• 제목/요약/키워드: Contaminant level

검색결과 136건 처리시간 0.027초

Level I Fugacity Model을 이용한 Biopile 내 유기화합물 5종의 분포 예측 (Prediction of Distribution for Five Organic Contaminants in Biopiles by Level I Fugacity Model)

  • 김계훈;김호진
    • 한국토양비료학회지
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    • 제41권3호
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    • pp.228-234
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    • 2008
  • 본 연구는 level I fugacity model을 이용하여 유류오염 토양에서 많이 존재하며 생태적 위해성이 큰 다섯가지 유기성오염물질 (anthracene, benzene, benzo[a]pyrene, 1-methylphenanthrene, phenanthrene) 이 기상, 액상, 고상 및 비수용성액체(NAPL)의 네 가지 상(phase)으로 구성된 biopile 내에서 어떻게 분포 하는가를 예측하기 위하여 수행하였다. 이를 위하여 영국 내에서 장기간 유류로 오염된 세 지역으로부터 토양 시료를 채취, 분석하였고 토양 분석 결과와 관련 인자를 level I fugacity model에 입력하여 fugacity 및 오염물질의 토양 중 분포를 구하였다. 다섯 오염물질의 fugacity 간에는 큰 차이가 있었으나 동일 오염물 질은 시료 간 fugacity에서 별다른 차이를 보이지 않았다. 모든 오염물질은 NAPL과 고상에 주로 존재하였으며 토양시료간의 유기탄소함량 차이가 오염물질 의 분배 동태에 큰 영향을 미쳤다. benzene은 기상과 액상에 높은 농도로 존재함으로써 위해성에 근거한 기상과 액상 중 benzene 관리의 중요성을 나타내었다. 반면 다른 오염물질은 기상과 액상에 거의 존재하지않음을 보임으로써 지하수 오염 가능성을 현저하게 감소시켰다. 본 연구의 결과는 위해성이 큰 오염물질과 복원 처리를 토양 내 오염물질 잔류 농도 간에 관련이있음을 보였으며 또한 유류오염 토양의 위해성 평가과정에서 NAPL과 고상을 고려하는 일의 중요성도 나타내었다.

Intensive land-based production of red and green macroalgae for human consumption in the Pacific Northwest: an evaluation of seasonal growth, yield, nutritional composition, and contaminant levels

  • Gadberry, Bradley A.;Colt, John;Maynard, Desmond;Boratyn, Diane C.;Webb, Ken;Johnson, Ronald B.;Saunders, Gary W.;Boyer, Richard H.
    • ALGAE
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    • 제33권1호
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    • pp.109-125
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    • 2018
  • Turkish towel (Chondracanthus exasperatus), Pacific dulse (Palmaria mollis, also known as Red ribbon seaweed), and sea lettuce (Ulva spp.) were cultivated in a land-based intensive culture system at the Manchester Research Station, USA from August 2013 to September 2014. Macroalgae were grown in tumble-aerated tanks, harvested bimonthly for seasonal growth calculations, and analyzed for protein, lipid, ash, and amino acid content. Growth rate of all three species exhibited a similar pattern, with the highest specific growth rates occurring during the summer months (Turkish towel: 7.8%, Pacific dulse: 8.2%, and sea lettuce: 6.2%). Growth of all three species was lowest around winter solstice; with negative growth only observed in sea lettuce. On a dry weight basis significant differences in protein content existed between the three species with highest values for sea lettuce ($29.5{\pm}1.4%$). Lipid content varied between species (0.95-2.78%) with significantly higher lipid observed in sea lettuce (0.58-4.82%). No significant differences were detected on a seasonal basis among each species. Essential amino acids accounted for $43{\pm}0.9$ to $47{\pm}1.2%$ of total amino acids with Turkish towel having the highest value. Turkish towel had a significantly higher taurine level ($0.82{\pm}0.27$) than the other macroalgae. The levels of persistent organic pollutants and heavy metals were low. The estimated annual product of the three species ranged from 50- to $70-mt\;dry\;weight\;ha^{-1}\;y^{-1}$, significantly higher than conventional crops. Land-based culture of these species can produce year-round harvest, consistent product quality, and low contaminant levels.

