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Adsorption Characteristics of Malachite Green on Zeolite (제올라이트에 의한 말라카이트 그린의 흡착특성)

  • Lee, Jong-Jib;Um, Myeong-Heon
    • Clean Technology
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    • v.18 no.3
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    • pp.312-319
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    • 2012
  • Malachite green is used a dye but malachite green is harmful toxic substance. In this study, the adsorption characteristics of zeolite has been investigated for the adsorption of malachite green dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of malachite green by a fixed amount of zeolite have been studied in batch adsorber and fixed bed. The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 25 to $45^{\circ}C$. The estimated values of k and ${\beta}$ are 23.60-46.88, 0.225-0.347, respectively. The mechanism of the adsorption process was determined from the intraparticle diffusion model. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet concentration and initial flow rate of malachite green are increased, the corresponding adsorption breaktime appears to decrease. Breaktime increased with increasing bed height and length of adsorption zone showed similar patterns.

'Look at the Alcohol If You Want to Know the Country': Drinking Vessels as a Cultural Marker of Medieval Korea

  • KIM HAN, IN-SUNG
    • Acta Via Serica
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    • v.4 no.2
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    • pp.29-59
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    • 2019
  • As 'a total social fact,' drinks and drinking may serve as a lens through which we can view a distant society. Although not frequently discussed, drinking vessels serve the same function for accessing a past world hidden or forgotten behind written records. The present article is an art history attempt to seek a cultural link between liquor vessels used in medieval Korea and the political and social change of the period. The Goryeo period (918-1392) saw an unprecedented abundance of drinking vessels in various forms and decorations. Goryeo artisans and craftsmen produced ewers, pitchers, flasks, bottles, and others in addition to the pre-existing shapes of vessels mainly consisting of jars and bowls. I argue that this sudden burst of creativity during the Goryeo period was closely related to Goryeo's constant and diverse contacts with foreign powers. Their zone of international connections was not confined to the Chinese world, as we have commonly presumed. Even before the Mongol intervention, Goryeo was in contact with regions beyond East Asia through the northern nomadic states. Khitan Liao was recorded as having worked as a kind of international intermediary to link the Chinese and Islamic worlds. This medieval global culture became a norm in Goryeo society when it became an important part of the Mongol Empire. These nomadic powers brought global trends to Goryeo, and foreign drinks were among them; kumis, araq, and grape wines are just three cases of them discussed in this article. The change of alcoholic drinks led to, or was accompanied by, a new range of drinking vessels. Three types of ewers, familiar to East Asian consumers but foreign in their origin, are discussed in the main text to highlight such social change. Three more cases of drinking cups are also presented. The article shows that medieval Korean society was far more open to international art and culture than our usual understanding, and in their drinking vessels, Goryeo culture embraced global trends reaching China, the Islamic world and Europe.

Optimization of Drive-in Process with Various Times and Temperatures in Crystalline Silicon Solar Cell Fabrication (결정질 실리콘 태양전지 도핑 확산 공정에서 시간과 온도 변화에 의한 Drive-in 공정 연구)

  • Lee, Hee-Jun;Choi, Sung-Jin;Myoung, Jae-Min;Song, Hee-Eun;Yu, Gwon-Jong
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.51-55
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    • 2011
  • In this paper, the optimized doping condition of crystalline silicon solar cells with 156 ${\times}$ 156 mm2 area was studied. To optimize the drive-in condition in the doping process, the other conditions except drive-in temperature and time were fixed. After etching 7 ${\mu}m$ of the surface to form the pyramidal structure, the silicon nitride deposited by the PECVD had 75~80 nm thickness and 2 to 2.1 for a refractive index. The silver and aluminium electrodes for front and back sheet, respectively, were formed by screen-printing method, followed by firing in $400-425-450-550-850^{\circ}C$ five-zone temperature conditions to make the ohmic contact. Drive-in temperature was changed in range of $828^{\circ}C$ to $860^{\circ}C$ and time was from 3 min to 40 min. The sheet resistance of wafer was fixed to avoid its effect on solar cell. The solar cell fabricated with various conditions showed the similar conversion efficiency of 17.4%. This experimental result showed the drive-in temperatures and times little influence on solar cell characteristics.

