• Title/Summary/Keyword: Contents of lignin

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Manufacture of Specialty Paper with Hemp Bast Fiber Cultivated in Korea (Part 1) - Characteristics of Hemp-Wood Paper by Soda Pulping - (삼섬유를 이용한 특수기능지 개발 (제 1보) - 소다펄프화 삼 섬유의 수초지 특성 -)

  • Lee, Dah-Hee;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.30-35
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    • 2013
  • To conserve wood resources for papermaking, chemical compositions of the hemp (Cannabis sativa L.) bast fiber cultivated in Korea such as holocellulose, ${\alpha}$-cellulose, lignin, alcohol-benzene extractives, hot and cold water extractives, and ash contents were investigated to manufacture the specialty packaging paper effectively. Significantly very low klason lignin content of 3.3% was accomplished by removing of the outer shell of bark. Laboratory soda pulping method which is very useful for the nonwood fiber was adapted, and it was found that there was no significant difference in both kappa number and H-factor between 25% and 30% NaOH charge. Hemp pulp cooked with the laboratory digester in 25% NaOH at $170^{\circ}C$ were mixed together with the wood pulp(NBKP:LBKP=1:1) in order to find the optimum mixture ratio which exhibited acceptable paper strength properties such as tensile index, burst index, and tear strength. When 10% of hemp soda pulps was mixed with 90% of wood pulps comprised of SwBKP and HwBKP (1:1), all physical strength increased significantly. The physical strength decreased as the amount of hemp pulp increased because the cell wall of bast fiber is very thick which causes low conformability and low fiber-fiber bonding. These results showed that paper made of hemp-wood pulp can be used for the specialty packaging paper which requires both the characteristic surface properties and the high physical strength of hemp fiber.

Studies on In-Situ Digestibility and Feed Value of Rice as Influenced by Ripening Stage (벼의 생육시기가 한우 반추위 소화율과 사료가치에 미치는 영향)

  • Lee, Sung Cheol
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.4
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    • pp.345-350
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    • 1998
  • In order to evaluate the feed value of rice straw as influenced by ripening stage, and to determine the effects of chemical treatments and ensiling on its feeding value, in situ studies using a rumen fistulated Korean cow nylon bag technique, and digestion trials with sheep were conducted. Experiments were conducted at the Experimental Farms, Woosuk University, Wanju in 1998. The results obtained are summarized as follows; 1. The contents of crude protein and crude fat were decreased(P<0.05), while those of crude fiber and crude ash were increased as the ripening of rice straw progressed. The content of NDF was not affected by the ripening stage. After the yellow stage hemicellulose was remarkably decreased while cellulose and lignin were increased. 2. Degradation of rice straw NDF in the rumen was most rapid when at the heading stage, but degradation of straws after the milky stage were similar each other. Degradation of rice straw ADF, on the other hand, did not show any difference with advancing ripening stage. In Conclusion, the change of chemical composition and degradation rate of rice straw in the rumen under the different ripening stage, it can be concluded that the lignification of rice straw was accelerated after the heading stage.

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Studies on Productivity and Nutrient Quality of Forage Rape (Brassica napus Subsp. oleifera) IV. Influence of sowing time on growth, yield and nutrient quality of forage rape. (사초용유채 ( Brassica napus Subsp. Oleifera ) 의 생산성과 사료가치에 관한 연구 IV. 파종기가 사초용 유채의 생육특성 , 수량 및 영양가치에 미치는 영향)

  • ;;Ichiro Goto
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.9 no.2
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    • pp.103-107
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    • 1989
  • To determine optimal sowing time of forage rape in southern areas of Korea, forage rape cv. Velox, the highest yielding variety among seventeen introduced varieties of forage rape, was grown under five different sowing times. The results obtained are summarized as follows: 1. Yield components such as plant length, number of branches and number of leaves etc. were highest at the sowing time of Sep. 14 and Sep. 24. 2. Plants sown at Sep. 14 and Sep. 24 also showed highest'fresh and dry matter yield. 3. As plants were grown under later sowing time, they showed higher values in content of crude protein and lower values in contents of crude fiber such as NDF, ADF, cellulose and lignin. 4. There was no relationship between variation of IVDMD and sowing time. Plants sown at Sep. 14 and Sep. 24 showed highest digestible dry matter yields.

