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Study of Simultaneous Analysis of Indicator Components of DTP(Digital Textile Printing) Textile Products Using HPLC-MS/MS - Focusing on Natural Dyes - (HPLC-MS/MS를 활용한 DTP(Digital Textile Printing) 제품의 지표성분 동시분석법 연구 - 천연염료를 중심으로 -)

  • Lee, Wonkyoung;Sung, Eunji;Moon, Joung Ryul;Kim, Miji;Kim, Jonghoon
    • Fashion & Textile Research Journal
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    • v.23 no.6
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    • pp.844-851
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    • 2021
  • Due to the increase in consumers' interest about well-being, interest in eco-friendly products has been increasing due to the harmful effects of various harmful substances contained in textile products and environmental issues. As a result, natural dyes of less potential risk than synthetic dyes and digital textile printing(DTP) textile products with less environmental pollution are drawing attention. However, due to the lack of evaluation criteria for DTP textile products with natural ink and the nature of many colors are stacked layer by layer for dying, the need for simultaneous analysis is emerging. To evaluate whether the natural dye is derived from natural ingredients, the biocarbon content is analyzed. However, in the case of ink made using natural dyes and DTP textile products using natural ink, it is difficult to analyze the biocarbon content due to the limitation of the presence of a small amount of dye contained therein. In this study, we were shown the possibility of natural derived verification by cross-checking the analytes of natural dyes (Persicaria tinctoria, an indigo dye; Dactylopius coccus, a light red; and Curcum longa L., i.e., turmeric) and natural ink with HPLC-MS/MS. The coefficient of determination was 0.999 or higher, the limit of quantification was 0.647-3.664 ㎍/L and a %RSD of each indicator material was less than 10. Then, the extraction amount of natural dyes for five patterned fabrics was analyzed.

A comparative study on enhanced anti-inflammatory activity of Cannabis root extract prepared by combined processing process (복합가공 과정에 의한 대마 뿌리 추출물의 항염증 활성 증진에 관한 비교 연구)

  • Ga-Ram Yu;Hye-Lin Jin;Da-Hoon Kim;Jay Kyun Noah;Hyuck Kim;Dong-Woo Lim
    • The Journal of Korean Medicine
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    • v.45 no.2
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    • pp.41-54
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    • 2024
  • Objectives: Cannabis root is a medicinal plant that has been used in traditional medicine around the world. However, in previous studies using simple extracts, the biological activity was not relatively prominent compared to other herbal medicines. The aim of the present study is to confirm the enhancement of anti-inflammatory activity and bioactive compound of Cannabis root extract prepared by combined processing process. Methods: A series of processes including repeated steam and dry, fermentation, hydrothermal extraction and ethanol extraction was applied to Cannabis root. The antioxidant content of cannabis root extracts obtained through a combined processing process was investigated by analyzing the total phenolic, tannin, and flavonoid contents. Anti-inflammatory effects were tested in LPS-treated RAW264.7 cells. The anti-inflammatory mechanism was examined by western blot. Finally, the component profile of Cannabis root extract was analyzed using High Performance Liquid Chromatography (HPLC) and Thin layer chromatography (TLC). Results: The cannabis root extract prepared by complex processing process had higher antioxidant and anti-inflammatory effects than simple extract. Total phenolic and tannin contents were significantly increased, and DPPH free radical inhibition activity was strengthened by combined processing process. Increased NO production and iNOS expression in LPS-treated RAW264.7 cells were decreased in a concentration-dependent manner upon extract treatment by complex processing process. Additionally, the Stigmasterol content of Cannabis root extract was increased through a complex processing process. Conclusions: Further research is needed on the mechanisms and substances that exhibit the anti-inflammatory effects of Cannabis roots extract prepared by complex processing process.

Characteristic Changes of Swine Manure by Air Suction Composting System (돈분 퇴비화 시 공기 흡입 시스템에 따른 퇴비화 특성 변화)