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Assessment of Steam Generator Tubes with Multiple Axial Through-Wall Cracks (축방향 다중관통균열이 존재하는 증기발생기 세관 평가법)

  • Moon, Seong-In;Chang, Yoon-Suk;Kim, Young-Jin;Lee, Jin-Ho;Song, Myung-Ho;Choi, Young-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.11
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    • pp.1741-1751
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    • 2004
  • It is commonly requested that the steam generator tubes wall-thinned in excess of 40% should be plugged. However, the plugging criterion is known to be too conservative for some locations and types of defects and its application is limited to a single crack in spite of the fact that the occurrence of multiple through-wall cracks is more common in general. The objective of this research is to propose the optimum failure prediction models for two adjacent through-wall cracks in steam generator tubes. The conservatism of the present plugging criteria was reviewed using the existing failure prediction models for a single crack, and six new failure prediction models for multiple through-wall cracks have been introduced. Then, in order to determine the optimum ones among these new local or global failure prediction models, a series of plastic collapse tests and corresponding finite element analyses for two adjacent through-wall cracks in thin plate were carried out. Thereby, the reaction force model, plastic zone contact model and COD (Crack-Opening Displacement) base model were selected as the optimum ones for assessment of steam generator tubes with multiple through-wall cracks. The selected optimum failure prediction models, finally, were used to estimate the coalescence pressure of two adjacent through-wall cracks in steam generator tubes.

Measurement and Analysis of Coal Conversion Efficiency for a Coal Recirculating Fuel Cell Simulator (석탄순환형 연료전지 모사시스템용 석탄전환율 측정 및 분석법개발에 관한 연구)

  • Lee, Sangcho;Kim, Chihwan;Hwang, Munkyeong;kim, Minseong;Kim, Kyubo;Jeon, Chunghwan;Song, Juhun
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.503-512
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    • 2012
  • There is a new power generation system such as direct coal fuel cell (DCFC) with a solid oxide electrolyte operated at relatively high temperature. In the system, it is of great importance to feed coal continuously into anodic electrode surface for its better contact, otherwise it would reduce electrochemical conversion of coal. For that purpose, it is required to improve the electrochemical conversion efficiency by using either rigorous mixing condition such as fluidized bed condition or just by recirculating coal particle itself successively into the reaction zone of the system. In this preliminary study, we followed the second approach to investigate how significantly particle recycle would affect the coal conversion efficiency. As a first phase, coal conversion was analyzed and evaluated from the thermochemical reaction of carbon with air under particle recirculating condition. The coal conversion efficiency was obtained from raw data measured by two different techniques. Effects of temperature and fuel properties on the coal conversion are specifically examined from the thermochemical reaction.

Improvement Method for Preventing Groundwater Pollution in Jeju Island (제주도 지하수관정의 오염저감방안)

  • Yang, Sung-Kee;Han, Sang-Cheol
    • Journal of Environmental Science International
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    • v.16 no.6
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    • pp.735-743
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    • 2007
  • A grouting method is the way to effectively prevent pollutants from spreading into the ground during the digging process of groundwater. This study, based on the comparative study of grouting methods being generally accepted, suggests various construction methods which are suitable for geological structure as follows: In Jeju Island, it is very likely that rocks may fall in shuttered zones such as cracks, joints, scoria layers, and clinker layers. For this reason, it is recommended that materials be injected from the bottom toward the top, not from the top to the bottom. In the case where the amount of injected materials become too large in the areas of cracks or joints because of high level of permeability coefficient, grouting materials which smeared into surrounding areas may cause unwanted cut in the aquifer of the bottom level. To avoid this, the amount of water should be reduced from the typical water-cement ratio of 1:2, and grouting materials with larger grading should be used. If the deep excavation of ground is made in Jeju Island, it is likely to have lots of voids because of geological characteristics. Based on the results of this research, it is found that to construct interior casing, the centralizer should be attached to the casing to prevent the casing from being in contact with the counter fort. The grouting in Jeju Island should be thicker than usual. To avoid over-use of grouting materials, to prevent grouting in more than necessary zone, and to facilitate grouting of void areas, the flexible selection of materials is required. And, to exactly figure out the interior of dug well, an examination through CCTV should necessarily be performed when grouting work is in progress.

Development of Feature Selection Method for Neural Network AE Signal Pattern Recognition and Its Application to Classification of Defects of Weld and Rotating Components (신경망 AE 신호 형상인식을 위한 특징값 선택법의 개발과 용접부 및 회전체 결함 분류에의 적용 연구)

  • Lee, Kang-Yong;Hwang, In-Bom
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.1
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    • pp.46-53
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    • 2001
  • The purpose of this paper is to develop a new feature selection method for AE signal classification. The neural network of back propagation algorithm is used. The proposed feature selection method uses the difference between feature coordinates in feature space. This method is compared with the existing methods such as Fisher's criterion, class mean scatter criterion and eigenvector analysis in terms of the recognition rate and the convergence speed, using the signals from the defects in welding zone of austenitic stainless steel and in the metal contact of the rotary compressor. The proposed feature selection methods such as 2-D and 3-D criteria showed better results in the recognition rate than the existing ones.