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A Study on the Chemical Composition and Structure of Sludge, Compost and Charcoal (폐수처리 슬럿지와 퇴비 및 목탄의 화학적 특성과 구조에 관한 연구)

  • 임기표;위승곤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.27-32
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    • 2003
  • To understand the chemical structure of sewer sludge in comparison with commercial compost and charcoal used as a soil improver, it was carried out to analyse their ash contents and metal ions, and to elucidate the chemical structure of their residuals after a sequential treatment of alcohol-benzene(1:2) extraction in Soxhlet, 3% HCl reflux and 79% H₂SO₄ hydrolysis, using CHNS analyzer and solid C-13 NMR spectrometer. The results obtained were as follows: 1. Ash content of sludge was about 46% that is higher than those of compost (17%) and charcoal (4%). 2. The residual of sludge after a sequential treatment of HCl and H₂SO₄ hydrolyses had high ash content about 23%, too. 3. The sludge seems to be suitable to the soil improver because the content of heavy metal ions in sludge was near the compost and below the organic fertilizer standard. 4. Elemental composition of sludge residual after HCl-H₂SO₄ hydrolyes was C/sub 56/H/sub 91/O/sub 12/N₂S = (C/sub 6/H/sub 10/O/sub 5/)/sub 7/(C/sub 6/H₄)/sub 7/C₂H/sub 43/O₂N₂S, similar to C/sub 103/H/sub 122/O/sub 33/N/sub 6/S = (C/sub 6/H/sub 10/O/sub 5/)/sub 6/(C/sub 6/H₄)/sub 10/C/sub 7/H/sub 22/O₃N/sub 6/S of compost. 5. The sludge residual had proved to have both considerable aliphatic and aromatic groups, but the compost residual to have mainly aliphatic groups and the charcoal to have mainly aromatic groups, through the peak analysis of solid C-13 NMR charts. 6. So, the sewer sludge is proved to have a considerable amount of aromaticity like in woody biomass containing lignin.

Nitrogen level in tillage and no-tillage systems in Direct-seeded rice (경운과 무경운 조건에서 벼 건답휴립직파재배의 질소시비량)

  • 이석순;홍승범;백준호
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.2
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    • pp.160-165
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    • 1991
  • Growth performance of dry seeded paddy rice was studied at four N levels (10, 15, 20, and 25 kg/l0a) in tillage and no-tillage systems. Althougth the number of seedlings and maximum tillers tended to be higher and heading date was delayed by 2 days in tillage compared with those in no-tillage system, grainyield, yield components, lodging related characteristics, and N uptake were similar between two tillage ,systems. As N level increased, grain yield increased due to increased panicle number althougth the number of spikelets per panicle and percent ripended grains were similar and I, 000 grain weight decreased slightly. {Lodging index increased with increased N level due to higher plant height and decreased breaking strength and (culm base weigth, but lodging was not occurred in the field. Cellulose, hemicellulose, and lignin contents of culm base were similar among N levels. Concentration and uptake of N increased as N level increased.

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A Study on Pyrolytic and Anatomical Characteristics of Korean Softwood and Hardwood (국산 침·활엽수재의 열분해 및 해부학적 특성에 관한 연구)

  • Kim, Dae-Young;Kang, Sung-Ho;Jeong, Heon-young
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.31-42
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    • 2007
  • To investigate the pyrolytic and anatomical characteristics of Korean softwood, Pinus densi-flora, Pinus rigida and Larix leptolepis, and hardwood, Acer palntatum, Fraxinus rhynchophylla and Quercus variabilis, chemical components analysis, TG-DTA (Thermogravimetric Analysis & Differential Thermal Analysis), MBA (Methylene Blue Adsorption) test and SEM observation were carried out. For TG-DTA, samples were carbonized up to $800^{\circ}C$ at the heating rate of $10^{\circ}C$/min under $N_2$ flows 1 l/min using thermogravimetric analyzer. Chemical component analysis of all samples resulted in typical contents of major wood component. In TG-DTA results, softwood showed higher char yield than hardwood, and lignin displayed the highest char yield among the major wood components. All samples showed typical TGA, DTG and DTA curves for wood pyrolysis except a few differences between softwood and hardwood. Content of lignin influenced its pyrolysis characteristics, while molecular structure of lignin affected not only the weight loss but also the yield of char. In MBA test results, MBA of softwoods was higher than that of hardwoods. Char of Pinus densiflora showed the highest MBA, but its degree was lower than activated carbon or fine charcoal about 23 and 4 times, respectively. SEM observation showed carbonization process preserves wood structure and retain the micro-structure of wood fibers.

Pyrolysis of Waste Oriental Medicine Byproduct Obtained from the Decoction Process of Achyranthes Root (우슬(Achyranthes Root) 탕제 후 얻어진 폐한약재 부산물의 열분해)

  • Park, Ji Hui;Jeong, JaeHun;Lee, Ji Young;Kim, Young-Min;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.474-478
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    • 2018
  • Thermal decomposition of waste Achyranthes Root (WAR) emitted from its decoction process was investigated using a TG analyzer and a fixed-bed reactor. The WAR had the larger C and fixed carbon content than fresh AR (FAR) due to the extraction of hemicelluloses from FAR during decoction process. Thermogravimetric (TG) analysis results also revealed the elimination of hemicellulose by its decoction. Relatively high contents of the cellulose and lignin made high contents of their typical pyrolyzates, such as acids, ketones, furans, and phenols, in the pyrolysis of WAR using the fixed-bed reactor. The increase of pyrolysis temperature from 400 to $500^{\circ}C$ increased yields of oil and gas due to the more effective cracking efficiency of WAR at a higher temperature. The chemical composition of product oil was also changed by applying the higher pyrolysis temperature, which increased the selectivity to furans and phenols.