  • Lee, Dong-jun;Kim, Jung Kon;Jeong, Kwang-Hwa;Cho, Won-Mo;Ravindran, B.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.3
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    • pp.63-74
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    • 2016
  • The objective of this study was to investigate the variations of physico-chemical properties during the swine manure composting, sawdust as the bulking agent was composted at different points (Top layer, Side of middle layer, Bottom layer). Air suction system with constant bottom aeration in bench scale reactors (30 L). The highest temperature was reached in the range of $58^{\circ}C$ to $62^{\circ}C$ on $3^{rd}$ day and this thermophilic phase (> $50^{\circ}C$) was continued for 3 days in all the treatment mixtures. However, the temperature was gradually decreased to room temperature at the end of 60 day composting process. Except control, the discharged ammonia ($NH_3$) was a maximum in the treatment order of Top layer>Bottom layer>Side of middle layer as 500 ppm, 162 ppm and 120 ppm, respectively, on the $4^{th}$ day and showing that Top layer point Air suction produce much more ammonia content than the other point. During the composting process, the total Kjeldahl nitrogen (TKN) was gradually increased due to the mass loss in the composting mixtures. At the same time, C/N ratio was decreased to Top layer, 13; Side of middle layer, 12 and Bottom layer, 13 at Air suction points. The significant reduction of C/N ratio in all different air suction system when manure was matured. The $NH_4-N$ to $NO_3-N$ ratio was recorded as 10.52 at the initial stage of the compost mixtures and reduced to 0.97 (Top layer), 0.70 (Side of middle layer), 3.2 (Bottom layer) because of manure decomposition. The overall results revealed that Top layer and Side of middle layer Air suction is a suitable option when compared other point for high quality composts.

Investigation on the Characteristics of Vertical Composting System Using Layer Manure (수직 종형퇴비화시설에서의 산란계분 퇴비화 특성 조사 연구)

  • Kwag, J.H.;Kim, J.H.;Cho, S.H.;Jeong, K.H.;Choi, D.Y.;Jeong, Y.S.;Jeong, M.S.;Kang, H.S.;Ra, C.S.
    • Journal of Animal Environmental Science
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    • v.16 no.3
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    • pp.237-244
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    • 2010
  • Using a vertical composting system in layer farms, the composting process was characterized in terms of temperature variation, change of moisture contents, fertilizer ingredient and so on. In this study, two types of layer farms were examined. The layer manure was produced as 3,300 and 116,650 kg/day for Farm A and Farm B, respectively. Also, their average moisture contents were 74.4% (Farm A) and 65.6 % (Farm B). The inside temperature of composting in Farm A was varied in the range of 50 to $70^{\circ}C$, and moisture content of it decreased from 59.5% to 20.6% at the edge of vertical composting system. While in Farm B, composting temperature was fluctuated between 50 and $65^{\circ}C$ and moisture content declined from 34.0% to 13.4% at the end of vertical composting system. The fertilizer ingredients such as T-N, $P_2O_5$ and $K_2O$ were not significantly influenced by seasonal effect. Their values were changed in the range of 0.90% to 0.47% for T-N, 0.16% to 0.42% for $P_2O_5$, and 0.22% to 0.28 for $K_2O$, respectively. Also, OM/N ratio was varied from 36.8 to 84.4.

Thin Layer Drying and Quality Characteristics of Ainsliaea acerifolia Sch. Bip. Using Far Infrared Radiation (원적외선을 이용한 단풍취의 박층 건조 및 품질 특성)

  • Ning, Xiao Feng;Li, He;Kang, Tae Hwan;Lee, Jun Soo;Lee, Jeong Hyun;Ha, Chung Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.6
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    • pp.884-892
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    • 2014
  • The purpose of this study was to investigate the drying characteristics and drying models of Ainsliaea acerifolia Sch. Bip. using far-infrared thin layer drying. Far-infrared thin layer drying test on Ainsliaea acerifolia Sch. Bip. was conducted at two air velocities of 0.6 and 0.8 m/sec, as well as three drying temperatures of 40, 45, and $50^{\circ}C$ respectively. The drying models were estimated using coefficient of determination and root mean square error. Drying characteristics were analyzed based on factors such as drying rate, leaf color changes, antioxidant activity, and contents of polyphenolics and flavonoids. The results revealed that increases in drying temperature and air velocity caused a reduction in drying time. The Thompson model was considered suitable for thin layer drying using far-infrared radiation for Ainsliaea accerifolia Sch. Bip. Greenness and yellowness values decreased and lightness values increased after far-infrared thin layer drying, and the color difference (${\Delta}E$) values at $40^{\circ}C$ were higher than those at $45^{\circ}C$ and $50^{\circ}C$. The antioxidant properties of Ainsliaea acerifolia Sch. Bip. decreased under all far-infrared thin layer drying conditions, and the highest polyphenolic content (37.9 mg/g), flavonoid content (22.7 mg/g), DPPH radical scavenging activity (32.5), and ABTS radical scavenging activity (31.1) were observed at a drying temperature of $40^{\circ}C$ with an air velocity of 0.8 m/sec.

