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Stabilizing Properties of SiOF Film with Low Dielectric Constant by $N_2O$ Plasma Annealing ($N_2O$ 플라즈마 열처리에 의한 저유전율 SiOF 박막의 물성 안정화)

  • Kim, Yoon-Hae;Lee, Seok-Kiu;Kim, Sun-Oo;Kim, Hyeong-Joon
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.317-322
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    • 1998
  • The stabilization of low dielectric constant SiOF films prepared by conventional PECVD using TEOS and $C_2F_6$ was evaluated by the $N_2O$-plasma post-deposition annealing. Properties of SiOF film became unstable when it was air-exposed or heat-treated. Water absorption of SiOF films was increased as F content was increased due to the for¬mation of F -Si- F bonds. Also F content of SiOF films decreased after heat treatment. $N_2O$-plasma post-deposition annealing was proved to be effective on stabilizing SiOF films. which was mainly due to the formation of thin SiON layer near the top surface of films. However. the value of dielectric constant was greatly increased again when $N_2O$-plasma post-deposition annealing was done for a long time. To stabilize the SiOF films without an increase of dielec¬tric constant by $N_2O$- plasma post-deposition annealing. the annealing time should be kept the minimum value. to which stabilizing effects against air environment and heat treatment were preserved.

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Effect of Al Content Variation on High Temperature Gas Nitriding in 13%Cr-0.16%C Stainless Steel (13%Cr-0.17%C 스테인리스강의 고온 가스질화에 미치는 Al 함량 변화의 영향)

  • Park, B.T.;Kim, J.M.;Kang, H.J.;Kong, J.H.;Kang, C.Y.;Sung, J.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.6
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    • pp.318-326
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    • 2011
  • This study has been performed to investigate the effect of Al addition on High Temperature Gas Nitriding (HTGN) in 13%Cr-0.16%C stainless steel with different Al contents of 0.54%, 1.76% and 2.36%, respectively. HTGN treatment was carried out at $1100^{\circ}C$ for 1 hr, 5 hrs and 10 hrs. Nitrogen-permeated surface layers showed round type carbides of $Cr_{23}C_6$ and needle type nitrides of AlN in the matrix of martensite, representing 600~700 Hv. And the thickness of the surface layer increased with increasing Al content and HTGN treatment time. The inner region that was not permeated nitrogen showed chromium carbides in the mixed phase of martensite and ferrite for the 0.53% Al alloyed steel, however chromium carbides in the matrix of ferrite single phase were shown for the steels with the addition of 1.76%Al and 2.36%Al, representing the hardness of ~200 Hv. During nitrogen permeation from surface to the interior, substitutional elements of Cr, Al and Si moved toward the surface and interstitial element of carbon also moved from interior to the surface. This movement of alloying elements leads high concentration of these elements at the outmost surface, subsequently the lowest peak of substitutional elements were shown in the vicinity of near surface. After showing the lowest peak, the high concentration region of Al and C were formed due to the continuous movement of Al toward the surface. The long discontinuous precipitates of $Cr_{23}C_6$ and AlN were formed along the outmost surface owing to the high concentration of these alloying elements.

Performance of Constructed Facilities: Pavement Structural Evaluation of William P Hobby Airport in Houston, Texas

  • Kim, Sung-Hee;Jeong, Jin-Hoon;Kim, Nak-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.21-25
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    • 2009
  • The results of a recent case study for material characterizations and structural evaluation to design asphalt overlay thickness of William P Hobby airport in Houston, Texas are presented herein. The existing runway 12R-30L of Hobby airport consisted of thick asphalt overlay over Portland Cement Concrete (PCC) and the localized surface shoving as evident in the closure of surface groove has been observed recently. Using the field cored asphalt concrete mixtures, measurements of percent air voids, asphalt content and aggregate gradation were conducted to find out the causations of surface shoving and groove closure. The FAA layered elastic program, LEDFAA was utilized to evaluate pavement structural conditions for new asphalt overlay. Two different composition assumptions for existing pavement were made to evaluate the pavement as followings: 1) APC, Asphalt Concrete Overlay over PCC pavement and 2) AC, Asphalt Concrete pavement. Based on laboratory testing results, a ratio of percent passing #200 to asphalt content ranged 1.1 to 2.2, which is considered a high ratio and a tendency of tender mix design was observed. Thus, the localized surface shoving and groove closure of the runway 12R-30L could be attributed to the use of excessive fine contents and tender mix design. Based on the structural evaluation results, it was ascertained that the analysis assuming the pavement structure as AC pavement gives more realistic structural life when the asphalt overlay is thicker enough compared to PCC layer because the existing PCC pavement under asphalt overlay acts more like a high quality base material.

