation showed a pseudo-first order kinetics.

Ammonia Emissions from Composting Hog Manure Amended with Sawdust under Continuous and Intermittent Aeration (돈분과 톱밥혼합물의 연속 및 간헐 통기 퇴비화에서 암모니아 휘산)

  • 홍지형
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.4
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    • pp.113-119
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    • 2001
  • Ammonia emissions during composting of hog manure mixed with sawdust were studied in four runs comprising a total of 22 pilot-scale reactor vessels. These four runs extended previous work and both verified and extended the previous conclusions. The pilot-scale vessels were 205 L insulated stainless steel drums that were aerated either continuously (high/low thermostatically controlled fans) or intermittently (5 min high fan 55 min off). Temperature ammonia emissions air flow rates carbon dioxide production and oxygen utilization moisture and dry matter reduction initial and final chemical compositions were measured. Ammonia emissions from the intermittently aerated vessels were only about 50% as great as those from the continuously aerated ones but this was found to be a result more related to total air flow than to aeration technique. All of the data for total result more related to total air flow were fitted with a linear regression line y=0.139x+29.835 where y is ammonia expressed as g of N and x is air flow in kg with $R^2$=0.6808. this general trend indicates that about 50% reduction in ammonia emissions can be achieved with 75% reduction in air flow. For the aeration techniques used the minimum oxygen level in te exhaust gas from the vessels was 5% and this is probably a resonable lower limit constraining air flow reduction. However within this constraint lower air flow now appears to be a technique that can reduce odorous ammonia emissions.

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Analysis of an Immobilized β-Galactosidase Reactor with Competitive Product Inhibition Kinetics (경쟁적 저해를 갖는 고정화 β-galactosidase 반응기의 해석)

  • Kang, Byung Chul
    • Journal of Life Science
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    • v.23 no.12
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    • pp.1471-1476
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    • 2013
  • The present study deals with the immobilization of Kluyveromyces lactis ${\beta}$-galactosidase on a weak ionic exchange resin (Duolite A568) as polymer support. ${\beta}$-Galactosidase was immobilized using the adsorption method. A kinetic study of the immobilized enzyme was performed in a packed-bed reactor. The adsorption of the enzyme followed a typical Freundlich adsorption isotherm. The adsorption parameters of k and n were 14.6 and 1.74, respectively. The initial rates method was used to characterize the kinetic parameters of the free and immobilized enzymes. The Michaelis-Menten constant ($K_m$) for the immobilized enzyme (120 mM) was higher than it was for the free enzyme (79 mM). The effect of competitive inhibition kinetics was studied by changing the concentration of galactose in a recycling packed-bed reactor. The kinetic model with competitive inhibition by galactose was best fitted to the experimental results with $V_m$, $K_m$, and $K_I$ values of 46.3 $mmolmin^{-1}mg^{-1}$, 120 mM, and 24.4 mM, respectively. In a continuous packed-bed reactor, increasing the flow rate of the lactose solution decreased the conversion efficiency of lactose at different input lactose concentrations. Continuous operation of 11 days was conducted to investigate the stability of a long-term operation. The retained activity of the immobilized enzymes was 63% and the half-life of the immobilized enzyme was found to be 15 days.

Synthesis of Structured Lipids from Corn Oil and Conjugated Linoleic Acid in the Continuous Type Reactor (연속식 반응기를 이용한 Conjugated Linoleic Acid 함유 재구성지질의 합성 연구)

  • 박래균;이기택
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.8
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    • pp.1200-1205
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    • 2003
  • Structured lipids (SL) were synthesized by transesterification of corn oil and conjugated linoleic acid (CLA) in the continuous type reactor using sn-1,3 specific Rhizomucor miehei lipase. The parameters of reaction were observed in terms of flow rate, temperature, and substrate molar ratios. The highest incorporation of CLA was obtained with 1 mL/min flow rate, 55$^{\circ}C$ and 1 : 3 (corn oil/CLA) molar ratio, showing 10.26 ㏖%. When different reaction temperatures and substrate ratios were studied, the highest incorporation was obtained at $65^{\circ}C$ (17.33 ㏖%) and 1 : 5 (corn oil/CLA) ratio (17.50 ㏖%), respectively. After pancreatic lipase analysis, most of all CLA were found at sn-1,3 position. The iodine values of obtained SLs ranged from 110 to 120. From the neutral lipid analysis by normal-phase HPLC, produced SLs composed of 99.35 ∼ 99.89% triacylglycerols, 0.11 ∼ 0.51% 1,2- and 1,3-diacylglycerols, and 0.06 ∼ 0.22% monoacylglycerols.

