• Title/Summary/Keyword: Contaminated area

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Study on the Oxidation and Dissolution Characteristics of Biogenic Mackinawite (미생물 기원 맥키나와이트의 산화 및 용해 특성 연구)

  • Lee, Seung-Yeop;Baik, Min-Hoon;Jeong, Jong-Tae
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.3
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    • pp.155-162
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    • 2012
  • We observed characteristic oxidation and dissolution phenomena induced by dissolved oxygen for mackinawite that is produced via sulfate-reducing bacteria (SRB) living in anaerobic environments such as soils and groundwater. We tried to recognize the role of the sulfide minerals that usually coexist with some stabilized radionuclides (e.g., reduced uranium), which can be reoxidized and redissolved by an oxygen-rich groundwater invaded into a contaminated area. The mackinawite produced by 'Desulfovibrio desulfuricans', a sulfate-reducing bacterium, was conducted to be dissolved for 2 weeks by some oxidants such as 'hydrogen peroxide' and 'sodium nitrite'. Although mineralogical oxidation and dissolution characteristics were different from each other according to the oxidants, the initially oxidized solution was early stabilized through the oxygen consumption by ${\mu}m$-sized sulfide particles and the resultant increase of sulfate in solution. From these results, we can anticipate that the large amount of sulfide minerals generated by SRB can not only repress the anoxic environment to be disturbed by the consumption of oxygen in groundwater, but also contribute to stabilize the reduced/precipitated radionuclides as a buffer material for a long time.

Reduction Efficiency of Cr(VI) in Aqueous Solution by Different Sources of Zero-Valent Irons (수용액 중 영가 철(Zero-Valent Iron)의 특성에 따른 Cr(VI)의 환원 효율 비교)

  • Yang, Jae-E.;Kim, Jong-Sung;Ok, Yong-Sik;Yoo, Kyung-Yoal
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.203-209
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    • 2005
  • Objective of this research was to assess the effectiveness of the different sources of the zero-valent irons (ZVIs) on the reduction of the toxic Cr(VI) to the nonhazardous Cr(III) in an aqueous solution. The physical and chemical properties of the six ZVIs were determined. Particle size and specific surface area of the ZVIs were in the ranges of $85.55{\sim}196.46{\mu}m\;and\;0.055{\sim}0.091m^2/g$, respectively. Most of the ZVIs contained Fe greater than 98% except for J (93%) and PU (88%). Reduction efficiencies of the ZVI for Cr(VI) reduction were varied with kinds of ZVIs. The J and PU ZVIs reduced 100% and 98% of Cr(VI) in the aqueous solution, respectively, within 3 hrs of reaction. However, PA, F, Sand J1 reduced 74, 65, 29 and 11% of Cr(VI), respectively, after 48 hrs. The pH of the reacting solution was rapidly increased from 3 to $4.34{\sim}9.04$ within 3 hrs. The oxidation-reduction potential (Eh) of the reacting solution was dropped from 600 to 319 mV within 3 hrs following addition of ZVIs to the Cr(VI) contaminated water. The capability of ZVIs for Cr(VI) reduction was the orders of PU > J > PA > F > S > J1, which coincided with the capacities to increase the pH and decrease the redox potentials. Results suggested that the reduction of Cr(VI) to Cr(III) was derived from the oxidation of the ZVI in the aqueous solution.

Diversity of the Cretaceous basaltic volcanics in Gyeongsang Basin, Korea (경상분지내 백악기 현무암질 화산암류의 다양성)

  • 김상욱;황상구;이윤종;고인석
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.1-12
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    • 2000
  • The Cretaceous basaltic rocks in Gyeongsang Basin are temporally and spatially dispersed widely in thick sedimentary piles: Chilgog basaltic rock (CGB) and Cheongyongsa basaltic rock (CSB) in the Shindong Group, and Hakbong basaltic rocks (HBB), Osibbong basalt (OSB), Secheondong basaltic rocks (SCB), Haman basaltic rocks (HAB), Hama basaltic rocks (HMB), and Chaeyaksan basaltic rocks (CYB) in the Hayang Group, upwardly in their stratigraphy. Chilgog basaltic rock is merely identified as pebbles in the Shilla Conglomerate and its provenance has not been found, and it is characteristics that the volcanics except Osibbong basalt and Chaeyaksan basaltic rocks are very small in both of their thickness and extension. Petrochemical diversity of the basaltic rocks are revealed; OSB and SCB distributed in the Yeongyang Minor Basin preserve the calc-alkaline natures in major and immobile minor element geochemistry, but CGB, HBB, HAB, and CYB reflect that they might be originated from calc-alkaline basaltic magma of volcanic arc in continental margin area by trace elements and altered to alkaline suites in the viewpoint of their major element geochemistry. Major and trace element geochemistry of CSB and HMB suggests that they may be derived from within -plate alkaline magma contaminated by the upper continental crust, especially in the case of the former.