우수방사성의약품 생산시설 개발 (Development of Good Manufacturing facility for Radiopharmaceuticals)

  • 신병철;정원명;박상현;이규일;박경배;박진호
    • Journal of Pharmaceutical Investigation
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    • 제33권2호
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    • pp.145-149
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    • 2003
  • Manufacturing facilities of the pharmaceuticals must meet certain level of the cleanness required so that foreign substances such as dust, moisture, heat, microorganism, or virus do not contaminate the product. In case of radiopharmaceuticals for medical treatment and diagnosis, not only should the operators and environment be protected from radiation but also need to be isolated from the foreign contaminant. Therefore, manufacturing facilities for radiopharmaceuticals must satisfy the design standards of both hot cell and clean room which are specified by GMP. However, standards of maintaining negative pressure for preventing spread of radioactive contaminant in isolated facilities conflict with the standards of maintaining positive pressure for keeping cleanness. To solve this problem, air pressure of hot cell was designed lower than in the adjacent area to meet standards of the radiation safety. To keep higher cleanness in certain part of the hot cell for filling, minimal relative positive pressure allows. In order to effectively maintain the cleanness that is required for production of Tc-99m generator, which takes 70% of whole demand of radiopharmaceuticals, the rooms placed in each side of production room are used as a buffer area and three lead hot cells are installed in production room. In this research, we established the appropriate engineered design concept for Tc-99m generator manufacturing facility, which satisfies both GMP cleanness standard for preventing particles, bacteria, other contaminants and the regulations of radiation safety for supervising and controlling the amount of radiation exposure and exhausted radioactivity. And the concept of multi-barrier buffer zones is introduced to apply negative air pressure for hot cell with first priority and to continue relative positive air pressure for clean room.

난지도 매립지 주변 지하수환경의 오염 특성에 관한 연구 (The Contamination Characteristics of the Nanji Uncontrolled Landfill and its Surrounding Hydrogeologic Environment)

  • 이철효;한정상
    • 대한지하수환경학회지
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    • 제3권1호
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    • pp.27-36
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    • 1996
  • 난지도 매립지는 바닥차수재나 침출수 차집시설과 같은 오염방지시설이 전혀 설치되어 있지 않은 대표적인 불량 매립지로써 투수성 충적층상에 조성되어 현재 그 인근 지하수와 지표수환경에 심각한 악영향을 미치고 있다. 침출수에 의해 오염된 주변 지하수환경의 오염운(구간) 탐지시 사용할 수 있는 오염지시인자를 결정하고 난지도 매립지를 중심으로 거리별로 설치된 10개의 관측정과 1개의 BTMW*정을 이용하여 물시료를 채취 분석하거나 Electric data logger를 이용하여 그 오염물질의 수직 및 수평적인 분포특성을 파악하였다. 그 결과 온도와 전기전도도는 매립지에서 가까운 지점일수록 높았으며 침출수는 지표하 85 m 지점까지 거동하였다. 오염성분중 전기전도도와 온도는 매립지 인근지에서 오염지시인자임이 판명되었다. 완전스크린설치정(Fully screened well)에서 측정한 오염물질의 심도별 농도는 공내 전구간을 통해 일정하거나 하부구간이 약간 높은데 반해 BTMW에서 측정한 오염물질의 농도는 심도가 깊어짐에 따라 점이적으로 감소하였다. 이는 상하구간이 완전히 관통된 완전스크린설치정에서는 오염물질의 온도나 밀도차이 혹은 침출수의 수직흐름 때문에 농도가 공내에서 평준화되었기 때문이다. 따라서 매립지 인근지역에서 침출수의 수직 및 수평분포상태나 그 거동을 규명하기 위해서는 BTMW나 다점시료 채취정(multi level sampling well)을 이용하여 물시료를 채취 분석한 값을 이용해야 한다.