A Characteristics of Biogas Recovery and Biodegradability of Piggery Wastewater Using Granule of Two-Phase Anaerobic Process with UASB (UASB를 적용한 이상 혐기공정 granule에 의한 양돈폐수의 바이오가스 생성과 생분해 특성 평가)

  • Oh, SungMo;Bae, Yoon Sun;Park, Chul Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.315-322
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    • 2007
  • The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a granule of two-phase anaerobic process applied UASB. BMP test was conducted as simple means to monitor relative biodegradability of substrate and to determine methane production of an organic material. The two-phase anaerobic process is consisted of a continuous flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. A stable maximum biogas production rate was 400mL. The methane contents ranged from 73 to 80% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

A Study on the Reduction Process of VOCs Emission from Paint Booth - A Hybrid Process of Biotrickling Filter and Activated Sludge Reactor

  • Lim Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.41-48
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    • 2005
  • A novel hybrid system composed of a biotrickling filter and an activated sludge reactor was investigated under the conditions of four different SRTs (sludge retention times). The performance of the hybrid reactor was found to be directly comparable among the four different sludge ages. Discernible differences in the removal performance were observed among four different SRTs of 2, 4, 6, and 8 days. High removal efficiency was achieved by continuous circulation of activated sludge over the immobilized mixture culture, which allowed on pH control, addition of nutrients, and removal of paint VOCs (volatile organic compounds). The results also showed that the removal efficiency for a given pollutant depends on the activity of microorganisms based on the SRT. As the SRT increased gradually from 2 to 8 days, the average removal performance decreased. The highest removal rate was achieved at the SRT of 2 days at which the highest OUR (oxygen uptake rate), $6.1mg-O_2/liter-min$ was measured. Biological activity in the recycle microbes decreased to a much lower level, $3.6mg-O_2/liter-min$ at a SRT of 8 days. It is thus believed that young microorganisms were more active and more efficient for the VOCs removal of low concentrations and high flow rates. The apparent correlation of $R^2=0.996$ between the average removal efficiency and the average OUR at each SRTs suggests that VOCs degradation by young cells significantly affected the overall removal efficiency for the tested SRTs.

Ambient adsorption of $CO_2$ using an inorganic sorbent (무기흡착제를 이용한 $CO_2$의 상온흡착)

  • Jo, Young-Min;Lee, Ju-Yeol;Park, Young-Koo;Park, Joon-Seok;Kim, Seung-Ho;Ko, Jae-Churl
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.92-97
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    • 2007
  • The present paper deals with gaseous carbon dioxide separation by a commercial adsorbent: X-type zeolite. Experimental work was carried out at an ambient condition focusing on how well meeting to the national guideline. A few types of reactor and material were examined, and practical capability was found in a granular bed type reactor with the flow of 2.5 CMM. An optimum design of reactor and adsorbent could provide the required concentration, less than 2500 ppm, for the continuous operation up to 10 hours. More work including automatic regeneration is now underworking.

Development of Uranium-foil Fabrication Technology for Mo-99 Irradiation Target by Self Gravity Flowing for PFC Method (용탕자중공급 PFC법을 이용한 의료용 동위원소 Mo-99 조사타겟용 우라늄박판 제조공정개발)

  • Sim, Moon-Soo;Kim, Chang-Kyu;Kim, Ki-Hwan;Kim, Woo-Jung;Lee, Jong-Hyeon
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.288-292
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    • 2011
  • In order to complement the drawbacks of quartz crucible such as fragile-like break and melt-leakage through open slit nozzle, a new PFC system has been developed using a common graphite crucible and plugging system. The u melt is fed on to the rotating a roll through slit nozzle by self-gravity. The new equipment was designed and manufactured successfully. An effort for optimizing all related parameter has been made. Then using the optimized parameters about 10 meters u foil having very thin thickness, which meets the target thickness of 130 ${\mu}m$ and enough width more than 60 mm could be made. The thickness homogeneity set improved, due to the lower eddy flowing of the melt flow the self-gravity feeding system.

Antibacterial Effect of $TiO_2$ Photocatalytic Reactor against Food-borne Pathogens

  • Kim, Byung-Hoon;Cho, Dong-Lyun;Ohk, Seung-Ho;Ko, Yeong-Mu
    • Food Science and Biotechnology
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    • v.17 no.6
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    • pp.1345-1348
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    • 2008
  • Titanium dioxide ($TiO_2$) shows antibacterial effects when exposed to near ultra violet (UV) light. In this study, $TiO_2$ photocatalytic continuous reactor was designed and applied to food-borne pathogens such as Vibrio parahaemolyticus ATCC 17802, Salmonella choleraesuis ATCC 14028, and Listeria monocytogenes ATCC 15313. $TiO_2$ films were prepared by conventional sol-gel dip-coating method using titanium tetra iso-propoxide (TTIP). The antibacterial activity of photocatalytic reactor with various flow rates and UV-A illumination time showed effective bactericidal activity. As the UV-A illumination time increased, survival rates of those bacteria decreased. After 60 min of UV-A illumination, the survival rates of V. parahaemolyticus and S. choleraesuis were less than 0.1%. However, that of L. monocytogenes was about 5% at that time point. These results present an effective way to exclude pathogenic bacteria from aqueous foods.