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Modification and Properties of Polyolefin with Maleic Anhydride as a Functional Monomer (관능성 단량체로서 Maleic Anhydride를 이용한 Polyolefin의 개질 및 물성)

  • Mo, Jong-Hun;Lee, Jae-Seok;Choi, Im-Cheol;Lee, Won-Kee;Park, Sang-Bo;Min, Seong-Kee;Park, Chan-Young
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.162-167
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    • 2012
  • Surface modification of macromolecules renders a progressive and favorable method to enhance the properties of polymeric materials and improves conductivity, wettability, stability, adhesion, antibacterial properties, etc. of polymeric surfaces without deterioration of the polymer bulk properties. Polyolefins such as polyethylene and polypropylene were grafted with maleic anhydride(MAH) as a functional monomer in solution. Evidence for grafting was shown with FTIR measurement. The grafting ratio was determined from chemical titration. The higher MAH loading, the lower contact angle(${\theta}$) was obtained. With the increasing content of MAH, melting temperature($T_m$) of maleic anhydride grafted polymer decreased while decomposition temperature($T_d$) of maleic anhydride grafted polymer increased.

Controlled Release of Nerve Growth Factor from Sandwiched Poly(L-lactide-co-glycolide) Films for the Application in Neural Tissue Engineering

  • Gilson Khang;Jeon, Eun-Kyung;John M. Rhee;Lee, Ilwoo;Lee, Sang-Jin;Lee, Hai-Bang
    • Macromolecular Research
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    • v.11 no.5
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    • pp.334-340
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    • 2003
  • In order to fabricate new sustained delivery device of nerve growth factor (NGF), we developed NGF-loaded biodegradable poly(L-lactide-co-glycolide) (PLGA, the mole ratio of lactide to glycolide 75:25, molecular weight: 83,000 and 43,000 g/mole, respectively) film by novel and simple sandwich solvent casting method for the possibility of the application of neural tissue engineering. PLGA was copolymerized by direct condensation reaction and the molecular weight was controlled by reaction time. Released behavior of NGF from NGF-loaded films was characterized by enzyme linked immunosorbent assay (ELISA) and degradation characteristics were observed by scanning electron microscopy (SEM) and gel permeation chromatography (GPC). The bioactivity of released NGF was identified using a rat pheochromocytoma (PC-12) cell based bioassay. The release of NGF from the NGF-loaded PLGA films was prolonged over 35 days with zero-order rate of 0.5-0.8 ng NGF/day without initial burst and could be controlled by the variations of molecular weight and NGF loading amount. After 7 days NGF released in phosphate buffered saline and PC-12 cell cultured on the NGF-loaded PLGA film for 3 days. The released NGF stimulated neurite sprouting in cultured PC-12 cells, that is to say, the remained NGF in the NGF/PLGA film at 37 $^{\circ}C$ for 7 days was still bioactive. This study suggested that NGF-loaded PLGA sandwich film is released the desired period in delivery system and useful neuronal growth culture as nerve contact guidance tube for the application of neural tissue engineering.

A vision-based system for dynamic displacement measurement of long-span bridges: algorithm and verification

  • Ye, X.W.;Ni, Y.Q.;Wai, T.T.;Wong, K.Y.;Zhang, X.M.;Xu, F.
    • Smart Structures and Systems
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    • v.12 no.3_4
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    • pp.363-379
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    • 2013
  • Dynamic displacement of structures is an important index for in-service structural condition and behavior assessment, but accurate measurement of structural displacement for large-scale civil structures such as long-span bridges still remains as a challenging task. In this paper, a vision-based dynamic displacement measurement system with the use of digital image processing technology is developed, which is featured by its distinctive characteristics in non-contact, long-distance, and high-precision structural displacement measurement. The hardware of this system is mainly composed of a high-resolution industrial CCD (charge-coupled-device) digital camera and an extended-range zoom lens. Through continuously tracing and identifying a target on the structure, the structural displacement is derived through cross-correlation analysis between the predefined pattern and the captured digital images with the aid of a pattern matching algorithm. To validate the developed system, MTS tests of sinusoidal motions under different vibration frequencies and amplitudes and shaking table tests with different excitations (the El-Centro earthquake wave and a sinusoidal motion) are carried out. Additionally, in-situ verification experiments are performed to measure the mid-span vertical displacement of the suspension Tsing Ma Bridge in the operational condition and the cable-stayed Stonecutters Bridge during loading tests. The obtained results show that the developed system exhibits an excellent capability in real-time measurement of structural displacement and can serve as a good complement to the traditional sensors.