Thermally Induced Gelation of Alaska pollack Meat Paste -2. The states of water in meat paste by gelation- (가열에 의한 명태 연육의 Gel화에 관한 연구 -2. Gel화에 따른 연육내의 물의 거동-)

  • JUNG Woo-Jin;PARK Seong-Min;LEE Kang-Ho;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.3
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    • pp.230-234
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    • 1993
  • In order to obtain the fundamental factors influencing on gelation of Alaska pollack meat paste during processing, the states of water in gel from meat paste were studied using differential scanning calorimetry(DSC) and thermogravimetry(TG). In the differential scanning calorimetry, the calorimetric curves of gels were characterized by single peak through the evaporation of water. Each curve was divided into two divisions below and above $105^{\circ}C(Q_1\;and\;Q_2)$, and a quotient, $R_{105}[={Q_2/(Q_1+Q_2)}+100]$ was adopted to represent the amount of immobilized water in the total water of gels. There was a good correlationships between gel strength values and those quotients($R_{105}$), the correlation coefficient was 0.93. Three types of water(A, B, C) differentiated by evaporating velocity were regarded as free water and it was abundant among the three types of water. The type C water was regarded as the water in so-called mono-molecular layer region. The ratio of the content C versus total water content showed good correlationships with the gel strength and its correlation coefficient was 0.99.

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Classification of Forest Vegetation Type and Environmental Properties in Limestone Area of Korea (석회암지대 산림식생의 유형과 환경특성)

  • Yun, Chung-Weon;Moon, Hyun-Shik
    • Journal of agriculture & life science
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    • v.43 no.2
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    • pp.1-8
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    • 2009
  • The limestone area covers the narrow range of the Korean Peninsula, and it consists of a peculiar ecosystem and topography. Therefore, this study on limestone area was carried out classification of vegetation type, physicochemical properties of forest soils and correlation between environment factors and vegetation types in order to furnish fundamental data for the forest management of limestone area. Forest vegetation was classified into two community groups such as Quercus variabilis community group and Quercus mongolica community group, and it was classified into eight vegetation units. Soil texture of survey sites showed largely silt loam and soil pH indicated the value of mean 7.55 in the A layer of soil profile. Content of exchangeable cation such as calcium ion ($Ca^{2+}$) and magnesium ion ($Mg^{2+}$) showed $26.04cmol_{c}/kg$ and $2.93cmol_{c}/kg$, respectively, which was about ten times higher than average of other regions of Korea. According to corelation between environmental factors and vegetation units, Q. variabilis community group was positively correlated to soil pH, slope degree and the rate of bare rock, and content of calcium ion ($Ca^{2+}$), and then Q. mongolica community group was positively correlated to altitude, respectively.

Antioxidant Enzymes of Strains Panax ginseng C.A. Mey. and Panax quinquefolius L.