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Fe-loaded zeolite로 충진된 투수성 반응벽체를 이용한 지반 내 Cd과 Cr(VI)의 동시제거: 모형 토조 실험 (Simultaneous Removal of Cd and Cr(VI) in the Subsurface Using Permeable Reactive Barrier Filled with Fe-loaded Zeolite: Soil Box Experiment)

  • 이성수;이승학;박준범
    • 한국지반공학회논문집
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    • 제26권10호
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    • pp.61-68
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    • 2010
  • 반응벽제 기법을 이용해 지하수내 6가 크롬($CrO_4^{2-}$)과 카드뮴($Cd^{2+}$)을 동시 제거할 경우, 새로운 반응물질인 Fe-loaded zeolite의 적용성을 평가하기 위해 파일럿 규모의 모형 토조 실험을 수행하였다. 이를 위해, 폭 2.5m, 길이 3m, 높이 1.3m의 표가를 가지는 토조를 모래로 채우고, 양단에 수두차를 주어 지하수 흐름을 유도함으로써 대수층을 묘사하였다. 이후 6가 크롬과 카드뮴을 포함한 용액을 대수층에 주입하여 오염운을 발생시키고, 지속적인 모니터링을 통해 Fe-loaded zeolite로 구성된 모형 반응벽체의 오염운 정화거동을 관찰하였다. 실험결과, Fe-loaded zeolite로 구성된 반응벽체는 6가 크롬과 카드륨 오염운을 효과적으로 제거하며, 반응벽에 고정화된 오염물은 재탈착/유출되지 않음을 알 수 있었다. 이를 통해 Fe-loaded zeolite는, Cr(VI)과 Cd과 같이 서로 다른 이온 형태를 가진 무기 오염 물질로 동시에 오염된 지하수 정화에 반응벽체를 적용함에 있어 효과적인 충진물질이 될 수 있다는 결론을 도출하였다.

초음파검사용 젤 용기의 제균을 위한 세척방법 평가 (Evaluation of Washing Method for Sterilization of Gel Container for Ultrasound Inspection)

  • 이희정;이석준;성열훈
    • 대한방사선기술학회지:방사선기술과학
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    • 제41권3호
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    • pp.241-247
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    • 2018
  • The purpose of this study was to compare the ultrasound gel container washing methods for the sterilization of contaminants and to find the useful methods for the prevention of infection caused by the ultrasonic gel containers. In this experiment, a 250 mL ultrasonic gel container was used, and the ultrasonic gel used was a non-sterile gel (ECO GEL 99, SeungWon Medical, Korea). In order to evaluate the degree of contamination, new 250 mL 15 containers were divided into 5 groups to perform five types of washing by no treatment, washing with water, washing with soap, washing with bottle cleaner and high disinfection level washing. After the washing process, filled the gel container with gel and after 2 weeks, the number of colonies in the gel container was sampled repeatedly twice in the same ultrasonic laboratory and compared before and after washing. As a result of among the five cleaning methods used in this study, 87.2% and 88.9% of the soapy water washing (p = 0.028) and high level washing (p = 0.027) showed significant bacterial reduction rates, respectively. Our findings conclusively an ultrasonic gel container cleaning method for removing contaminants has been found to be an effective sterilization method at a low cost with a soapy water cleaning method. Therefore, it is expected that it will be helpful to prevent the infection caused by the ultrasonic gel container by suggesting the sterilization cleaning method that is practically useful in this study.

인공 및 자연강우를 이용한 축산자원화물의 배출특성에 관한 연구 (A study on the runoff characteristics of livestock resources using artificial and natural rainfall)

  • 장미향;송시훈;이현규;최윤영;황하선;김은정;김용석;이재관;류덕희;박배경
    • 한국환경과학회지
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    • 제22권12호
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    • pp.1661-1669
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    • 2013
  • This study conducted a laboratory simulation using artificial and natural rainfall in order to investigate the runoff characteristics of livestock resources through the analysis of the surface runoff water and infiltration water by rainfall intensity and fertilization level. Cattle manure and pig liquid fertilizer was used as livestock resource. As a result of this study, it was observed that the surface runoff occurred over 32 mm/hr rainfall intensity, and flow rate of the surface runoff water and the runoff ratio of contaminant parameters from livestock resource was increased, as rainfall intensity was stronger. With doubled fertilization level, T-N increased in compost and the amount of $COD_{Mn}$ runoff also considerably increased in liquefied fertilizer. In the case of natural rainfall, the runoff ratio of T-P clearly increased in compost and the T-N of final surface runoff ratio in compost and liquefied fertilizer was ranged from 0.13047 to 0.13623 with stronger rainfall intensity.

