• Title/Summary/Keyword: Contaminated Particle

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Fabrication of Niobium Powder for Solid-electrolyte Capacitors (고체 전해커패시터용 니오븀 분말제조)

  • Yoon, Jae-Sik;Hwang, Sun-Ho;Kim, Byung-Il
    • Journal of the Korean institute of surface engineering
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    • v.42 no.5
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    • pp.227-231
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    • 2009
  • The niobium capacitor showed somewhat more unstable characteristics than the commercial tantalum capacitors, but is nonetheless considered applicable as a future substitute for tantalum capacitors. In this study, niobium powder was fabricated by metallothermic reduction process using $K_2NbF_7$ as the raw materials, KCl and KF as the diluents and Na as the reducing agent. The niobium particle size greatly decreased from 0.7um to 0.2 um as the amount of diluent increased. However if a higher surface area of powder is required, more diluents need to be used in the said method in order to produce niobium powder. The niobium powder morphology and particle size are very sensitive to a amount of sodium excess. The particle size of niobium powder increased with a increasing amount of sodium excess. When more diluent and sodium are used, the niobium powder will be contaminated with more impurities such as Fe, Cr, Ni so on.

A Study on the $H_2S$ Removal with Utilization of Seashell Waste(I) -The Characteristics of Sulfided Reaction Using Thermal Gravimetric Analyzer- (패각 폐기물을 이용한 $H_2S$ 제거에 관한 연구(I) -열중량분석기를 이용한 황화반응특성-)

  • 김영식
    • Journal of Environmental Health Sciences
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    • v.29 no.2
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    • pp.45-49
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    • 2003
  • In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. According to TGA results, temperature had influenced on H$_2$S removal efficiency. As desulfurization temperature increased, desulfurization efficiency increased. Also, maximum desulfurization efficiency was observed at 80$0^{\circ}C$. Desulfurization was related to calcination temperature. Considering temperature ranges of exhausted gas from hot gas gasification equipment were 400~80$0^{\circ}C$. Thus, desulfurization efficiency would be increased desulfurization temperature situation at highly. Experiments by TGA showed that particle size of sorbents had influenced on desulfurization capacity. Maximum desulfurization capacity was observed at 0.631 mm for oyster and clam. Rest of sorbents showed similar capacity within 0.171~0.335 mm particle size range. So, particle size would be considered. When would be used waste shells as IGCC sorbents. According to the results about desulfurization capacity by TGA, oyster had the best desulfurization capacity among limestone and waste shell. We would be identify to substituted oyster for existing sorbents

Electrical Properties of Silicone Rubber with Different Particle Size and Amount of ATH (ATH의 입자크기 및 첨가량에 따른 실리콘 고무의 전기적 특성)

  • Park, Hoy-Yul;Kang, Dong-Pil;Ahn, Myeong-Sang;Myung, In-Hae;Lee, Tae-Hui;Lee, Tae-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.227-230
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    • 2003
  • Silicone rubber has very excellent chemical stability and hydrophobicity. A hydrophobic surface can prevent the formation of continuous water films on the surface in wet and heavily contaminated conditions. This phenomenon contributes to the suppression of leakage current and partial discharges on insulator surfaces. Silicone rubber has been used much for housing materials of polymer insulators. ATH is added to the silicone rubber for improvement of its resistance against surface discharge. In this paper, ATH with different particle size and content was added to the silicone rubber during compounding. Silicone rubber was deteriorated by a corona treatment. Hydrophobicity recovery rate after corona treatment and arc resistance of silicone rubber were investigated. Hydrophobicity recovery rate of silicone rubber was evaluated by the measurement of contact angle. Arc resistance was evaluated by measuring weight loss of silicone rubber after arc resistance test. It was observed that the hydrophobicity recovery rate and arc resistance of silicone rubber were different when different particle size and content of ATH were added.

