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Chemical Vapor Deposition of Ga2O3 Thin Films on Si Substrates

  • Kim, Doo-Hyun;Yoo, Seung-Ho;Chung, Taek-Mo;An, Ki-Seok;Yoo, Hee-Soo;Kim, Yun-Soo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.225-228
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    • 2002
  • Amorphous $Ga_2O_3$ films have been grown on Si(100) substrates by metal organic chemical vapor deposition (MOCVD) using gallium isopropoxide, $Ga(O^iPr)_3$, as single precursor. Deposition was carried out in the substrate temperature range 400-800 $^{\circ}C$. X-ray photoelectron spectroscopy (XPS) analysis revealed deposition of stoichiometric $Ga_2O_3$ thin films at 500-600 $^{\circ}C$. XPS depth profiling by $Ar^+$ ion sputtering indicated that carbon contamination exists mostly in the surface region with less than 3.5% content in the film. Microscopic images of the films by scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed formation of grains of approximately 20-40 nm in size on the film surfaces. The root-mean-square surface roughness from an AFM image was ${\sim}10{\AA}$. The interfacial layer of the $Ga_2O_3$/Si was measured to be ${\sim}35{\AA}$ thick by cross-sectional transmission electron microscopy (TEM). From the analysis of gaseous products of the CVD reaction by gas chromatography-mass spectrometry (GC-MS), an effort was made to explain the CVD mechanism.

Anthocyanin Synthesis in Cell Cultures of Populus alba L. × P. glandulosa Uyeki (세포배양(細胞培養)을 이용(利用)한 현사시나무의 안토시아닌 생성(生成))

  • Park, Young Goo;Choi, Myung Suk;Son, Sung Ho
    • Journal of Korean Society of Forest Science
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    • v.81 no.2
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    • pp.183-190
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    • 1992
  • The influence of various levels of major medium components such as sucrose, nitrate, phosphate, plant growth regulators, and light intensity for cell growth and the production of anthocyanin content in cell cultures of Populus alba ${\times}$ P. glandulosa were investigated. Best results for anthocyanin yield were obtained using Murashige and Skoog(MS) medium containing 5% sucrose, 12.5% nitrate, 200% phosphate, 1.0mg/l indole-3-acetic acid(IAA), 1.0mg/l benaylaminopurine(BAP), and continuous illumination of 7,000 lux. On the other hand, maximum cell growth was achieved with 5% sucrose, 50% nitrate above 400% phosphate compare with that of MS basal mediumi, and 0.5mg/l 2, 4-dichlorophenoxyacetic acid(2, 4-D). Anthocyanin accumulation in a suspension cultured cells of given genotype was stimulated by subculturing onto the medium lacking 2, 4-D. Pigmented cell clusters were extracted with methanol containing 1% hydrochloric acid (HCl) and then anthocyanin was identified by thin layer chromatography (TLC) and U. V. spectrophotometer.

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Analysis about Fill Deposit Poor Drainage through Permeability Test and Groundwater Monitoring (투수시험과 지하수 모니터링을 통한 매립층의 배수불량 원인 분석)

  • Jung, Hee-Suk;Lee, Kang-Il;Kim, Joon-Seok
    • Journal of the Society of Disaster Information
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    • v.14 no.2
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    • pp.165-173
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    • 2018
  • Purpose: The area such as historic sites where distributed in the hills surrounded by the mountains in the past, if heavy rains occur, soil that distributed in the substructure of a sedimentary layer's permeability decreases therefore, water do not smoothly drainage and increases surface structures' moisture content. Therefore, many phenomena occur such as the muddy ground. This experiment tried to figure out the cause of poor drainage, predicting poor drainage system when rainfall occur. So not only the base of cultural properties distributed in the historic site, but also have big influences on the upper structure. Method: We are going to propose an improvement plan through the various sites exploration and the field permeability test. In addition, analyze interrelationship to figure out the cause of the poor drainage through monitoring under ground water. Conclusion: As the result of the experiment, the cause of the poor drainage system formed on shallow depth of ground level inside of a land. We can see that soil of surface and fill deposit permeability was in poor condition. Therefore, it was in very inappropriate hydrogeological condition when surface water permeate into the underground when rainfall occurs.

High Temperature Gas Nitriding of Austenitic Stainless Steels (오스테나이트계 스테인리스강의 고온질화)

  • Kong, J.H.;Yoo, D.K.;Park, J.H.;Lee, H.W.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.6
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    • pp.311-317
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    • 2007
  • This study examined the phase changes, nitride precipitation and variation in mechanical properties of STS 304, STS 321 and STS 316L austenitic stainless steels after high temperature gas nitriding (HTGN) at temperature ranges from $1050^{\circ}C\;to\;1150^{\circ}C$. Fine round type of $Cr_2N$ nitrides were observed in the surface layers of 304 and 316L steels, even more in STS 321. Additionally, square type of TiN was found in STS 321 austenitic matrix too. As a result of many precipitates in the surface layer of the STS 321, it was seen $370{\sim}470Hv$ hardness variation depending on the HTGN treatment conditions, and interior region of austenite represented 150Hv. The surface hardness value of STS 304 and STS 316L showed $255{\sim}320Hv$, respectively. The nitrogen content was shown 0.27, 1.7 and 0.4% respectively at the surface layers of the STS 304, STS 321 and STS 316L. After the HTGN it was shown the improvement of corrosion resistance of the STS 321 and STS 316L compared with solution annealed steels in the solution of 1N $H_2SO_4$ whereas the STS 304 was not.