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Geometric Scheme Analysis and Region Segmentation for Industrial CR Images (산업용 CR영상의 기하학적 구도분석과 영역분할)

  • Hwang, Jung-Won;Hwang, Jae-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.46 no.4
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    • pp.124-131
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    • 2009
  • A reliable detection of regions in radiography is one of the most important task before the evaluation of defects on welded joints. The extracted features is to be classified into distinctive clusters for each segmented region. But conventional segmentation techniques give unsatisfactory results for this task due to the spatial superposition of intensity and low signal-to-ratio(SNR) in radiographic images. The usage of global or local processes not only provide the necessary noise resistance but also fail in classification of regions. In this paper, we presents an appropriate approach for segmentation of region-based indications in industrial Computed Radiography(CR) images. The geometric differences between welded and non-welded area which is generated on radiography as the representative regions(background, thickness, middle and welded region in steel tube image) have constructed the hierarchical structure. Although this structure is contaminated by noise, the scheme between regions can be selected by the help of local clustering based on distinctive geometric property of each region. Because of the geometric nature of the considered region and so that the region is selected layer by layer, and that the real class represents the boundary between regions, the vertical and horizontal clustering process in each layer must be judicious. In order to show the effectiveness of this approach, a comparative experiment of various segmentation method is performed on industrial steel tube CR images.

Predicting Power Generation Patterns Using the Wind Power Data (풍력 데이터를 이용한 발전 패턴 예측)

  • Suh, Dong-Hyok;Kim, Kyu-Ik;Kim, Kwang-Deuk;Ryu, Keun-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.16 no.11
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    • pp.245-253
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    • 2011
  • Due to the imprudent spending of the fossil fuels, the environment was contaminated seriously and the exhaustion problems of the fossil fuels loomed large. Therefore people become taking a great interest in alternative energy resources which can solve problems of fossil fuels. The wind power energy is one of the most interested energy in the new and renewable energy. However, the plants of wind power energy and the traditional power plants should be balanced between the power generation and the power consumption. Therefore, we need analysis and prediction to generate power efficiently using wind energy. In this paper, we have performed a research to predict power generation patterns using the wind power data. Prediction approaches of datamining area can be used for building a prediction model. The research steps are as follows: 1) we performed preprocessing to handle the missing values and anomalous data. And we extracted the characteristic vector data. 2) The representative patterns were found by the MIA(Mean Index Adequacy) measure and the SOM(Self-Organizing Feature Map) clustering approach using the normalized dataset. We assigned the class labels to each data. 3) We built a new predicting model about the wind power generation with classification approach. In this experiment, we built a forecasting model to predict wind power generation patterns using the decision tree.

Reduction of Outdoor and Indoor Ambient Dose Equivalent after Decontamination in the Fukushima Evacuation Zones

