• Title/Summary/Keyword: Contamination process

Search Result 744, Processing Time 0.027 seconds

Quantitative Determination of PFOA and PFOS in the Effluent of Sewage Treatment Plants and in Han River (서울시 하수처리장 방류수 및 한강 내 PFOA와 PFOS의 과불화화합물 모니터링 연구)

  • Shin, Mi-Yeon;Im, Jong-Kwon;Kho, Young-Lim;Choi, Kyoung-Sik;Zoh, Kyung-Duk
    • Journal of Environmental Health Sciences
    • /
    • v.35 no.4
    • /
    • pp.334-342
    • /
    • 2009
  • Perfluorinated compounds (PFCs) have a wide range of domestic and industrial applications, but they are persistent in the environment. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) are among the metabolites of PFCs and occur at high concentration in the environment. Korea is the largest importer of PFC compounds in the world, therefore, the accumulation of these compounds is possible. In this study, the concentrations of PFOS and PFOA were determined in water samples taken from sewage treatment plants (STPs) and the Han River in Seoul, Korea. After extraction with a HLB cartridge, PFCs in the samples were analyzed by HPLC with an ion trap mass spectrometry in electrospray negative mode. Limits of detection was between 1 and 1.6 ng/l. The result showed that the concentrations of PFOS and PFOA in effluent and influent of the four STPs in Seoul were 60~570 ng/l, and not detected (nd)~254 ng/l, respectively. The levels of PFOS and PFOA were higher in the effluents which passed through the treatment process than in influent water samples which was against expectation. The concentration of PFOA and PFOS in the Han River was 60~570 ng/l and nd~254 ng/l, respectively. PFOA was detected in every sample, but PFOS was only detected in the downstreams of the Han River. This result indicates that there is comprehensive contamination of PFCs in the aquatic environment in Korea.

A Study on the Dyeing of CDP(cation dyeable polyester)/Silk Knitted Fabrics With Disperse Type Cation Dyes/Acid Dyes (분산형캐티온염료/산성염료에 의한 CDP(cation dyeable polyester)/견 교편물의 염색에 관한 연구)

  • Sung, Woo-Kyung
    • Fashion & Textile Research Journal
    • /
    • v.13 no.5
    • /
    • pp.797-805
    • /
    • 2011
  • This study was carried out to investigate dyeing characteristics of CDP(cation dyeable polyester)/silk knitted fabrics with disperse type cation dyes/acid dyes by one bath dyeing method in comparison with two bath dyeing method in the interests for rationalization of the dyeing process. The apparent color depth(K/S) of the disperse type cation dyes with CDP and that of acid dyes with silk decreased slowly with increasing pH values of dyebath with the exception of sharp decrease at alkali region for CDP. The contamination behavior of CDP by the acid dyes and that of silk by the disperse type cation dyes decreased with progressing of dyeing. The migration ratio(%) of the disperse type cation dyes with CDP is low compared with that of acid dyes with silk. The sediment in mixed dying solution of disperse type cation dyes and acid dyes remarkably less compared with that of regular type cation dyes and acid dyes at $100^{\circ}C$ regardless applying of preventer agent of precipitation. When CDP/silk knitted fabrics was dyed with by with mixtures of disperse type cation dyes/acid dyes one bath or two bath dyeing method, the characteristic of reflectance spectra of CDP components were greatly influenced by disperse type cation dyes and that of silk components by acid dyes. It was confirmed that K/S values of each components of CDP/silk knitted fabrics dyed by one bath dyeing method decreased slightly compared with two bath dyeing method.

Analysis of New Air Control System in Clean Stocker (Clean Stocker내 새로운 방식의 기류제어에 관한 해석)

  • Choe, Gi-Han;Han, Chang-U;Lee, Sang-Ryong
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.26 no.1
    • /
    • pp.121-130
    • /
    • 2002
  • Clean stockers are being used by semiconductor and TFT-LCD manufacturers to store and buffer work in process. Since an important function of a stocker is to keep the contained material clean. The only way to keep the stored product clean is to provide constant clean airflow the product and through stocker, The airflow across the product prevent contamination from settling on the product. Up to now, stocker typically have been configured to receive their laminar airflow from fan filter units that are located on the side of the stocker This type of stocker may have such problems as complexity of structure, increment of temperature, mechanical vibration, initial investment and running cost. In this study, In order to solve the above mentioned problems, new air control system in stocker is proposed, which is to control open ratios of exits that are located on the side of the stocker without fan filter units. Open ratios of exits need to be optimized for the same quantities of airflow in each exit. In this study, static pressure regain was used for the analysis of the open ratios of exits theoretically and Blue Ridge Numerics FEM software, CFDesign, was used fur simulating airflow in stocker. As a result, Open ratios of exits important to provide constant clean airflow can be obtained by the analysis of static pressure regain and was verified by simulation results. Therefore, new air control system in stocker can be used by the semiconductor and TFT-LCD manufacturers.