Low Temperature Drying Simulation of Rough Rice (벼의 저온건조 시뮬레이션)

  • Kim, Hoon;Han, Jae-Woong
    • Journal of Biosystems Engineering
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    • v.34 no.5
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    • pp.351-357
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    • 2009
  • This study was conducted to verify the simulation model through the drying test, and investigate effect of factors, such as temperature of drying air, airflow rate, and velocity of the airflow, on the drying. The low temperature drying simulation model was developed based on the circulation dry simulation model presented by Keum et al. (1987), and by modifying low temperature thin layer drying model, equilibrium moisture content model, latent heat of vaporization model, and crack ratio prediction model. The heat pump and experimental dryer with a capacity of 150kg were used for the test. The RMSE between the predicted and measured value was 0.27% (drying temperature), 0.15% (crack ratio), and 2.08% (relative humidity), so the relevance of the model was verified. In addition, the effect of drying temperature, airflow rate, and velocity of the airflow on the drying was examined. The experimental results showed that the crack ratio at drying temperature of $25{\sim}40^{\circ}C$ was allowable. Moreover, at below $30^{\circ}C$, variation of the crack ratio was slight, but drying time was delayed. Given these results, the drying temperature of over $30^{\circ}C$ was effective. As the airflow rate increased, required energy dramatically increased. Whereas drying rate slowly increased, so loss of drying efficiency was caused. Considering these results, the dryer needed to be designed and adjusted to lower than $30\;m^3/min{\cdot}ton$. As velocity of the airflow increased, required drying energy increased when the velocity of the airflow was over $5\;m^3$/hr, while crack ratio and drying rate showed little variation.

Intercomparison of the Global Ocean Reanalysis Data (전지구 해양 재분석 자료 비교 분석)

  • Chang, You-Soon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.2
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    • pp.102-118
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    • 2015
  • This study summarized the results of the international ocean reanalysis intercomparison project. We introduced the characteristics of various ocean reanalysis systems and analyzed the assimilated performance on the typical eight oceanic variables (heat content, steric height, sea level, surface heat fluxes, mixed layer depth, subsurface salinity, depth of $20^{\circ}C$ isotherm, sea ice). In general, ensemble means show better estimations than those of any individual ocean reanalysis, but it depends on analyzed regions and variables. Among the eight oceanic variables, salinity and sea ice variabilities have large spreads among models. The deep sea, Southern Ocean, and coastal regions including western boundary current commonly appear as the areas with largest uncertainty between different objective analyses and assimilation models. We expect that intercomparison project for the ocean assimilation models independently operated in Korea should be processed, which allows us to join relevant international programs in the near future.

Natural Ripening versus Artificial Enhancing of Silty Reclaimed Tidal Soils for Upland Cropping Tested by Profile Characterization

  • Ibrahim, Muhammad;Han, Kyung-Hwa;Lee, Kyung-Do;Youn, Kwan-Hee;Ha, Sang-Keun;Zhang, Yong-Seon;Hur, Seung-Oh;Yoon, Sung-Won;Cho, Hee-Rae
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.9-15
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    • 2012
  • This study was performed to produce basic data for silty reclaimed tidal lands and to develop techniques of environmentally-friendly utilization in agricultural system. We chose the two sites in Saemangeum reclaimed tidal lands, one (Site I) has been treated with cultivating green manure and conducting the desalinization process through submergence since April, 2007 and the other (Site II) has been under natural condition without artificial treatment. In situ and ex situ physic-chemical properties were determined and comparisons were made for soil profiles examined at these two sites in April 2009. Surface soil of Site I had lower EC and higher field saturated hydraulic conductivity than those of Site II, uncultivated land. Especially, exchangeable sodium content was lowest in Site I Ap1 layer than in other layers. This is probably due to flooding desalination and green manure cultivation. Besides, Ap1 and A2 layers of soil profile in Site I showed brighter soil color and more root observation than those of Site II. This is probably due to green manure cultivation. By the large, for high cash upland crops and intensive agricultural use of silty reclaimed tidal land, site-specific soil ripening such as flooding desalination and green manure cultivation could be useful.