청원지역 지하수의 우라늄과 라돈의 산출 특성과 수리지화학 (Hydrogeochemistry and Occurrences of Uranium and Radon in Groundwater of in Chungwon, Korea)

  • 이병대
    • 한국환경과학회지
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    • 제27권8호
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    • pp.651-663
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    • 2018
  • The hydrochemistry of groundwater from 47 wells in the Chungwon area, Korea was analyzed to examine the occurrence of natural radionuclides like uranium and radon. The range of Electrical Conductivity (EC) value in the study area was $67{\sim}1,404{\mu}S/cm$. In addition to the high EC value, the content of cations and anions also tends to increase. Uranium concentrations ranged from $ND{\sim}178{\mu}g/L$ (median value, $0.8{\mu}g/L$) and radon concentrations ranged from 80~12,900 pCi/L (median value, 1,250 pCi/L). Uranium concentrations in one well, that is 2.8% of the samples, exceeded $30{\mu}g/L$, which is the Maximum Contaminant Level (MCL) proposed by the US Environmental Protection Agency (EPA), based on the chemical toxicity of uranium. Radon concentrations in three wells, that is 6% of the samples, and one well, that is 2.8% of the samples, exceeded 4,000 pCi/L (AMCL of the US EPA) and 8,100 pCi/L (Finland's guideline level), respectively. Concentrations of uranium and radon related to geology of the study area show the highest values in the groundwater of the granite area. The uranium and radon contents in the groundwater were found to be low compared to those of other countries with similar geological settings. It is likely that the measured value was lower than the actual content due to the inflow of shallow groundwater by the lack of casing and grouting.

국내 주요 정수장 수돗물의 퍼클로레이트 검출현황 (Occurrence of Perchlorate in Drinking Water in Korea)

  • 김현구;김정화;이연희
    • 한국물환경학회지
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    • 제23권6호
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    • pp.822-828
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    • 2007
  • Perchlorate is an unregulated contaminant but recently many cases of perchlorate contamination have been reported in the US. In Japan, also, a couple of contamination incidents caused by perchlorate occurred. Against this backdrop, investigation on perchlorate was urgent for Korea. Accordingly, perchlorate investigation in tap water and river water was conducted one time a week for seven consecutive weeks at major water sources of Korea including Han River, Guem River, Yeong-san River, and Nak-dong River. Perchlorate was not found at Han River, Guem River, and Yeong-san River. However, all the 4 tap water samples in Nak-dong River recorded high level of perchlorate. Among others, NT1 located at Daegu posted the highest value of $22.3{\mu}g/L$. This level is lower than $24.5{\mu}g/L$, the threshold recommended by US EPA. Still, perchlorate contamination in drinking water can deal a heavy blow to nerve development of infants and children by causing iodine deficiency. At the 1st and 2nd investigations, perchlorate concentration reached $18.7{\sim}95.6{\mu}g/L$ and $4.0{\sim}25.6{\mu}g/L$ respectively, both of which are relatively higher. The high perchlorate concentration in Nak-dong River was possible because of the waste water discharged from LCD manufacturing factory which was located at NS3 in Gumi, Korea. Perchlorate concentration of waste water from the factory was $730{\sim}1,858{\mu}g/L$.

지하철에 의한 서울특별시 광역 지하수 유동 특성 (Regional Groundwater Flow Characteristics due to the Subway System in Seoul, Korea)

  • 신에스더;김형수;하규철;윤희성;이은희
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권3호
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    • pp.41-50
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    • 2015
  • Hydrogeologic environment of the Mega City such as Seoul, suffers from rapid changes caused by urbanization, construction of underground subway or buildings, and contaminant loading by diverse anthropogenic activities. Understanding the present condition of groundwater environment and water budget is necessary to prevent natural and manmade disasters and to prepare for sustainable water resource management of urban environment. In this study, regional groundwater flow and water budget status of Seoul was analyzed using numerical simulation. Modeling result indicated that groundwater level distribution of Seoul generally followed the topography, but the significant decreases in groundwater level were observed around the subway network. Steady-state water balance analysis showed groundwater recharge by rainfall and leakage from the water supply network was about 550,495 m3/day. Surface water inflow and baseflow rate via Han River and major streams accounted for 799,689 m3/day and 1,103,906 m3/day, respectively. Groundwater usage was 60,945 m3/day, and the total groundwater leakage along the subway lines amounted to 114,746 m3/day. Modeling results revealed that the subway could decrease net groundwater baseflow by 40%. Our study result demonstrated that the subway system can have a significant influence on the groundwater environment of Seoul.