  • Slepyan L.I.;Kirillova N.V;Strelkova M.A.
    • Proceedings of the Ginseng society Conference
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    • 2002.10a
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    • pp.502-508
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    • 2002
  • The strains of Panax ginseng C.A. Mey., P. quinquefolius L. and selected strains P. ginseng-B, P.ginseng-A, P. quinquefolius-C were investigated. Activities of SOD, catalase and peroxydase were determined by methods of Fridovich et al. (1979), Komov et al.(1975), Bovaird et al.(1982) respectively. Activities of SOD, catalase, peroxydase were investigated every day 5 in cycle of cultivation. For P. ginseng it was the 35 days, P. quinquefolius the 70 days, P. quinquefolius-C 90 days. P. ginseng-B 90 days, P. ginseng-A 60 days. The P. quinquefolius, P. quinquefolius-C, P. ginseng-B had clear differentiation and developed tracheid elements, which are absent in strain of P. ginseng. The peaks of protein content for P. ginseng (4.5 units/g) and for P. quinquefolius (3.5 units/g) were on day 10 and remained unchanged till the last cultivation. The strain P. ginseng-A had two peaks of protein content (2.5 mg/g) on day 15 and on day 30. For P. ginseng-B strain these peaks were on day 5 and day 40 (3.5 mg/g). Peroxydase activity peak (60 units/g) in P. ginseng strain was on day 10. This activity in P. ginseng-B had two peaks on day 15 and day 35 and reached 95 units/g , increasing to 150 units/g to day 80. In strain of P. ginseng-A was only one maximum of this activity -130 units/g on day 45. In P. quinquefolius peroxydase activity was 103 units/g on day 40, increasing to 135 units/g to day 90. For P. quinquefolius-C this activity peak was 136 units/g on day 60. Peroxydase activities for the upper and lower layers of biomass was different and varied considerably from 28-35 units/g in lower to 270-290 units/g for upper layer. The SOD activity had two peaks in P. ginseng strain the 80 units/g and the 70 units/g on day 20 and day 35 respectively. Activity of SOD in P. quinquefolius strain reached 53 units/g on day 40 and increased up to 83 units/g to day 60.The similar increase of SOD activity was marked for P. ginseng-B to 85 units/g on day 90. In P. ginseng strain the 6 molecular isoforms SOD was defined. One of them with RfO,6 was determined in all days of cycle, three other (Rf-0.43; 0.54;0.80) only on day 10 and day 20. The isoform of SOD with Rf-0,29 was detected only on day 10 and with Rf-0,35 only on day 35. The catalase activity decreased in all strains to the last days of cultivation. The changes of SOD, catalase and peroxydase activities reflect the differences between the strains of Panax ginseng and Panax quinquefolius and their selected forms. The correlation between maximum life span of strains and activities of their antioxydant enzymes were detected.

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Calculation of Soil Moisture Control Section to determine Soil Moisture Regime of Medium Textured Soil Catena in Hilly Area (경사지(傾斜地) 중립질토양연접군(中粒質土壤連接群)에 대한 토양수분상(土壤水分相) 결정(決定)을 위한 부위(部位) 선정(選定))

  • Jung, Yeun-Tae;Kim, Jung-Kon;Son, Il-Soo;Yoon, El-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.1
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    • pp.1-5
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    • 1989
  • This study was carried out by using laboratory data to calculate Soil Moisture Control Section (SMCS) for medium textured topo-sequential soils derived from porphyry in Milyang area. The soils studied were characterized by loam to silty clay loam, and the moisture content at -1/3 bar in the solum ranged around 21.06% to 32.42%. The moisture contents per centimeter of soil layer within a solum calculated at field capacity (FC) ranged from 0.11cm to 0.19cm. The upper boundaries of SMCS of the soils calculated on the basis of FC as the water content at -1/3 bar, ranged from 16.2cm to 21.2cm and the lower boundaries from 44.4cm to 63.8cm, and the depth of SMCS were from 27.7cm to 42.6cm in the soil profiles. The Bongsan soil on the summit had shallower in the boundaries and narrower in the depth of SMCS than the soils on side-slopes or on valley.