Analysis on the Rainfall Triggered Slope Failure with a Variation of Soil Layer Thickness: Flume Tests (강우로 인한 조립토 사면에서의 토층 두께 변화에 따른 사면의 활동 분석: 실내 모형실험)

  • SaGong, Myung;Yoo, Jea-Ho;Lee, Sung-Jin
    • Journal of the Korean Geotechnical Society
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    • v.25 no.4
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    • pp.91-103
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    • 2009
  • Slope failure depends upon the climatic features related to related rainfall, structural geology and geomorphological features as well as the variation of the mechanical behaviors of soil constituting a slope. In this paper, among many variables, effects of soil layer thickness on the slope failure process, and variations of matric suction and volumetric water content were observed. When the soil layer is relatively thick, the descending wetting front decreases matric suction and the observed matric suction reaches to "0" value. When the wetting front reaches to the impermeable boundary, the bottom surface of steel soil box, ascending wetting front was observed. This observation can be postulated to be the effects of various sizes of pores. When macro size pores exist, the capillary effects can be reduced and infilling of pore will be limited. The partially filled pores would be filled with water during the ascending of the wetting front, which bounces from the impermeable boundary. This assumption has been assured from the observation of variation of the volumetric water contents at different depth. When the soil layer is thick (thickness = 20 cm), for granular material, erosion is a cause triggering the slope failure. It has been found that the initiation of erosion occurs when the top soil is fully saturated. Meanwhile, when the soil layer is shallow (thickness = 10 cm), slope slides as en mass. The slope failure for this condition occurs when the wetting front reaches to the interface between the soil layer and steel soil box. As the wetting front approaches to the bottom of soil layer, reduction of shear resistance along the boundary and increase of the unit weight due to the infiltration occur and these produce complex effects on the slope failure processes.

Mineralogical Studies on Luster of Seawater Cultured Pearls, Tongyeong, Korea (경남 통영 해수양식진주의 광택에 대한 광물학적 연구)

  • Cho, Hyen Goo;Kim, Soon-Oh;Do, Jin Young
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.1
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    • pp.9-16
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    • 2015
  • A mineralogical analysis on the factors affecting the luster of pearls was carried out using gravity measurement, optical microscope observation, X-ray diffraction analysis, and scanning electron microscopy. We divided the seawater cultured pearls from Tongyeong into the following four types based on luster and shape; good luster and round (LR), lackluster and round (LLR), lackluster and baroque (LLB), and lackluster and two nucleus (LTN) pearls. Pearls with high-quality luster had slightly lower specific gravity as compared to pearls with low-quality luster, but both these types of pearls are within the specific gravity range of commercial pearls. Regarding the cross-sectional thickness of the mother-of-pearl layer, LR pearls showed a uniform thickness of about 0.3 mm in average. On the other hand, LLR pearls were characterized by relatively thinner, but uniform thickness. LTN and LLB pearls showed a tendency of significantly large variation in thickness even within a single pearl. For the surface of pearls, pearls with high-quality luster showed narrower and clearer growth lines of aragonite crystals as compared to pearls with low-quality luster. Pearls with high-quality luster were characterized by fewer aragonite crystal lattice defects as compared to pearls with low-quality luster, and the former showed parallel arrangement, thinner thickness, and less difference in thickness on the surface and inside. If a pearl has a prismatic layer, it is composed of aragonite with calcite in the prismatic and nacreous layer, and calcite content is very high in the lackluster pearl. Pearls without a prismatic layer were devoid of calcite irrespective of their quality of luster, and were composed of aragonite.

A Study on external and internal morphology and pattern analysis in 4 kinds of Mok-Hyaeng Radix (4종류 목향류(木香類)의 외부(外部) 및 내부형태(內部形態)와 이화학패턴연구)