Plasma etching behavior of RE-Si-Al-O glass (RE: Y, La, Gd)

  • Lee, Jeong-Gi;Hwang, Seong-Jin;Lee, Seong-Min;Kim, Hyeong-Sun
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2010.05a
    • /
    • pp.49.1-49.1
    • /
    • 2010
  • The particle generation during the plasma enhanced process is highly considered as serious problem in the semiconductor manufacturing industry. The material for the plasma processing chamber requires the plasma etching characteristics which are homogeneously etched surface and low plasma etching depth for preventing particulate contamination and high durability. We found that the materials without grain boundaries can prevent the particle generation. Therefore, the amorphous material with the low plasma etching rate may be the best candidate for the plasma processing chamber instead of the polycrystalline materials such as yttria and alumina. Three glasses based on $SiO_2$ and $Al_2O_3$ were prepared with various rare-earth elements (Gd, Y and La) which are same content in the glass. The glasses were plasma etched in the same condition and their plasma etching rate was compared including reference materials such as Si-wafer, quartz, yttria and alumina. The mechanical and thermal properties of the glasses were highly related with cationic field strength (CFS) of the rare-earth elements. We assumed that the plasma etching resistance may highly contributed by the thermal properties of the fluorine byproducts generated during the plasma exposure and it is expected that the Gd containing glass may have the highest plasma etching resistance due to the highest sublimation temperature of $GdF_3$ among three rare-earth elements (Gd, Y and La). However, it is found that the plasma etching results is highly related with the mechanical property of the glasses which indicates the cationic field strength. From the result, we conclude that the glass structure should be analyzed and the plasma etching test should be conducted with different condition in the future to understand the plasma etching behavior of the glasses perfectly.

  • PDF

Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Lee, Un-Yong;Han, Dong-Hee;Kang, Sung-Hwa;Choi, In-Hyuk;Lim, Kee-Joe
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.1
    • /
    • pp.62-67
    • /
    • 2005
  • Recently, polymer insulators that are used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination that lead to dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. Polymer material is also investigated it's tracking resistance by adding surface active agent in IEC 587. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination, STRI guide and thermal image camera.

Prospects for Building a Legal System for Marine Environment Protection in China (중국의 해양환경법제 분석과 전개방향에 관한 고찰)

  • Yang, Hee-Cheol;Park, Seong-Wook;Park, Su-Jin;Kwon, Suk-Jae
    • Ocean and Polar Research
    • /
    • v.30 no.1
    • /
    • pp.89-107
    • /
    • 2008
  • Marine environment is subject serious destruction because of frequent accidents during exploration of marine resources and overseas transport. Also, as many industrial enterprises discharge high volume of wastes and contamination, marine pollution has become a serious threat to people (especially in China). China is quickly becoming a world economic leader of the 21st century. Rapid industrialization and social changes have raised the standard of living of millions of the Chinese, mainly in the areas of East and South East coast. The process of industrialization, however, is often followed by deterioration of the marine environment and rarely turned around until a country has increased its standard of living. Solving these array of problems will take decades and currently the government is addressing minor specific issues only. Fortunately, the Chinese government has enacted a number of marine pollution control laws. On 25 December 1999, the 13th Session of the Ninth Standing Commettee of the National People's Congress passed the amended the Marine Environment Protection Law of the People's Republic of China. This Law establishes rights and responsibilities of the relevant departments concerning marine environment management and provides for two new chapters on "Marine Environment Supervision" and "Marine Ecological Protection", along with "Supervision of Pollution Prevention for Marine Construction Projects", "Marine Ecological Protection" and "Marine Environment Pollution Prevention for Marine Construction Projects". Also, the Law was amended with provisions for integrated pollution discharge control system and oil spillage emergency response plan and enhanced legal responsibilities. Chinese government recognizes that international and national experience can be useful for China to prevent further ecological degradation of the marine environment.