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장풍 폐광산의 산성광산폐수에 의한 침출수 유동에 대한 지구물리 및 지화학탐사자료의 상관해석

  • Kim, Ji-Su;Han, Su-Hyeong;Choe, Sang-Hun;Lee, Gyeong-Ju;Lee, In-Gyeong;Lee, Pyeong-Gu
    • Journal of the Korean Geophysical Society
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    • v.5 no.1
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    • pp.19-27
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    • 2002
  • Geophysical surveys(self-potential, electromagnetic, electrical resistivity, and seismic refraction methods) were performed to delineate the flow channel of leachate from a AMD (acid mine drainage) by correlating the anomalies to geochemical characteristics at an abandoned mine (Jangpoong mine). The geophysical responses attempted to be correlated with water sample analysis data(pH, EC, heavy metals, ${SO_4}^{-2}$). Electrical dipole-dipole resistivity sections represent the low-resistivity zone trending northwest, which indicates the leachate flow by AMD along the contact of the mine waste rock dump and the bedrock. From the overall points of geophysical and geochemical anomalies, it is summarized that the flow channel of leachate by AMD can be successfully imaged with composite interpretations on the geophysical and geochemical studies.

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Development of Evaluation Model of Pumping and Drainage Station Using Performance Degradation Factors (농업기반시설물 양·배수장의 성능저하 요인분석 및 성능평가 모델 개발)

  • Lee, Jonghyuk;Lee, Sangik;Jeong, Youngjoon;Lee, Jemyung;Yoon, Seongsoo;Park, Jinseon;Lee, Byeongjoon;Lee, Joongu;Choi, Won
    • Journal of The Korean Society of Agricultural Engineers
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    • v.61 no.4
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    • pp.75-86
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    • 2019
  • Recently, natural disasters due to abnormal climates are frequently outbreaking, and there is rapid increase of damage to aged agricultural infrastructure. As agricultural infrastructure facilities are in contact with water throughout the year and the number of them is significant, it is important to build a maintenance management system. Especially, the current maintenance management system of pumping and drainage stations among the agricultural facilities has the limit of lack of objectivity and management personnel. The purpose of this study is to develop a performance evaluation model using the factors related to performance degradation of pumping and drainage facilities and to predict the performance of the facilities in response to climate change. In this study, we focused on the pumping and drainage stations belonging to each climatic zone separated by the Korea geographical climatic classification system. The performance evaluation model was developed using three different statistical models of POLS, RE, and LASSO. As the result of analysis of statistical models, LASSO was selected for the performance evaluation model as it solved the multicollinearity problem between variables, and showed the smallest MSE. To predict the performance degradation due to climate change, the climate change response variables were classified into three categories: climate exposure, sensitivity, and adaptive capacity. The performance degradation prediction was performed at each facility using the developed performance evaluation model and the climate change response variables.

Review of the Silicon Oxide and Polysilicon Layer as the Passivated Contacts for TOPCon Solar Cells

  • Mengmeng Chu;Muhammad Quddamah Khokhar;Hasnain Yousuf;Xinyi Fan;Seungyong Han;Youngkuk Kim;Suresh Kumar Dhungel;Junsin Yi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.233-240
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    • 2023
  • p-type Tunnel Oxide Passivating Contacts (TOPCon) solar cell is fabricated with a poly-Si/SiOx structure. It simultaneously achieves surface passivation and enhances the carriers' selective collection, which is a promising technology for conventional solar cells. The quality of passivation is depended on the quality of the tunnel oxide layer at the interface with the c-Si wafer, which is affected by the bond of SiO formed during the subsequent annealing process. The highest cell efficiency reported to date for the laboratory scale has increased to 26.1%, fabricated by the Institute for Solar Energy Research. The cells used a p-type float zone silicon with an interdigitated back contact (IBC) structure that fabricates poly-Si and SiOx layer achieves the highest implied open-circuit voltage (iVoc) is 750 mV, and the highest level of edge passivation is 40%. This review presents an overview of p-type TOPCon technologies, including the ultra-thin silicon oxide layer (SiOx) and poly-silicon layer (poly-Si), as well as the advancement of the SiOx and poly-Si layers. Subsequently, the limitations of improving efficiency are discussed in detail. Consequently, it is expected to provide a basis for the simplification of industrial mass production.