THREE-DIMENSIONAL FINITE ELEMENT ANALYSIS OF STRESS DISTRIBUTION AND PRELOAD OF DIFFERENT CONNECTION TYPES IMPLANT WITH INITIAL CLAMPING (임플랜트의 체결방식에 따른 초기조임력에 의한 응력분포 및 전하중에 관한 연구)

  • Lee Bum-Hyun;Chun Heoung-Jae;Lee Soo-Hong;Han Chong-Hyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.2
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    • pp.197-206
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    • 2006
  • Statement of problem: One of common problems associated with single teeth dental implant prosthetic is the loosening of screws that retain the implants. Purpose: The maintenance of screw joint stability is considered a function of the preload achieved in the screw when the suggested initial tightening torque is applied. The purpose of this study was to investigate acquired preload after initial clamping torque for estimating screw joint stability. Material and methods: A comparative study on the effect of initial clamping of two types of implant systems with different connections was conducted Three dimensional non-linear finite element analysis is adopted to compare the characteristics of screw preloads and stress distributions between two different types of implant systems composed with abutment, screw, and fixture under the same loading and boundary conditions. Results: 1. When the initial clamping torque of 32Ncm was applied to the implant systems, all types of implants generated the maximum effective stress at the first helix region of screw. 2. Morse taper connection types of implants generate lower stress distributions compared to those by butt joint connection types or implants due to large contact surface between abutment and fixture. 3. The internal types of implant systems with friction grip type implant systems have higher resistance to screw loosening than that of the external types of implant systems since the internal types of implant systems generated larger preload than that generated by the external types for the same tightening moments.

Strength of Unidirectional and Fabric Hybrid Laminate Joints (일방향-평직 복합재 혼합 적층판의 체결부 강도 연구)

  • An,Hyeon-Su;Sin,So-Yeong;Gwon,Jin-Hui;Choe,Jin-Ho;Lee,Sang-Gwan;Yang,Seung-Un
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.1
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    • pp.25-33
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    • 2003
  • The failure load and mode of the unidirectional and fabric hybrid composite laminate joints are studied by test and finite element analysis. Test is conducted for the specimens with nine various geometries under pin loading. Finite element analysis is performed considering the contact and friction effects between the pin and laminate by MSC/NASTRAN. Failure is estimated by Tsai-Wu and Yamada-Sun criteria on the characteristic curve. While the failure of the specimens with the small width and edge length are much affected by the joint geometry, the geometry effects are negligible in the specimens with large width and edge length. Finite element analysis based on the characteristic length method reasonably predicts the failure load and mode of the joints.

Adsorption Thermodynamics, Kinetics and Isosteric Heat of Adsorption of Rhodamin-B onto Granular Activated Carbon (입상 활성탄에 의한 Rhodamin-B의 흡착 열역학, 동력학 및 등량 흡착열에 관한 연구)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.199-204
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    • 2016
  • The adsorption of Rhodamine-B dye using granular activated carbon from aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, pH initial concentration, contact time and temperature. The equilibrium adsorption data showed a good fit to Langmuir isotherm model. Based on the estimated Langmuir separation factor ($R_L$ = 0.0164~0.0314), our adsorption process could be employed as an effective treatment method. The kinetics of adsorption followed the pseudo first order model. Also, the negative values of Gibbs free energy (-4.51~-13.44 kJ/mol) and positive enthalpy (128.97 kJ/mol) indicated that the adsorption was spontaneous and endothermic process. The isosteric heat of adsorption increased with increase in the surface loading indicating lateral interactions between the adsorbed dye molecules.

Optimization of Thermal Deformation in Probe Card (프로브 카드의 열변형 최적화)

  • Chang, Yong-Hoon;Yin, Jeong-Je;Suh, Yong-S.
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4121-4128
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    • 2010
  • A probe card is used in testing semiconductor wafers. It must maintain a precise location tolerance for a fine pitch due to highly densified chips. However, high heat transferred from its lower chuck causes thermal deformations of the probe card. Vertical deformation due to the heat will bring contact problems to the pins in the probe card, while horizontal deformation will cause positional inaccuracies. Therefore, probe cards must be designed with proper materials and structures so that the thermal deformations are within allowable tolerances. In this paper, heat transfer analyses under realistic loading conditions are simulated using ANSYS$^{TM}$ finite element analysis program. Thermal deformations are calculated based on steady-state temperature gradients, and an optimal structure of the probe card is proposed by adjusting a set of relevant design parameters so that the deformations are minimized.

