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A Study on EPMA on Ni-Cr Alloy by Nb content for Porcelain Fused to Metal Crown (Nb이 첨가된 금속소부도재관용 Ni-Cr 합금 표면의 EPMA 관찰)

  • Kim, Chi-Young;Choi, Sung-Min;Cho, Hyeon-Seol
    • Journal of Technologic Dentistry
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    • v.28 no.1
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    • pp.19-26
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    • 2006
  • The effect of Nb on interfacial bonding characteristics of Ni-Cr alloy for porcelain fused to metal crown (PFM) has been studied in order to investigate oxide layer. A specimens of Ni-Cr alloy, which is 0.8mm in thickness, within the porcelain furnace of 1,000$^{\circ}C$ with four tests such as air, vacuum, air for 5 minutes and vacuum for 5 minutes in order to examine an oxide behavior of alloy surface generated by the adding of Nb to be controlled at a rate of 0, 1, 3 and 5. Oxide film was observed form of the fired specimens with scanning electron microscope (SEM), and at the same time it measured Electron Probe Micro Analyzer (EPMA). The result of this study were as follows: 1. Cr oxide film and Nb oxide film were observed from the surface of specimen to be controlled at a rate of Nb 1%. 2. Nb oxide film was observed from the interface of specimens to be controlled at a rate of Nb 1% and 3%. 3. The stability of oxide films that treated in air were more stable than treated under vacuum.

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Synthesis and Application of Caffeic Acid Methoxy Polyethylene Glycol Ester (카페산 메톡시 폴리에틸렌글리콜 에스테르의 합성 및 응용)

  • Lee, Hyun-Gi;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.259-266
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    • 2011
  • Caffeic acid is a kind of phytochemicals occurred in coffee, which is worked as a carcinogenesis restrainer and antioxidants on the human body. In this study, as one type of caffeic acid derivatives, methoxypolyethylene glycol caffeate(MPC) was synthesized by the esterification between caffeic acid and methoxypolyethylene glycol with N,N'-dicyclohexyl carbodiimide, 4-dimethylamino pyridine. The synthesized product was confirmed by using FT-IR and $^1H$-NMR, thin-layer chromatography. And these compound was investigated as antioxidant, Tyrosinase hindrance and skin moisturizers. In the free radical scavenging study, antioxidant effect of MPC was averagely high than the red ginseng extract that be used as a natural antioxidants. The result of Tyrosinase anti-activity test was better than embryo bud of rice extract at low concentration. At the iNOS anti-activity tested by using Raw 264.7 cell, and confirmed anti-inflammatory function. For the MPC handled with sodium lauryl sulfate, was tested for the skin moisture content and skin moisture loss.

Density Composition and Feeding Guild of the Dominant Polychaetous Community in Shallow Muddy Bottom in Tomioka Bay, Amakusa, Japan

  • LEE Si-Wan;PAIK Eui-In
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.6
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    • pp.793-804
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    • 1995
  • Polychaetous community survey in Tomioka Bay was carried out 5 times seasonally from May 1991 to March 1992 by quantitative grab sampling (0.05m2) at 11 stations. Based on the granulometric composition and environmental factors, a homogeneous soft bottom was found in St.5-10. The species of the polychaete were classified into three feeding groups using the Fauchald and Jumars' feeding guild system. According to polychaetous community composition data, deposit feeders predominate in sandy silt area where the silt-clay content is $60-69.3\%.$ These deposit feeders were subdivided into surface deposit feeders and subsurface deposit feeders by their living position and mode. Also, suspension feeding group comes as the third dominant group. Seasonal changes of each feeding group were described in terms of numerical density and biomass. Feeding layer and types of dominant species (Lumbrineris longifolia: surface deposit feeder; Praxillella pacifica: subsurface deposit feeder; Chone duneri; suspension filter feeder, etc.) were examined in the intact sediment core samples. Also, longterm density change among the three dominant species during 10 years was disussed.