  • Yoshida-Ohuchi, Hiroko;Kanagami, Takashi;Naitoh, Yutaka;Kameyama, Mizuki;Hosoda, Masahiro
    • Journal of Radiation Protection and Research
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    • v.42 no.1
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    • pp.42-47
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    • 2017
  • Background: One of the most urgent issues following the accident at the Fukushima Daiichi nuclear power plant (FDNPP) was the remediation of the land, in particular, for residential area contaminated by the radioactive materials discharged. In this study, the effect of decontamination on reduction of ambient dose equivalent outdoors and indoors was evaluated. The latter is essential for residents as most individuals spend a large portion of their time indoors. Materials and Methods: From December 2012 to November 2014, thirty-seven Japanese single-family detached wooden houses were investigated before and after decontamination in evacuation zones. Outdoor and indoor dose measurements (n = 84 and 114, respectively) were collected based on in situ measurements using the NaI (Tl) scintillation surveymeter. Results and Discussion: The outdoor ambient dose equivalents [$H^*(10)_{out}$] ranged from 0.61 to $3.71{\mu}Sv\;h^{-1}$ and from 0.23 to $1.32{\mu}Sv\;h^{-1}$ before and after decontamination, respectively. The indoor ambient dose equivalents [$H^*(10)_{in}$] ranged from 0.29 to $2.53{\mu}Sv\;h^{-1}$ and from 0.16 to $1.22{\mu}Sv\;h^{-1}$ before and after decontamination, respectively. The values of reduction efficiency (RE), defined as the ratio by which the radiation dose has been reduced via decontamination, were evaluated as $0.47{\pm}0.13$, $0.51{\pm}0.13$, and $0.58{\pm}0.08$ ($average{\pm}{\sigma}$) when $H^*(10)_{out}$ < $1.0{\mu}Sv\;h^{-1}$, $1.0{\mu}Sv\;h^{-1}$ < $H^*(10)_{out}$ < $2.0{\mu}Sv\;h^{-1}$, and $2.0{\mu}Sv\;h^{-1}$ < $H^*(10)_{out}$, respectively, indicating the values of RE increased as $H^*(10)_{out}$ increased. It was found that the values of RE were $0.53{\pm}0.12$ outdoors and $0.41{\pm}0.09$ indoors, respectively, indicating RE was larger outdoors than indoors. Conclusion: Indoor dose is essential as most individuals spend a large portion of their time indoors. The difference between outdoors and indoors should be considered carefully in order to estimate residents' exposure dose before their returning home.

The Persistent Paresthesia Care on Left Lingual & Buccal Shelf Regions after the Lingual & Long Buccal Nerve Block Anesthesia -A Case Report- (설신경과 장협신경 전달마취 시행 후 발생된 설부와 협선반부의 장기간 이상감각증 관리 -증례보고-)

  • Kim, Ha-Rang;Yoo, Jae-Ha;Choi, Byung-Ho;Mo, Dong-Yub;Lee, Chun-Ui;Kim, Jong-Bae
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.9 no.2
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    • pp.108-115
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    • 2009
  • Trauma to any nerve may lead to persistent paresthesia. Trauma to the nerve sheath can be produced by the needle. The patient frequently reports the sensation of an electric shock throughout the distribution of the nerve involved. It is difficult for the type of needle used in dental practice to actually sever a nerve trunk or even its fibers. Trauma to the nerve produced by contact with the needle is all that is needed to produce paresthesia. Hemorrhage into or around the neural sheath is another cause. Bleeding increases pressure on the nerve, leading to paresthesia. Injection of local anesthetic solutions contaminated by alcohol or sterilizing solution near a nerve produces irritation; the resulting edema increases pressure in the region of the nerve, leading to paresthesia. Persistent paresthesia can lead to injury to adjacent tissues. Biting or thermal or chemical insult can occur without a patient's awareness, until the process has progressed to a serious degree. Most paresthesias resolve in approximately 8 weeks without treatment. In most situations paresthesia is only minimal, with the patient retaining most sensory function to the affected area. In these cases there is only a very slight possibility of self injury. But, the patient complaints the discomfort symptoms of paresthesia, such as causalgia, neuralgiaform pain and anesthesia dolorosa. Most paresthesias involve the lingual nerve, with the inferior alveolar nerve a close second. This is the report of a case, that had the persistent paresthesia care on left lingual & buccal shelf regions after the lingual and long buccal nerve block anesthesia.

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A Study on the Measurement of Activity Concentrations of Pu and Am and Their Isotopic Ratios in the Radioactively Contaminated Soil (방사능으로 오염된 토양에 대한 Pu 및 Am 방사능 농도 및 동위원소비 측정에 대한 연구)