Continuous Production of Succinic Acid Using an External Membrane Cell Recycle System

  • Kim, Moon-Il;Kim, Nag-Jong;Shang, Longan;Chang, Yong-Keun;Lee, Sang-Yup;Chang, Ho-Nam
    • Journal of Microbiology and Biotechnology
    • /
    • v.19 no.11
    • /
    • pp.1369-1373
    • /
    • 2009
  • Succinic acid was produced by continuous fermentation of Actinobacillus succinogenes sp. 130Z in an external membrane cell recycle reactor to improve viable cell concentration and productivity. Using this system, cell concentration increased to 16.4 g/l at the dilution rate $0.2\;h^{-1}$, up to 3 times higher than that of batch culture, and the volumetric productivity of succinic acid increased up to 6.63 g/l/h at the dilution rate $0.5\;h^{-1}$, 5 times higher than that of batch fermentation. However, in the continuous culture using a high dilution rate, operational problems including severe membrane fouling and contamination by lactic acid producer were observed. Another succinic acid producer, Mannheimia succiniciproducens MBEL55E, was also utilized in this system, and the cell concentration and productivity of succinic acid at the dilution rate of $0.3\;h^{-1}$ were found to be above 3 and 2.3 times higher, respectively, compared with those obtained at the dilution rate of $0.1\;h^{-1}$. These observations give a deep insight into the process design for a continuous succinic acid production by microorganisms.

Analysis of Microbial Contaminants and Microbial Changes during Dried-laver Pyropia spp. Processing (마른김(Pyropia spp.) 가공 공정 경과에 따른 미생물 오염도 분석)

  • Kwon, Kion;Ryu, Dae-Gyu;Jeong, Min-Chul;Kang, Eun-Hye;Jang, Yumi;Kwon, Ji Young;Kim, Jeong-Mok;Shin, Il-Shik;Kim, Young-Mog
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.51 no.1
    • /
    • pp.8-14
    • /
    • 2018
  • We investigated the levels of microbial contaminants and microbial hazards during dried-laver processing. We analyzed 321 samples obtained from 18 dried-laver Pyropia spp. manufacturing facilities, including water, swab-, and processing samples as well as final products. The levels of microbial contaminants, including viable cell counts (VCC) and coliform bacteria, increased as processing progressed. The sanitary indicator bacterium, Escherichia coli, was not detected in the final products although VCC levels were high, generally exceeding 5 log CFU/g. We also investigated changes in microbial contaminants at each processing step. Both VCC and total coliform dramatically increased after 4 days of continuous processing, indicating that microbial contaminants originated, mainly, from cross contamination during processing.

Vitellogenesis in Vertebrates and Environmental Estrogen (척추동물의 난황형성과 환경에스트로젠)

  • 계명찬;한명수
    • Korean Journal of Environmental Biology
    • /
    • v.18 no.3
    • /
    • pp.291-298
    • /
    • 2000
  • Vitellogenesis, an important reproductive process in oviparous animals, includes the processes of hormonally regulated synthesis of yolk precursor protein, vitellogenin (Vg), and their deposition in ovarian oocytes as a vitellin which is an important energy source as well as buoyancy regulator of the egg. Vg genes consist of a gene family that encompasses a large number of lipoproteins and produce different Mr. Vg proteins in liver. The expression of Vg is largely dependent on the estrogen, and both reproductive cycle and temperature also influence Vg synthesis. Synthetic estrogens or estrogenic pollutants was sufficient to induce Vg in both sexes of oviparous vertebrates. Therefore, the estrogenic induction of vitellogenesis in male has been used for biological marker in the screening of estrogenicity of certain endocrine disrupting compounds and the monitoring the world-wide contamination of estrogenic compounds in wild life. In the studies on the biological hazard and influence of endocrine disrupting chemicals using the Vg induction in oviparous males, it is important to consider the reproductive cycle, zoogeography and biodiversity of the wild life animals in Korea.

  • PDF

A Case History of Confinement of the Contaminated Landfill Using a Vortical Barrier (연직 차수벽을 이용한 폐기물매립지 침출수 오염 제어 사례 연구)

  • 이재영;정문경;고재만
    • Journal of Korea Soil Environment Society
    • /
    • v.4 no.2
    • /
    • pp.163-174
    • /
    • 1999
  • This paper presents a case history of remedial action adopted for contaminated groundwater in a landfill. The objectives of the projects are : (1) to effectively confine contaminated groundwater with an economically reasonable means, (2) to prevent further contamination of soil by collecting and treat the contaminant. and (3) to assure the environmental safety of the landfill during its operating period. Reported are the process from site investigation, through design and construction of an appropriate remedial action, to the monitoring of the selected confinement system. In view of the results of site investigation, deep soil mixing cutoff wall using the DMW(deep soil mixing cutoff wall) method and specially produced HEC soil stabilizer were used for the construction of deep soil mixing cutoff wall. For rock foundation with sever fractures, chemical grout curtain with urethane was installed. The monitoring results to date indicate that the selected vertical barrier performed satisfactorily.

  • PDF