• Title/Summary/Keyword: Contaminant aging

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Surface Aging Phenomena of EPDM rubber by Contaminant (오손액에 의한 EPDM rubber의 표면열화 현상)

  • 이철호;김상욱
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.317-320
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    • 1997
  • The paper reports on a study of the influence of the size of the particles of alumina trihydrate(ATH) filler on the surface aging characteristics of ehylene propylene diene terpolymer(EPDM). A fixed 100pph concentration of the filler of ATH was used (or all particle sizes from 0.7 to 20$\mu\textrm{m}$, It is show that hysteresis of contact angle and leakage current increase with increasing particle size, whereas tracking resistance decrease with increasing particle size.

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The Effect of Contaminants and Surface Roughness on Tracking Aging (트랙킹 열화에 미치는 오손액과 표면거칠기의 영향)

  • Cho, H.G.;Kim, I.S.;Kang, T.P.;Ahn, M.S.;Park, Y.K.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1673-1675
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    • 1996
  • We have studied the effect of surface tension and flow rate of contaminants, wettability, frequency of applied voltage dependence of tracking breakdown. As the flow rate of contaminant is increasd, the surface resistivity is decreased, and the leakage current is increased, the time to tracking breakdown is decreased. It is found that time to tracking breakdown depends on the frequency of contaminant, that is difference of wettability. And as the frequency of applied voltage is increased, time to tracking breakdown decreased.

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Effect of Long-term Corona-discharge on RTV Silicone Rubber (장기 코로나 처리에 따른 RTV 실리콘 절연재료의 특성변화)

  • Youn, Bok-Hee;Ahn, Jong-Sik;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.266-269
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    • 2001
  • This paper investigated the aging characteristic under long-term corona discharge on roan temperature vulcanized silicone rubber, which has been using as a protective coating material for solving the contaminant problem. The applied electrical field is 10kV/cm ac and corona discharge treatment was applied on RTV silicone rubber sheet for maximum 250 hours. With the duration of corona discharge. the diffusible low molecular weight species increased, which was determined the usage of n-hexane extraction method. In addition, the contaminant layer was formed on the treated surface, and then measured the contact angle. We investigated the relation of contact angle and diffusible low molecular weight species. It is found that scissor of main chain PDMS and side chains $(CH_3)$ and the generation of LMW species were occurred by a corona discharge. The improvement of hydrophobicity rate is thought due to the increase of diffusible LMW species.

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The Effect of Contaminants on Tracking Aging in Polymer Insulating Materials (고분자 절연재료의 트랙킹 열화에 미치는 오손액의 영향)

  • 조한구;박용관
    • Electrical & Electronic Materials
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    • v.10 no.8
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    • pp.770-777
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    • 1997
  • Some polymer materials including epoxy resin are being instead of porcelain for outdoor insulating materials such as insulators bushings cable terminators and surge arrester housing. And the largest problem to be overcomed is the tracking and erosion of the outdoor polymer material brought about by dry band arcing during prolonged exposure to contaminations. In this paper the effect of surface tension wettability flow rate of contaminants with varying surfactant content and frequency of applied voltage on the tracking breakdown of epoxy insulating materials were investigated. As the flow rate of contaminant is increased the surface resistivity is decreased and the leakage current is increased the time to tracking breakdown is decreased. It is found that time to tracking breakdown depends on the surface tension of contaminant that is difference of wettability. And as the frequency of applied voltage is increased time to tracking breakdown decreased.

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Effect of Long-term Corona-discharge on RTV Silicone Rubber (장기 코로나 처리에 따른 RTV 실리콘 절연재료의 특성변화)

  • 연복희;안종식;허창수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.266-269
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    • 2001
  • This paper investigated the aging characteristic under long-term corona discharge on loon temperature vulcanized silicone rubber, which has been using as a protective coating material for solving the contaminant problem. The applied electrical field is 10kV/cm ac and corona discharge treatment was applied on RTV silicone rubber sheet for maximum 250 hours. With the duration of corona discharge, the diffusible low molecular weight species increased, which was determined the usage of n-hexane extraction method. In addition, the contaminant layer was formed on the treated surface, and then measured the contact angle. We investigated the relation of contact angle and diffusible low molecular weight species. It is found that scissor of main chain PDMS and side chains (CH$_3$) and the generation of LMW species were occurred by a corona discharge. The improvement of hydrophobicity rate is thought due to the increase of diffusible LMW species.