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DCT and Homomorphic Encryption based Watermarking Scheme in Buyer-seller Watermarking Protocol

  • Seong, Teak-Young;Kwon, Ki-Chang;Lee, Suk-Hwan;Moon, Kwang-Seok;Kwon, Ki-Ryong
    • Journal of Korea Multimedia Society
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    • v.17 no.12
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    • pp.1402-1411
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    • 2014
  • Buyer-seller watermarking protocol is defined as the practice of imperceptible altering a digital content to embed a message using watermarking in the encryption domain. This protocol is acknowledged as one kind of copyright protection techniques in electronic commerce. Buyer-seller watermarking protocol is fundamentally based on public-key cryptosystem that is operating using the algebraic property of an integer. However, in general usage, digital contents which are handled in watermarking scheme mostly exist as real numbers in frequency domain through DCT, DFT, DWT, etc. Therefore, in order to use the watermarking scheme in a cryptographic protocol, digital contents that exist as real number must be transformed into integer type through preprocessing beforehand. In this paper, we presented a new watermarking scheme in an encrypted domain in an image that is based on the block-DCT framework and homomorphic encryption method for buyer-seller watermarking protocol. We applied integral-processing in order to modify the decimal layer. And we designed a direction-adaptive watermarking scheme by analyzing distribution property of the frequency coefficients in a block using JND threshold. From the experimental results, the proposed scheme was confirmed to have a good robustness and invisibility.

Effects of Dietary Supplementation of Copper Chelates in the Form of Methionine, Chitosan and Yeast in Laying Hens

  • Lim, H.S.;Paik, I.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.8
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    • pp.1174-1178
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    • 2006
  • An experiment was conducted to investigate the effects of dietary supplementation of copper chelates in the form of methionine, chitosan and yeast on the performance of laying hens. Four hundred ISA Brown layers, 84 wks old, were assigned to 4 treatments: control, 100 ppm Cu in methionine chelate (Met-Cu), 100 ppm Cu as chitosan chelate (Chitosan-Cu) and 100 ppm Cu as yeast chelate (Yeast-Cu). Each treatment had five replicates of 20 hens. Hen-day and hen-housed egg production and egg weight were significantly (p<0.05) increased by Met-Cu supplementation. The increase by Chitosan-Cu and Yeast-Cu supplementation was not significant. Contrast of the control vs. Cu chelates showed egg weight was significantly (p<0.05) increased by Cu chelate supplementation. Soft-shell egg production was significantly (p<0.05) reduced by supplementation of Cu chelates. Met-Cu treatment showed the lowest incidence of soft egg production. Gizzard erosion index was increased by Cu chelate supplementation. Crude fat in liver, total cholesterol in yolk and Cu content in liver and yolk were not significantly influenced by Cu chelate supplementation. It was concluded that dietary supplementation of 100 ppm Cu as Met-Cu significantly increased egg production and egg weight. Cu-Met chelate was also effective in reducing soft-shell egg production but increased gizzard erosion index.

N$_2$ Plasma Treatment Effects of Silicon Nitride Insulator Layer for Thin Film Transistor Applications

  • Ko, Jae-Kyung;Park, Yong-Seob;Park, Joong-Hyun;Kim, Do-Young;Yi, Jun-Sin;Chakrabarty, K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.563-566
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    • 2002
  • We investigated to decrease the leakage current of SiNx film by employing $N_2$ plasma treatment. The insulator layers were prepared by two step process; the $N_2$ plasma treatment and then PECVD SiNx deposition with $SiH_4$, $N_2$ gases. To prove the influence of the $N_2$ plasma treatment, the Si substrate was exposed to the plasma, which was generated in Ne gas ambient. Without plasma treatment SiNx film grow at the rate of 7. 03 nm/min, has a refractive index n = 1.77 and hydrogen content of $2.16{\times}10^{22}cm^{-3}$ for $N_2/SiH_4$ gas flow ratio of 20. The obtained films were analyzed in terms of deposition rates, refractive index, hydrogen concentration, and electrical properties. By employing $N_2$ plasma treatment, interface traps such as mobile charges and injected charges were removed, hysteresis of capacitance-voltage (C-V) disappeared. We observed plasma treated sample were decreased the leakage current density reduces by 2 orders with respect to the sample having no plasma treatment.