3D FEM analysis of earthquake induced pounding responses between asymmetric buildings

  • Bi, Kaiming;Hao, Hong;Sun, Zhiguo
    • Earthquakes and Structures
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    • v.13 no.4
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    • pp.377-386
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    • 2017
  • Earthquake-induced pounding damages to building structures were repeatedly observed in many previous major earthquakes. Extensive researches have been carried out in this field. Previous studies mainly focused on the regular shaped buildings and each building was normally simplified as a single-degree-of-freedom (SDOF) system or a multi-degree-of-freedom (MDOF) system by assuming the masses of the building lumped at the floor levels. The researches on the pounding responses between irregular asymmetric buildings are rare. For the asymmetric buildings subjected to earthquake loading, torsional vibration modes of the structures are excited, which in turn may significantly change the structural responses. Moreover, contact element was normally used to consider the pounding phenomenon in previous studies, which may result in inaccurate estimations of the structural responses since this method is based on the point-to-point pounding assumption with the predetermined pounding locations. In reality, poundings may take place between any locations. In other words, the pounding locations cannot be predefined. To more realistically consider the arbitrary poundings between asymmetric structures, detailed three-dimensional (3D) finite element models (FEM) and arbitrary pounding algorithm are necessary. This paper carries out numerical simulations on the pounding responses between a symmetric rectangular-shaped building and an asymmetric L-shaped building by using the explicit finite element code LS-DYNA. The detailed 3D FEMs are developed and arbitrary 3D pounding locations between these two buildings under bi-directional earthquake ground motions are investigated. Special attention is paid to the relative locations of two adjacent buildings. The influences of the left-and-right, fore-and-aft relative locations and separation gap between the two buildings on the pounding responses are systematically investigated.

Thermal buckling analysis of FG plates resting on elastic foundation based on an efficient and simple trigonometric shear deformation theory

  • Tebboune, Wafa;Benrahou, Kouider Halim;Houari, Mohammed Sid Ahmed;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.18 no.2
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    • pp.443-465
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    • 2015
  • In this paper, an efficient and simple trigonometric shear deformation theory is presented for thermal buckling analysis of functionally graded plates. It is assumed that the plate is in contact with elastic foundation during deformation. The theory accounts for sinusoidal distribution of transverse shear stress, and satisfies the free transverse shear stress conditions on the top and bottom surfaces of the plate without using shear correction factor. Unlike the conventional trigonometric shear deformation theory, the proposed sinusoidal shear deformation theory contains only four unknowns. It is assumed that the mechanical and thermal non-homogeneous properties of functionally graded plate vary smoothly by distribution of power law across the plate thickness. Using the non-linear strain-displacement relations, the equilibrium and stability equations of plates made of functionally graded materials are derived. The boundary conditions for the plate are assumed to be simply supported on all edges. The elastic foundation is modelled by two-parameters Pasternak model, which is obtained by adding a shear layer to the Winkler model. The effects of thermal loading types and variations of power of functionally graded material, aspect ratio, and thickness ratio on the critical buckling temperature of functionally graded plates are investigated and discussed.

Verification of Effective Support Points of Stern Tube Bearing Using Nonlinear Elastic Multi-Support Bearing Elements (비선형 탄성 다점지지 베어링 요소를 이용한 선미관 베어링의 유효지지점 검증)

  • Choung, Joon-Mo;Choe, Ick-Heung;Kim, Kyu-Chang
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.5 s.143
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    • pp.479-486
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    • 2005
  • The final goal of shift alignment design is that the bearing reaction forces or mean pressures are within design boundaries for various service conditions of a ship. However, it is found that calculated bearing load can be substantially variable according to the locations of the effective support points of after sterntube bearing which are determined by simple calculation or assumption suggested by classification societies. A new analysis method for shaft alignment calculation is introduced in order to resolve these problems. Key concept of the new method is featured by adopting both nonlinear elastic and multi-support elements to simulate a bearing support Hertz contact theory is basically applied for nonlinear elastic stiffness calculation instead of the projected area method suggested by most of classification societies. Three loading conditions according to the bearing offset and the hydrodynamic moment and twelve models according to the locations of the effective support points of sterntube bearings are prepared to carry out quantitative verifications for an actual shafting system of 8000 TEU class container vessel. It is found that there is relatively large difference between assumed and calculated effective support points.