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Material Properties Evaluation of Cement Mortar Mixed with Organic/Inorganic Combined Water-repellent (유/무기 복합 발수제를 혼입한 모르타르의 재료특성 평가)

  • Kim, Wan-Su;Yoon, Chang-Bok;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.50-58
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    • 2020
  • When the concrete surface layer is damaged, The method of impregnating the concrete surface with a water repellent cannot secure the expected durability. Recently, various waterproofing and water-repellent materials were mixed into concrete or mortar to secure water repellency even inside cracks, but compressive strength was greatly reduced. In order to overcome the decrease in compressive strength, there has not yet been a study using the merits of organic and inorganic materials at the same time, so in this study, the physical properties and water repellency performance were evaluated by mixing an organic/inorganic composite water repellent appropriately mixed with an organic and inorganic material into the mortar. When mixed with organic/inorganic water repellent, the flow and air content were reduced by about 10% and 50% compared to the Liquid specimen. In the case of the P6L1 specimen, it was confirmed that the compressive strength decreased by about 3.5% compared to the non-mixed mortar at 39.5 MPa, the same as the existing water repellent, Powder. Water-repellent performance The organic-inorganic composite water repellent mixture specimen confirmed higher water repellency than the existing water repellent mixture powder, and the chloride penetration resistance evaluation result showed that the organic-inorganic composite water repellent mixture specimen reduced the passing charge by about 45% compared to the non-mixed mortar. In summary, it is judged that the P5L1 organic/inorganic composite water repellent mixed with a powder water repellent and a liquid water repellent in a ratio of 5:1 is the most reasonable to prevent the decrease in compressive strength and secure water repellency.

Geotechnical Properties of Pelagic Red Clay in Northeast Equatorial Pacific (북동태평양 원양성 적점토의 지질공학적 특성에 관한 연구)

  • Chi, Sang-Bum;Lee, Hyun-Bok;Hyeong, Ki-Seong;Ju, Se-Jong;Lee, Gun-Chang;Ham, Dong-Jin
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.3
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    • pp.286-294
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    • 2008
  • In order to understand the physical properties of deep-sea sediments, which mainly consist of pelagic red clays, sediment samples were collected at 24 stations using a multiple corer in the Clarion-Clipperton fracture zone of the northeast equatorial Pacific. The sampled sediment cores were examined for the mass physical properties(i.e. grain size distribution, mean grain size, water content, specific grain density, wet bulk density, void ratio, and porosity) and the geotechnical properties(i.e. shear strength and consistency limits) with the content of biogenic opal and mineral composition. Although KR1 and KR2 areas on the same latitude are logitudinally far from each other, the mass physical properties of these areas are not distinctly different except for shear strengths. The maximum shear strength of surface sediments in KR2 area is higher than that in KR1 due to the appearance of a consolidated lower layer(Unit 3) in the sediment core from KR2.

Effects of Fructooligosaccharide and Fruit and Vegetable Complex Extracts on Loperamide-induced Constipation in Rats (로페로마이드로 유도한 변비랫드 모델에서 프락토올리고당 및 과채복합 추출물의 변비개선 효과)

  • Hyun Kyoung Kim
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.3
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    • pp.865-872
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    • 2024
  • Loperamide-induced constipation reduced gastric emptying, small-intestinal and colonic motility, and these effects were prevented by Fruit and vegetable complex extracts(FVCE). In this study, the effects of FVCE on constipated male Sprague-Dawley rats induced by loperamide(3 mg/kg, s.c.,14 days) were investigated. Rats were randomly assigned to the normal control rats(regular diet), constipated rats(regular diet plus loperamide), constipated rats treated with 200 mg FVCE(regular diet supplemented with 200 mg/kg/day FVCE plus loperamide), constipated rats treated with 400 mg FVCE(regular diet supplemented with 400 mg/kg/day FVCE plus loperamide). There was less fecal excretion and lower fecal water content in loperamide-treated rats than in control rats. Oral administration of FVCE blocked the decrease of fecal excretion and fecal water content in the loperamide-treated rats. Mucus production of crypt cell and mucus contents at fecal and mucosa surface were reduced by loperamide-treated rat. But colonic crypt cell contained increased mucin in the FVCE treated group and mucus layer stained with alcian blue was significantly thicker in FVCE treated rats compared with in loperamide-treated rats. In isolated rat ileum, loperamide produced inhibition of ileal motility. Pretreatment with water extracts of FVCE in isolated rat ileum prevented inhibition by loperamide. These findings indicated that the FVCE was effective for alleviation of inhibition of colonic peristalsis by loperamide and that FVCE might be of value in the prevention of constipation.