Effect of Nitrogen Fertilization and Stage of Maturity of Mottgrass (Pennisetum purpureum) on its Chemical Composition, Dry Matter Intake, Ruminal Characteristics and Digestibility in Buffalo Bulls

  • Sarwar, M.;Mahr-un-Nisa, Mahr-un-Nisa
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.7
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    • pp.1035-1039
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    • 1999
  • Four ruminally cannulated buffalo bulls were fed mottgrass diets using a $4{\times}4$ Latin square design. Treatments were arranged factorially and consisted of mottgrass fertilized with 0 for Kg nitrogen (N) per acre and harvested at 40 and 60 days of age. Nitrogen fertilization improved the concentrations of neutral detergent fiber (NDF), and acid detergent fiber (ADF) in early-cut mottgrass (ECM) but, the acid detergent lignin (ADL) contents were higher in the late-cut mottgrass (LCM). The crude protein (CP) contents of the mottgrass decreased with advancing maturity, but N fertilization increased CP at both maturities. The intake of dry matter (DM), organic matter (OM), CP, NDF and ADF were higher by buffalo bulls fed ECM than those fed LCM. The ruminal pH increased in first 6 hours post feeding in animals fed N fertilized mottgrass and may be due to higher concentration of ruminal ammonia. The digestibilities of DM, OM, CP, NDF and ADF were higher by buffalo bulls fed ECM than those fed LCM. However, the application of N fertilizer did not affect the digestibilities of these nutrients.

Estimation of Pasture Production and Nutritive Vallue in Relation to Plant Heigth of Orchardgrass (Dactylis glomerata L. ) (Orchargrass 우점초지에서 초장에 의한 생산량과 사료가치 추정)

  • Park, Moon-Soo;Seo, Sung;Kim, Ha-Jong
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.3
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    • pp.169-174
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    • 1991
  • For simple estimation of pasture production and nutritive value in relation to height of orchardgrass (Ductylis glomumtu L.), the experiment was carried out in a pasture mixture dominated by orchardgrass. The samples of grasses were harvested at the heights of about 30, 40, 50, 70 and 90 cm at the first harvest under different percentage of 100 (grass coverage): 0 (bareland), 80 : 20, 60 : 40, 40 : 60 and 20 : 80, respectively. As the height of orchardgrass was increased, fresh and dry matter (DM) yield were significantly increased. The regression equation between DM yield (Y) and height (X) was Y=ll. 5390 X- 146.60 (r=O. 9414 * * ). Also the higher bareland, the lower pasture production was observed. As the plant height at the first harvest was increased, the contents of crude (C) protein, C. fat, C. ash and relative feed value were markedly decreased. On the other hand, the contents of C. fiber, NFE, NDF. ADF, cellulose and lignin were significantly increased, respectively. The higher height, the lower DM digestibility was found. The equation between digestibility (Y) and height (X) was Y=- 0.2193 X+ 80.99 (r = - 0.9862**). Considering DM yield, digestibility and crude protein, the optimum height of orchardgrass at the first harvest was 59 to 67crn for better pasture production and nutritive value.

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Assessment of the Nutritive Value of Whole Corn Stover and Its Morphological Fractions

  • Li, H.Y.;Xu, L.;Liu, W.J.;Fang, M.Q.;Wang, N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.2
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    • pp.194-200
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    • 2014
  • This study investigated the chemical composition and ruminal degradability of corn stover in three maize-planting regions in Qiqihaer, Heilongjiang Province, China. The whole stover was separated into seven morphological fractions, i.e., leaf blade, leaf sheath, stem rind, stem pith, stem node, ear husk, and corn tassel. The assessment of nutritive value of corn stover and its fractions was performed based on laboratory assays of the morphological proportions, chemical composition, and in situ degradability of dry matter (DM), neutral detergent fiber (NDF), and acid detergent fiber (ADF). The chemical composition of corn stover was significantly different from plant top to bottom (p<0.05). Among the whole corn stover and seven morphological fractions, leaf blade had the highest crude protein (CP) content and the lowest NDF and ADF contents (p<0.05), whereas stem rind had the lowest CP content and the highest ADF and acid detergent lignin (ADL) contents (p<0.05). Ear husk had significantly higher NDF content and relatively lower ADL content than other corn stover fractions. Overall, the effective degradability of DM, NDF, and ADF in rumen was the highest in leaf blade and stem pith, followed by ear husk. The results indicate that leaf blade, ear husk, and stem pith potentially have higher nutritive values than the other fractions of corn stover. This study provides reference data for high-efficiency use of corn stover in feeding ruminants.