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Aging Characteristics of Silicone Rubber for Outdoor Use by Inclined-Plane Method (경사평면법에 의한 옥외용 실리콘 고무의 열화 특성)

  • 김정호;박용관;조한구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.501-504
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    • 1997
  • We investigated the tracking and erosion resistance of the silicone rubber by Inclined-Plane Method. And. with the variation of experiment time, the chance of the leakage current waveform was evaluated. The typical leakage current waveform was the form of mixture of sinusoidal wave and rectifying wave. It is thought that the sinusoidal wave is due to conductivity of contaminant when wet. and the rectifying wave is due to arc of dry band.

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Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Han, Dong-Hee;Lee, Un-Yong;Lim, Kee-Joe;Choi, In-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1121-1124
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    • 2004
  • Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. The diagnosis methods in off-line most are the method for virgin and last aged sample. However, the diagnosis method in on-line is method that can be evaluate sample state as progressing continuously aging test in beginning, The diagnosis method in on-line is arranged as following: leakage current measurement, electric field, surface state investigation, thermal image, emitting light measurement and then so. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination.

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Investigations of Accelerated Aged Polymeric Insulators Using Partial Discharge Signal Measurement and Analysis

  • Mekala, K.;Chandrasekar, S.;Ravindran, R. Samson
    • Journal of Electrical Engineering and Technology
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    • v.10 no.1
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    • pp.299-307
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    • 2015
  • Reduction in pollution performance of polymeric insulators, aged due to water absorption stress and thermal stress, is a major threat to the reliable operation of power transmission and distribution system. Formation of partial discharges on the surface of wet polluted insulator plays a major role in determining the life time and pollution performance of outdoor polymeric insulators. However, reports on partial discharge characteristics of water absorption stress aged and thermal aged polymeric insulators are scanty. This paper discusses the pollution performance characteristics of accelerated aged polymeric insulators using the advanced ultra wide band PD signal measurement and analysis. Laboratory experiments on accelerated aged polymeric insulators were carried out as per IEC 60507 under AC voltage, at different humidity and contamination levels using NaCl as a contaminant. PRPD pattern and Time-Frequency map analysis of PD signals were carried out. From the results, it can be speculated that PD analysis is a well suited technique to understand the pollution performance of aged polymeric insulators.

Scientific Feasibility on the Risk-Based Clean-up and Management of Contaminated Sites ("위해성" 개념을 이용한 오염지역 정화 및 관리의 과학적 타당성)

  • Shin, Won-Sik
    • Journal of Soil and Groundwater Environment
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    • v.12 no.1
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    • pp.1-35
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    • 2007
  • In the last decades, the decrease in biological or chemical availability of sorbed contaminants as contact time passed, is generally accepted. This phenomenon so called as "aging" or "sequestration" is known to directly affect risk of the contaminats. This was observed for mainly for hydrophobic organic contaminants (HOCs), but also reported for heavy metals. Aging is known to be directly related to sorption-desorption hysteresis, irreversible sorption, desorption-resistance, nonequilibrium sorption, etc. The decrease in bioavailability due to aging or sequestration indicates realistic decrease in risk potential. Recently a risk-based management concept by scientific evidences but not the simple measurement of contaminant concentration has been attempted to determine environmentally acceptable remedial endpoint. This is because selection of remedial endpoint based on not total concentration but the bioavailability and toxicity of contaminants can reduce both the treatment cost and remedial activities of the contaminated sites. The bioavailability and toxicity of the residual contaminants are highly affected by the fate and transport and also directly affect the exposure pathways and bioaccumulation of contaminants in the living biota. In this paper, scientific feasibility on the risk-based clean-up and management of contaminated sites is reviewed.

Effects of Aging and Soil Texture on Composting of Diesel-Contaminated Soil (디젤오염기간 및 토성이 오염토양 콤포스팅 처리에 미치는 영향)

  • Choi, Jung-Young;Namkoong, Wan;Park, Joon-Seok;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.132-139
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    • 2002
  • This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

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