  • Kim, Hong-Jun;Kang, Kyoung-Sik;Choi, Go-Ya;Kim, Ho-Kyung;Jeong, Seung-Il;Ju, Young-Sung
    • Korean Journal of Oriental Medicine
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    • v.12 no.3 s.18
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    • pp.117-130
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    • 2006
  • The purpose of this study was to introduce the differential standard of Mok-Hyaeng Radix species. We established the classificatory standard according to the external and internal morphology and the pattern in 4 kinds of Mok-Hyaeng Radix. The results follow: 1. On the external morphology, Radix of Vladimiria souliei had a sticky material in the head of roots and it was yellowish white in the cut surface. It attached to teeth during chewing. Radix of Aucklandia lappa (=Saussurea lappa) was dark grayish brown and was grayish brown in the cut surface. It had special odor and was not attache to teeth chewing it. On the other hand, Radix of Inula helenium was dark brown. In the cut surface, cortical layer was different from wood layer. Radix of Aristolochia contorta was yellowish brown. In the cut surface, it was not smooth and cortical layer was different from wood layer. 2. On the internal morphology, Radix of Vladimiria souliei had many fascicular fibers and scattered large oil chambers in the bast ray, xylem ray, and parenchyma. On Radix of Aucklandia lappa (=Saussurea lappa), it was difficult to find out the trace when the cork layer was exfoliated. The cambium formed circle and the large oil chambers were scattered in the phloem and xylem. On the other hand, external cortical layer of Radix of Inula helenium was detached and cambium was formed to indistinct circle and large oil chambers were scattered in the phloem and xylem. On Radix of Arustolochia contorta, the large oil chambers were scattered in the surface later, bast part was relatively broad and cambium formed circle. 3. On the TLC pattern, Radix of Aristolochia contorta, Inula helenium, Aucklandia lappa, and Vladimiria souliei were chromogenic to violet and purple according to sulfuric acid colour pattern, especially faint on Aristolochia contorta. 4. On the pattern analysis of HPLC, we compared the content and the pattern of constunolide and dehydrocostus lactone, Radix of Aucklandia lappa was similar to Radix of Vladimiria souliei and Radix of Aristolochia contorta was similar to Radix of Inula helenium. On the total HPLC component pattern, constunolide and dehydrocostus lactone were similar in all four types, but it showed the Rf 5-6 peak was only in Radix of Aristolochia contorta, not in Radix of Inula helenium, Aucklandia lappa, and Vladimiria souliei. It is considered the results of this study will be furnished the basis to succeeding studies and it is needed to extensive comparative study for the same genus-degree of relatedness.

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Two Dimensional Shear Wave Velocity Using the Inversion of Surface Waves (표면파 역산을 이용한 2차원 S파 속도구조에 관한 연구)

  • Jung, Hee-Ok
    • Journal of the Korean earth science society
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    • v.21 no.6
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    • pp.675-682
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    • 2000
  • 25 seismic shot gathers were obtained to study the two dimensional subsurface shear wave velocities in a landfilled area near the Keum river estuary. Borehole(BH#1 and BH#2) tests at two sites were made in the same area. Standard Penetration Tests were also performed at the same time. The 2-D shear wave velocity structure resulted from the inversion of the seismic data shows that the subsurface of the studied area consists of the upper 1${\sim}$3 meter thick layer(200 m/sec${\sim}$700 m/sec), the middle 5${\sim}$8 m thick low velocity layer(100 m/sec${\sim}$400 m/sec), and the lower layer of 1000m/sec or higher shear wave velocities. The thickness of the low velocity layer decreases from the BH #1 site to the BH #2 site. The depth to the basement also decreases toward the BH #2 site. The examination of the S wave velocity structure, the description of the geologic contents, and the Standard Penetration Test values indicate that the middle layer of low shear wave velocity may be related to the clay content of the layer. On the other hand, the Standard Penetration test values increase with depth, showing no significant relationship with the geologic contents of the subsurface. This study shows that the inversion of surface waves can be effective in the study of the shear wave velocity, especially in the area where low velocity layers can be found. The method of inversion of surface waves also can be used as a viable technique to overcome the limit of the seismic refraction method.

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Late Pleistocene Unconformity in Tidal-Flat Deposit of Gyeonggi Bay, Western Coast of Korea (한국 서해 경기만 조간대 퇴적층의 후기 플라이스토세 부정합)

  • Jung, Hoi-Soo;Yoo, Hai-Soo;Seo, Jung-Mo;Paeng, Woo-Hyun;Lim, Dhong-Il
    • Journal of the Korean earth science society
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    • v.24 no.8
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    • pp.657-667
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    • 2003
  • Deep-drilled core sampling and high-resolution seismic survey were carried out to identify a Holocene-late Pleistocene boundary in Gyeonggi Bay, western coast of Korea. Analysis of core sections revealed the existence of an oxidized and semi-consolidated sediment layer, Iying immediately below a Holocene horizon (Unit I) and being developed at the top of a late Pleistocene deposit (Unit II). The oxidized sedimentary layer (uppermost part of Unit II) is characterized by semi-consolidated, yellowish sediments showing signs of desiccation and alteration such as high N value, low water content, periglacial cryogenic structure, depletion of smectite, and high geochemical weathering index (Ba/Sr ratio). This feature, together with radiocarbon ages, suggests that the layer has formed as a result of prolonged subaerial exposure of Unit II sediments during the late Wisconsin sea-level lowstand, producing a regional unconformity. Such unconformitic-bounding surface corresponds to a prominent near-surface reflector (R), which is observed in seismic profiles obtained across the drilled-core sections in the study area. Consequently, the buried oxidized-sedimentary layer associated with the seismic reflector possibly plays a key horizon for the understanding of late Quaternary environmental changes as well as evidence of the emergence of the Yellow Sea shelf during the late Wisconsin sea-level lowstand.