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Fabration of PLC susbstrate by slurry filling and sandblasting Method (Tape casting 법과 Sandblasting 법을 이용한 광소자용 기판 제조 (1))

  • Cho, Yun-Hui;Kim, Young-Seog;Lee, Young-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.341-345
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    • 2001
  • In this study, nano-sized powders of $Si0_2-0^{\sim}15mol%B_2O_3$ composition were prepared by sol-gel processing method using TEOS(Tetra ethyl ortho silicate) and $H_3BO_3$ solution. The powders were tape-cast on High silicate glass sheet(HSG) substrate and sintered to form a layer of undercladding for the planar light wave module, During the sol-gel processing, $H_2O/Si$ mole ratio were varied to modify the size of the powders in a range from 600 to 75nm. The dispersion of the powder was modified by changing the pH of the slurry. Sintering temperature of the tape was observed to decrease with the size of the powder and the $B_2O_3$ content in the powder. When the silica powders of 75-125nm in diameter containing 15mol% $B_2O_3$ were used, 98 TD% was obtained at $1250^{\circ}C$, which is approximately $300^{\circ}C$ reduction in sintering temperature compared with micrometer-sized powders.

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스파타링에 의한 탄화티탄 피복에 관한 연구

  • 김병옥;방병옥;윤병하
    • Journal of Surface Science and Engineering
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    • v.23 no.1
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    • pp.16-26
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    • 1990
  • The standrd electrolyte for the electrodeposition of chromium were preparwith reagent grade chromic acid(200g/L), sulfuric acid(pH=1.8)and oxalic acalic acid(640g/L)as additive. Carbon content in chromium plating varied about2.0-3.8 wt% with current density and temperatures of the bath. The hardeness of chromium platings incresed with increasing the annealing temperatures and showed maximum value of about Hv 1700 after annealing at$ 700^{\circ}C$for 60min. But, decreased it as annealing at above $700^{\circ}C$. The reason for varing thee hardness of chromium codeposited with carbon gradually foumed chromium carbide(Cr7C3), but that changed to Cr23C6 as annealing temperature at above $^700{\circ}C$. The X-ray diffraction pattern indicated that chromium carbides, such as Cr7C3 or Cr3C2, formed at formed at above $300^{\circ}C$. titanium coating sputtered on the on surface of chromium plating had performed and determined the hardness after annealing at 500, 600, $700^{\circ}C$ for 60min. the maximum hardeness was about Hv 2400 as annealing at $700^{\circ}C$. The titanium carbide formed in layer was identified by X-ray diffraction. It was confirmed that chromium and titanium carbide has effect of increasing the hardness.

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A Study on Oxidation-Resistance of Iron Nanoparticles Synthesized by Chemical Vapor Condensation Process (화학기상응축법으로 제조된 철 나노분말의 산화저항에 관한 연구)

  • Lee Dong-Won;Yu Ji-Hun;Bae Jeoung-Hyun;Jang Tae-Suk;Kim Byoung-Kee
    • Journal of Powder Materials
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    • v.12 no.3
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    • pp.225-230
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    • 2005
  • In order to prevent the oxide formation on the surface of nano-size iron particles and thereby to improve the oxidation resistance, iron nanoparticles synthesized by a chemical vapor condensation method were directly soaked in hexadecanethiol solution to coat them with a polymer layer. Oxygen content in the polymer-coated iron nanoparticles was significantly lower than that in air-passivated particles possessing iron-core/oxide-shell structure. Accordingly, oxidation resistance of the polymer-coated particles at an elevated temperature below $130^{\circ}C$ in air was $10\~40$ times higher than that of the air- passivated particles.

Isolation and Proteomic Analysis of a Chlamydomonas reinhardtii Mutant with Enhanced Lipid Production by the Gamma Irradiation Method

  • Baek, Jaewon;Choi, Jong-il;Park, Hyun;Lim, Sangyong;Park, Si Jae
    • Journal of Microbiology and Biotechnology
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    • v.26 no.12
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    • pp.2066-2075
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    • 2016
  • In this study, an enhanced lipid-producing mutant strain of the microalga Chlamydomonas reinhardtii was developed by gamma irradiation. To induce the mutation, C. reinhardtii was gamma irradiated at a dose of 400 Gy. After irradiation, the surviving cells were stained with Nile red. The mutant (Cr-4013) accumulating 20% more lipid than the wild type was selected. Thin-layer chromatography revealed the triglyceride and free fatty acid contents to be markedly increased in Cr-4013. The major fatty acids identified were palmitic acid, oleic acid, linoleic acid, and linolenic acid. Random amplified polymeric DNA analysis showed partial genetic modifications in Cr-4013. To ascertain the changes of protein expression in the mutant strain, two-dimensional electrophoresis was conducted. These results showed that gamma radiation could be used for the development of efficient microalgal strains for lipid production.