Behavior of Vibration Fracture for Sn-Ag-Cu-X Solders by Soldering (Sn-Ag-Cu-X 무연솔더로 솔더링 된 접합부의 진동파괴 거동)

  • Jin, Sang-Hun;Kang, Nam-Hyun;Cho, Kyung-Mox;Lee, Chang-Woo;Hong, Won-Sik
    • Journal of Welding and Joining
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    • v.30 no.2
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    • pp.65-69
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    • 2012
  • Environmental and health concerns over the lead have led to investigation of the alternative Pb-free solders to replace commonly used Pb-Sn solders in microelectronic packaging application. The leading candidates for lead-free solder alloys are presently the near eutectic Sn-Ag-Cu alloys. Therefore, extensive studies on reliability related with the composition have been reported. However, the insufficient drop property of the near eutectic Sn-Ag-Cu alloys has demanded solder compositions of low Ag content. In addition, the solder interconnections in automobile applications like a smart box require significantly improved vibration resistance. Therefore, this study investigated the effect of alloying elements (Ag, Bi, In) on the vibration fatigue strength. The vibration fatigue was conducted in 10~1000Hz frequency and 20Grms. The interface of the as-soldered cross section close to the Cu pad indicated the intermetallic compound ($Cu_6Sn_5$) regardless of solder composition. The type and thickness of IMC was not significantly changed after the vibration test. It indicates that no thermal activities occurred significantly during vibration. Furthermore, as a function of alloying composition, the vibration crack path was investigated with a focus on the IMCs. Vibration crack was initiated from the fillet surface of the heel for QFP parts and from the plating layer of chip parts. Regardless of the solder composition, the crack during a vibration test was propagated as same as that during a thermal fatigue test.

The Influence on the Runoff Charateristics by the Land Use in Small Watersheds (II) (소유역의 토지이용이 유출특성에 미치는 영향 (II))

  • Choi, Ye-Hwan;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.178-182
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    • 2005
  • In the forthcoming 21C, the development of cultural lives depends on that the water demand will increase or not. On the opposite site of that circumstance, many factors of the small watersheds will influence directly on how to cover the surface of watersheds with land use, no planning developing watersheds, and the rearrangement of small rivers. Especially as the extraordinary climatic Phenomena, exhaust of $CO_2$ and destruction of 03 layer, water resource and water foresting content of the small watersheds will be decreased by confusing on the malting a plan of water resources. For example, those are Typhoon Rusa in 2002, Typhoon Maemi in 2003 and heavy storms in 2004. This study area has three group and one of them having three small watersheds, total five small watersheds. That is, Sabukmyeon small watersheds in Chuncheon, Three small watersheds in Wonju(Jeoncheon, Jupocheon and Hasunamcheon), and Suipcheon in Yanggu-Gun which are located far away each other three group and different precipitation data. According to the land use such as dry field(or farm), rice field, forest land. building site and others in small watersheds, the amount of runoff will be impacted by monthly precipitation. The comparison between the runoff was getting from Kajiyama Formula and calculated runoff from multi-linear regressed equations by land use Percentage was performed with different precipitation data and different small watersheds. Its correlations which are estimated by coefficient of correlation will be accepted or not, as approached 1.0000 values. As the monthly water resources amount is estimated by multi-linear regressed equations with different precipitation data and different small watersheds having no gauging station, we make a plan in order to demand and supply the water quantity from small river watersheds during return periods.

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Groundwater Investigation in Northwestern Part of Saudi Arabia (Saudi Arabia 북서부의 지하수조사)

  • 한정상;정수웅
    • Water for future
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    • v.8 no.2
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    • pp.30-40
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    • 1975
  • Hydrogeological survey and geophysical prospecting have been carried out in Saudi Arabia for the purpose of finding groundwater in the soil and rock at the request of General trading company in Jeddah, Saudi Arabia. The surveyed area is located on $38^{\circ}-39^{\circ}$ 30' in longitude and $26^{\circ}-26^{\circ}$ 30' in latitude. The topography of this area is dominated by northwest southeast mountain range composed mostly of precambrian rocks and basalt of tertiary period. Geology is mainly composed of greenstone, granite, andesite, diorite rhyolite of pre-cambrian era and sandstone of cambrian period which are underlained by basalt and andesite of tertiary period and alluvium of quaternary unconformably. The instruments used in this investigation are TR-18B2 radioactivity unit which isjapanese patented and A.C. Terrameter, a resistivity meter manufactured by ABEM of Stockholm, Sweden. Radioactivity method has been conducted along the Alula-Khaybar road, totally 164Km by the car-borne. As a result of the above survey 16 places have been selected and these anomalies show 1.2N-1.6N compared to background of each area in intensity with width of 10-50m. Resistivity vertical profiling which made use of Schlumberger configuration method has been made over selected areas by radioactivity method to provide hydrogeological information for a water resources survey. The result of resistivity shows that good aquifers are located in the western part of surveyed area where sedimentary rock is distributed. The strata showing 10-50, ${\Omega}-m$ in resistivity are thought to be waterbearing layer. The variations in aquifer resistivity found, are thought to be due to verying clay content, which could be related to aquifer yield. It has proved impossible to detect small salinity variation in the buried aquifer by geophysics. As a result of resistivity prospecting 10 places are recommended to be drilled at the anomalies as shown attached map. yields from the proposed holes have been estimated approximately from $20m^3$ to $200m^3$ per day. Prior to drilling for groundwater, test boring using ${\c}4"$ should be drilled in order to obtain more reliable hydrogeological information for the construction of perfect wells.ells.

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