  • Lee, Myung Ho;Song, Byoung Chul;Park, Young Jai;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.514-519
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    • 2004
  • Soil samples collected from around the BOMARC Missile Site were measured for their activity concentrations and isotopic ratios of Pu and Am isotopes with particle sizes. The activity concentrations of Pu and Am in the BOMARC soil were remarkably higher than the fallout levels, and the activities decreased nearly exponentially with an increasing particle size of the soil due to a decreasing surface area. The activity ratios of Pu-238 / Pu-239, 240, Pu-241 / Pu-239, 240 and Am-241 / Pu-239, 240 observed in the BOMARC soil were much lower than those attributed to the nuclear reprocess plants and the Chernobyl fallout. Also, the atomic ratio of Pu-240 / Pu-239 in the BOMARC soil was remarkably lower than the fallout value influenced by the nuclear weapons testing and the Chernobyl accident. The atomic ratio of Pu-240 / Pu-239 was so close to the value of the weapons grade Pu released from the crash of a B52 plane in the Thule of the Greenland, such that the Pu isotopes detected in the BOMARC soil could have originated from the weapons grade plutonium.

A Feasibility Study on the Utilization of by-Product Sludge Generated from Waste Concrete Recycling Process (폐 콘크리트 재생순환자원 부산물 슬러지의 활용 기초연구)

  • Shin, Hee-young;Ji, Sangwoo;Woo, Jeong-youn;Ahn, Gi-oh;An, Sang-ho
    • Resources Recycling
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    • v.25 no.3
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    • pp.29-36
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    • 2016
  • The characteristics analysis and pH neutralization test were carried out to use of slurry generated from recycling processes of construction wastes. D (5.0) of raw sludge was $42.4{\mu}m$ and over 60 % of sludge distribute under 45 um (-325 mesh). Muscovite and carbonate minerals were main minerals of fine particles, and the portion of carbonate minerals increased as particle size decreased. Although the more heavy metals were observed in the finer particle size, the contents was found to be less than Korean contaminated soil regulation (area 2). The effects of flocculants addition for accelerating solid-liquid separation were negligible because the slurry already contains excess of coagulant added in the waste concrete recycling process. It was difficult to neutralize the sludge supernatant due to high pH (about 12) by adding acids, but the introduction of $CO_2$ decreased the pH to 8.5, The precipitate recovered during $CO_2$ introduction was determined to be $CaCO_3$ with XRD, and it indicates that high pure $CaCO_3$ could be obtained during the process.

Changes in Phytoavailability of Heavy Metals by Application of Limestone in the Farmland Soil nearby Abandoned Metal Mine and the Accumulation of Heavy Metals in Crops (폐금속 광산 주변 농경지 토양에서 석회석 처리에 의한 중금속의 식물유효도 변화 및 작물의 중금속 축적)

  • Yun, Sung-Wook;Yu, Chan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.3
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    • pp.1-9
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    • 2012
  • As topographic characteristics of Korea where 64 % of the national land area is forest and only 17 % is being used as farmland, remediation of farmland contaminated by heavy metals is a considerably important issue. In this study, as an alternative of practically and effectively remediating farmland which was abandoned as its crop plants exceeded maximum residue limit of heavy metals due to mining impact, applicability of stabilization method was examined through the pilot-scale field experiment. Three plots ($L{\times}W{\times}D=3m{\times}2m{\times}0.3m$) were installed at the selected farmland and in plot 1, only soil of the selected farmland was applied, in pilot 2, soil of the selected farmland plus 3 % limestone (w/w) was applied and in pilot 3, soil of the selected farmland plus 3 % limestone was applied and then uncontaminated soil was covered thereon (0.3 m). After that, seeds of radish, Korean cabbage and soybean of which characteristics of edible portions are different were sowed on each plot and cultivated. Afterwards, at a proper harvesting time (app. 80 days later), crop plants and soil were collected and phytoavailability (0.11 M HOAc extractable) of heavy metals in soil and accumulated concentration of heavy metal in edible portion of crop plants were examined. As a result, it was revealed that phytoavailability of heavy metals in soil added with limestone (plot 2) was clearly reduced compared with plot 1 (untreated) and owing to this treatment, accumulated concentration of heavy metals in edible portion of crops was also clearly reduced compared with plot 1. While radish cultivated in plot 1 had exceeded maximum residue limit of agricultural products, in particular, plot 2 using limestone had shown concentration lower than maximum residue limit and this plot had shown little difference with 3 plot where crop was cultivated in uncontaminated soil cover. Therefore, it was considered that for abandoned farmland like the selected farmland, reducing mobility and phytoavailability of heavy metals and reducing crop uptake through stabilization method would be an effective and practical alternative for producing safe agricultural products on a sustained basis.