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Remediation of benzo[a]pyrene Contaminated Soil using Subcritical Water (아임계수를 이용한 토양 내 벤조[a]피렌 정화)

  • Shin, Moon-Su;Islam, Mohammad Nazrul;Jo, Young-Tae;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.19 no.6
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    • pp.13-17
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    • 2014
  • Subcritical water acts like an organic solvent at elevated temperature in terms of its physicochemical properties. Taking into account this advantage, the remediation experiments of benzo[a]pyrene contaminated soil (8.45 mg/kg of initial concentration) were conducted using subcritical water extraction apparatus. The effect of operating factors on the removal efficiency was studied at the varying the conditions of the water temperature ranging $200{\sim}300^{\circ}C$, extraction time 30~90 min, and flow rate 0.3~2.0 mL/min. 12 g of benzo[a]pyrene contaminated soil was inserted into the extraction cell and placed into the reactor and then the subcritical water was driven through the cell. In this study, the removal efficiency of benzo[a]pyrene was increased from 55.1 to 98.1% when the temperature increased from 200 to $300^{\circ}C$. The removal efficiency was decreased from 97.0 to 77.0% when the flow rate increased from 0.3 to 2.0 mL/min, suggesting that the extraction is limited by intra-particle diffusion. The 30 min reaction time was determined as an effective treatment time at $250^{\circ}C$. Based on the results, the optimum condition for the remediation of benzo[a]pyrene contaminated soil was suggested to be $250^{\circ}C$, 30 min, and 0.3 mL/min.

Application of a Soil Separation System for the Remediation of Arsenic Contaminated Soil in a Metal Mining Area (폐금속광산 지역의 비소오염토양 처리를 위한 선별 기술 적용)

  • ParK, Chan-Oh;Kim, Jong-Won;Park, Jun-Hyoung;Lee, Young-Jae;Yang, In-Jae;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.5
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    • pp.56-64
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    • 2013
  • After the law has been enacted for the prevention and recovery of mining damage in 2005, efforts of remediation have been started to recover heavy metal contaminated soils in agricultural land near mining sites. As part of an effort, the upper part of cultivation layer has been treated through covering up with clean soil, but the heavy metal contamination could be still spreaded to the surrounding areas because heavy metals may be remained in the lower part of cultivation layers. In this study, the most frequently occurring arsenic (As) contamination was selected to study in agricultural land nearby an abandoned metal mining site. We applied separation technologies considering the differences in the physical characteristics of soil particles (particle size, density, magnetic properties, hydrophobicity, etc.). Based on physical and chemical properties of arsenic (As) containing particles in agricultural lands nearby mining sites, we applied sieve separation, specific gravity separation, magnetic separation, and flotation separation to remove arsenic (As)-containing particles in the contaminated soil. Results of this study show that the removal efficiency of arsenic (As) were higher in the order of the magnetic separation, flotation separation, specific gravity separation and sieve separation.

Raoultella ornithinolytica as a Potential Candidate for Bioremediation of Heavy Metal from Contaminated Environments

  • Laila Ibrahim Faqe Salih;Rezan Omer Rasheed;Sirwan Muhsin Muhammed
    • Journal of Microbiology and Biotechnology
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    • v.33 no.7
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    • pp.895-908
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    • 2023
  • Disposal of waste containing heavy metals into the environment is a major threat to human health and can result in toxic or chronic poisoning in aquatic life. In the current study, metal-resistant Raoultella ornithinolytica was isolated from metal-contaminated samples collected from the Tanjaro River, located southwest of Sulaymaniyah, Iraq. R. ornithinolytica was identified by partial amplification of 16S rRNA. The uptake potency of heavy metals was assessed using inductively coupled plasma-optical emission spectroscopy (ICP-OES) and indicated that R. ornithinolytica removed 67, 89, 63.4, 55.6, 56.5, 65, and 61.9% of Cd, Pb, Cr, Ni, Zn, Co, and Fe, respectively. These removal rates were influenced by temperature, pH, and contact time; at 35℃ and pH 5 with a change in the incubation time, the reduction rate improved from 89 to 95% for Pb, from 36.4 to 45% for Cu, and from 55.6 to 64% for Ni. Gene analysis indicated that R. ornithinolytica contained pbrT, chrB, nccA, iroN, and czcA genes, but the pcoD gene was absent. Energy-dispersive X-ray spectroscopy (EDS) images showed evidence of metal ion binding on the cell wall surface with different rates of binding. Transmission electron microscopy (TEM) detected different mechanisms for metal particle localization; cell surface adsorption was the main mechanism for Pb, Zn, and Co uptake, while Cd, Ni, and Fe were accumulated inside the cell. The current study describes, for the first time, the isolation of R. ornithinolytica from metal-contaminated water, which can be used as an eco-friendly biological expedient for the remediation and detoxification of metals from contaminated environments.

Influence of Surface Shape on Particle-initiated Breakdown in $SF_6$ Gas ($SF_6$ 가스중의 연면형상이 입자오손 파괴 전압에 미치는 영향)

  • Lee, Hyeong-Ho;Kim, Min-Kyu
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.645-647
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    • 1993
  • Surface breakdown characteristics are investigated under metallic-particle contaminated conditions in $SF_6$ gas. The main results show that a rib increases breakdown voltage by a corona stabilization effect and the elongation of discharge path. The breakdown voltage at higher pressures than 4 atm may be estimated on the basis of mean breakdown field strength($E_{BD}$) and discharge length(L) which depend on gas pressure and surface shape.

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Effect of Particulate Contamination on the Friction and Wear of Head-Disk Interface with Picoslider (오염입자가 Picoslider의 헤드-디스크 인테페이스 마찰 마모에 미치는 영향)

  • ;Bharat Bhushan
    • Tribology and Lubricants
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    • v.16 no.5
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    • pp.395-402
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    • 2000
  • The effect of particulate contamination on friction and wear between a negative-pressure picoslider and a laser-textured disk was studied. Particles of different concentrations, materials and sizes were injected to the head-disk interface (HDI), consisting of disks with various textures, at the same speed. In a contaminated environment, durability of head-disk interface gradually decreased as the particle concentration increased. Large particles caused HDI failure early and resulted in an extensive damage to the slider and disk surfaces. Hard particles also caused HDI failure earlier and damages more extensive than soft ones. Based on the test results, mechanisms of HDI failure with picoslider were presented.

Identification of flexible vehicle parameters on bridge using particle filter method

  • Talukdar, S.;Lalthlamuana, R.
    • Structural Engineering and Mechanics
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    • v.57 no.1
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    • pp.21-43
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    • 2016
  • A conditional probability based approach known as Particle Filter Method (PFM) is a powerful tool for system parameter identification. In this paper, PFM has been applied to identify the vehicle parameters based on response statistics of the bridge. The flexibility of vehicle model has been considered in the formulation of bridge-vehicle interaction dynamics. The random unevenness of bridge has been idealized as non homogeneous random process in space. The simulated response has been contaminated with artificial noise to reflect the field condition. The performance of the identification system has been examined for various measurement location, vehicle velocity, bridge surface roughness factor, noise level and assumption of prior probability density. Identified vehicle parameters are found reasonably accurate and reconstructed interactive force time history with identified parameters closely matches with the simulated results. The study also reveals that crude assumption of prior probability density function does not end up with an incorrect estimate of parameters except requiring longer time for the iterative process to converge.

Monitoring Airborne Nanoparticle Concentrations by Task in a Laboratory Making Carbon Nanotube Films (탄소나노튜브 필름 제조 실험실의 세부작업별 공기 중 나노입자 노출 농도)

  • Ha, Ju-Hyun;Shin, Yong-Chul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.4
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    • pp.248-255
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    • 2010
  • Airborne nanoparticle concentrations in three metrics (particle surface area concentration, particle number concentration, and particle mass concentrations) were measured by task in a laboratory making carbon nanotubes (CNTs) films using three direct reading instruments. Because of the conducted other researcher's experiment before the tasks, airborne nanoparticle surface area and number concentrations are the highest at the first time conducted weighing and mixing by sonication task, respectively. Because of the mist generated during mixing by sonication, the highest airborne nanoparticle surface area and PM1 concentrations were measured in the task among the total. Nanoparticle surface area concentrations at the researchers' breathing zones had high correlation (r=0.93, p<0.01) with those measured at an area in the laboratory. This result indicates that nanoparticles generated during the experiment contaminated the whole room air. When the experiment performed all the fume hoods weren't operated and making CNTs films task were conducted in the out of the fume hoods. In conclusion, researchers performing making CNTs film experiments were exposed to airborne nanoparticles generated during the experiment without adequate controls. We recommend that adequate controls should be implemented so that workers' exposures to airborne nanoparticle are limited to minimum levels.